Two‐sided matching framework for optimal user association in 5G multi‐RAT UDNs

Recently, academic and industrial research communities are paying more explicit attention to the 5G multiple radio access technology ultra‐dense networks (5G multi‐RAT UDNs) for boosting network capacity, especially in UD urban zones. To this aim, in this paper, we intend to tackle the user association problem in 5G multi‐RAT UDNs. By considering the decoupled uplink/downlink access (DUDA), we divide our user association problem into two distinct subproblems representing, respectively, the uplink and the downlink channels. Next, we formulated each one as a nonlinear optimization problem with binary variables. Then, to solve them, we were restricted by the hard complexity, as well as the hard feasibility of centralized user association schemes. Thus, to resolve our user association problem in a reasonable time and distributed manner, we formulated each subproblem as a many‐to‐one matching game based on matching theory. Next, we provide two fully distributed association algorithms to compute the uplink and downlink stable matching among user equipments (UEs) and base stations (BSs). Simulation results corroborate our theoretical model and show the effectiveness and improvement of our achieved results in terms of the overall network performance, quality of service (QoS), and energy efficiency (EE) of UEs.     

Fatty Acids in Heterocyclic Synthesis Part XII: Synthesis of Surfactants from Pyrazole, Isoxazole, Pyrimidine and Triazine, Incorporating the 1,3,4-Thiadiazole Moiety Having Dyeing and Antimicrobial Activities

The titled compounds were prepared from 2-amino-5-heptadecyl[1,3,4]thiadiazole (1). Diazotization of (1) produced (2) which was coupled with active methylene compounds and gave azo ⇌ hydrazono derivatives (3A, 3B) _a–d . It was found that there is regio-specificity for addition of different nucleophiles to these tautomers; thus, nitrogen nucleophiles such as hydrazine hydrate, hydroxylamine hydrochloride and thiourea were reacted via Azo tautomer (3A) to yield pyrazole, isoxazole and pyrimidine respectively (5-7), while carbon nucleophiles as phenylisocyanate was reacted via the hydrazono tautomer (3B) and produced triazine derivatives (4). Additionally, the diazonium chloride (2) was coupled with alkaline 2-naphthol and produced 2-(5-heptadecyl-[1,3,4]thiadiazol-2-yl)-1,2-dihydro-3-oxa-1,2-diaza-cyclopenta[a]naphthalene (8). UV–visible spectra of the synthesized colored compounds (2-8) showed λ _max at 374–398 nm, while screening these compounds in vitro against micro-organisms (including structure-activity relationship SAR study) revealed high antibacterial and moderate antifungal activities. Propoxylation of compounds 1, 3, 5, 6, 7 and 8 with 3, 5, 7 mol of propylene oxide produced nonionic surfactants I(a–c)–IX(a–c) having surface active properties so, it is clear that the tested surfactants can be used in the manufacture of dyes, drugs, cosmetics, emulsifiers, pesticides, luminphores for optical applications and many other industries with low toxicity to human beings and the environment owing to their high solubility and good biodegradability.     

Preparation, characterisation of thermally treated Algerian dolomite powders and application to azo-dye adsorption

Dolomite powder from Ouled Mimoun, Tlemcen (western region of Algeria) was thermally treated within the temperature range 450-1000 °C. The modifications undergone by dolomite, inherent to thermal treatment, were investigated from X-ray diffraction patterns. The results were also discussed using scanning electronic microscopy and nitrogen adsorption. The XRD data, analysed from X Pert Plus program, showed that the dolomite phase ceases at 700 °C and is relayed by the formation of in situ calcite and periclase. The crystallographic parameters of these two phases tend towards that of pure periclase and calcite at 1000 and 900 °C, respectively. SEM analysis indicated that the morphological properties were profoundly affected. SEM images of D-1000 (sample treated at 1000 °C) indicated that the original particle shape of dolomite (presence of discrete grains having sharp edges with presence of cleavages) was totally destroyed, leading to small spherical particles with a diameter of 0.1 μm. The specific surface area value of D-1000 increased more than 6 times against that of the raw dolomite. Adsorption of azo-dye Orange I from aqueous solutions onto untreated and treated dolomites was also reported. The isotherms were of L-type. The interaction was explained by electrostatic considerations between sulfonate groups of the dye (D-SO₃Na), which are dissociated in the aqueous system, and positively charged adsorption sites. The affinity of orange I for the dolomitic solids follows the sequence D-900 > D-1000 > D-800 > > D-600 > raw dolomite. The maximum retention capacity shown by D-900 was explained and correlated with its crystallographic properties.     

Synthesis of MIL-101@g-C<Subscript>3</Subscript>N<Subscript>4</Subscript> nanocomposite for enhanced adsorption capacity towards CO<Subscript>2</Subscript>

MIL-101@g-C₃N₄ nanocomposite was prepared by solvothermal synthesis and used for CO₂ adsorption. The parent materials (MIL-101 and g-C₃N₄) and the MIL-101@g-C₃N₄ were characterized by X-ray diffraction, argon adsorption/desorption, Fourier transform infrared spectroscopy, thermal analysis (TG/DTA), transmission electronic microscopy, and Energy-dispersive X-ray spectroscopy. The results confirmed the formation of well-defined MIL-101@g-C₃N₄ with interesting surface area and pore volume. Furthermore, both MIL-101 and MIL-101@g-C₃N₄ were accomplished in carbon dioxide capture at different temperatures (280, 288, 273 and 298 K) at lower pressure. The adsorption isotherms show that the nanocomposite has a good CO₂ adsorption affinity compared to MIL-101. The best adsorption capacity is about 1.6 mmol g^?1 obtained for the nanocomposite material which is two times higher than that of MIL-101, indicating strong interactions between CO₂ and MIL-101@g-C₃N₄. This difference in efficacy is mainly due to the presence of the amine groups dispersed in the nanocomposite. Finally, we have developed a simple route for the preparation of an effective and new adsorbent for the removal of CO₂, which can be used as an excellent candidate for gas storage, catalysis, and adsorption.     

Construction and analytical characterization of Prussian-Blue-based carbon paste electrodes and their assembly as oxidase enzyme sensors

This paper reports on the development and characterization of Prussian Blue-modified carbon paste electrodes. New methods of matrix modification with Prussian Blue are reported. Two different carbon pastes have been prepared, using mineral oil or solid paraffin, thus obtaining different types of sensors whose behavior toward the electrochemical reduction of hydrogen peroxide has been fully characterized. Results obtained with Prussian Blue-modified electrodes showed a long operational lifetime, an excellent stability in a wide range of pH (3-9), a high sensitivity, and a fast response time. In addition, the coupling of solid carbon paste modified with Prussian Blue and the enzymes glucose oxidase and choline oxidase led to the assembling of biosensors that showed an optimum working range at alkaline pH.     

Scheduling with accurate communication delay model and scheduler implementation for multiprocessor system-on-chip

In multiprocessor system-on-chip, tasks and communications should be scheduled carefully since their execution order affects the performance of the entire system. When we implement an MPSoC according to the scheduling result, we may find that the scheduling result is not correct or timing constraints are not met unless it takes into account the delays of MPSoC architecture. The unexpected scheduling results are mainly caused from inaccurate communication delays and or runtime scheduler’s overhead. Due to the big complexity of scheduling problem, most previous work neglects the inter-processor communication, or just assumes a fixed delay proportional to the communication volume, without taking into consideration subtle effects like the communication congestion and synchronization delay, which may change dynamically throughout tasks execution. In this paper, we propose an accurate scheduling model of hardware/software communication architecture to improve timing accuracy by taking into account the effects of dynamic software synchronization and detailed hardware resource constraints such as communication congestion and buffer sharing. We also propose a method for runtime scheduler implementation and consider its performance overhead in scheduling. In particular, we introduce efficient hardware and software scheduler architectures. Furthermore, we address the issue of centralized implementation versus distributed implementation of the schedulers. We investigate the pros and cons of the two different scheduler implementations. Through experiments with significant demonstration examples, we show the effectiveness of the proposed approach.     

Optimizing Concentration of Drag Reducing Polymer in Case of One- and Two-Phase Flow in 90° Copper Elbow

Journal of Failure Analysis and Prevention - The rate of diffusion-controlled corrosion of 90° Copper Elbow by acidified dichromate has been investigated in relation to the following...     

Heat transfer inside a horizontal channel with an open trapezoidal enclosure subjected to a heat source of different lengths

The heat transfer phenomena inside a horizontal channel with an open trapezoidal enclosure subjected to a heat source of different lengths was investigated numerically in the present work. The heat source is considered as a local heating element of varying length, which is embedded at the bottom wall of the enclosure and maintained at a constant temperature. The air flow enters the channel horizontally at a constant cold temperature and a fixed velocity. The other walls of the enclosure and the channel are kept thermally insulated. The flow is assumed laminar, incompressible, and two‐dimensional, whereas the fluid is considered Newtonian. The results are presented in the form of the contours of velocity, isotherms, and Nusselt numbers profiles for various values of the dimensionless heat source lengths (0.16 ≤ ε ≤ 1). while, both Prandtl and Reynolds numbers are kept constant at (Pr = 0.71) and (Re = 100), respectively. The results indicated that the distribution of the isotherms depends significantly on the length of the heat source. Also, it was noted that both the local and the average Nusselt numbers increase as the local heat source length increases. Moreover, the maximum temperature is located near the heat source location.     

Internet of Things for the Future of Smart Agriculture: A Comprehensive Survey of Emerging Technologies

This paper presents a comprehensive review of emerging technologies for the internet of things(IoT)-based smart agriculture.We begin by summarizing the existing surveys and describing emergent technologies for the agricultural IoT,such as unmanned aerial vehicles,wireless technologies,open-source IoT platforms,software defined networking(SDN),network function virtualization(NFV)technologies,cloud/fog computing,and middleware platforms.We also provide a classification of IoT applications for smart agriculture into seven categories:including smart monitoring,smart water management,agrochemicals applications,disease management,smart harvesting,supply chain management,and smart agricultural practices.Moreover,we provide a taxonomy and a side-by-side comparison of the state-ofthe-art methods toward supply chain management based on the blockchain technology for agricultural IoTs.Furthermore,we present real projects that use most of the aforementioned technologies,which demonstrate their great performance in the field of smart agriculture.Finally,we highlight open research challenges and discuss possible future research directions for agricultural IoTs.