Simultaneous removal of organic and inorganic pollutants in tannery wastewater using electrocoagulation technique

Tannery wastewater can cause severe environmental problems related to its high chemical oxygen demand, high biochemical oxygen demand, high total suspended solids, high oil and grease contents together with the elevated chromium concentration and objectionable color. The one-step electrocoagulation process was carried out to simultaneously remove chromium and various pollutants from tannery wastewater at ambient temperature in the laboratory scale. Low-cost commercial iron plates were employed in this study as anodes and cathode materials. Effects of various parameters were investigated including types of electrode configuration, initial pH of wastewater (7–9), current density (15.7–24.6 Am⁻²) and circulating flow rate of wastewater (0–3.67 lmin⁻¹). The optimum condition was found by applying the mono-polar electrode in a parallel connection at the current density of 22.4 Am⁻², flow rate of wastewater of 3.67 lmin⁻¹ and 20 min electrolysis time. The initial pH of wastewater ranging from 7–9 provided the similar removal efficiency. At optimum condition, more than 95% of chromium and pollutants except TKN and TDS were eliminated from the wastewater and the properties of the treated wastewater met the standard and permitted to discharge into the environment. The required energy consumption at optimum condition was less than 0.13 kWhm⁻³ wastewater. In addition, the COD reduction was fit very well with the first-order kinetics model.     

Effect of Suspension Plasma-Sprayed YSZ Columnar Microstructure and Bond Coat Surface Preparation on Thermal Barrier Coating Properties

Suspension plasma spraying (SPS) is identified as promising for the enhancement of thermal barrier coating (TBC) systems used in gas turbines. Particularly, the emerging columnar microstructure enabled by the SPS process is likely to bring about an interesting TBC lifetime. At the same time, the SPS process opens the way to a decrease in thermal conductivity, one of the main issues for the next generation of gas turbines, compared to the state-of-the-art deposition technique, so-called electron beam physical vapor deposition (EB-PVD). In this paper, yttria-stabilized zirconia (YSZ) coatings presenting columnar structures, performed using both SPS and EB-PVD processes, were studied. Depending on the columnar microstructure readily adaptable in the SPS process, low thermal conductivities can be obtained. At 1100 °C, a decrease from 1.3 W m^?1 K^?1 for EB-PVD YSZ coatings to about 0.7 W m^?1 K^?1 for SPS coatings was shown. The higher content of porosity in the case of SPS coatings increases the thermal resistance through the thickness and decreases thermal conductivity. The lifetime of SPS YSZ coatings was studied by isothermal cyclic tests, showing equivalent or even higher performances compared to EB-PVD ones. Tests were performed using classical bond coats used for EB-PVD TBC coatings. Thermal cyclic fatigue performance of the best SPS coating reached 1000 cycles to failure on AM1 substrates with a β-(Ni,Pt)Al bond coat. Tests were also performed on AM1 substrates with a Pt-diffused γ-Ni/γ′-Ni₃Al bond coat for which more than 2000 cycles to failure were observed for columnar SPS YSZ coatings. The high thermal compliance offered by both the columnar structure and the porosity allowed the reaching of a high lifetime, promising for a TBC application.     

Unimportance of geometric nonlinearity in analysis of flanged joints with metal-to-metal contact

Gasketless flanged joints with metal to metal contact offer some advantages over gasketed joints such as lower weight and better fatigue life. Design of such joints is often based on finite element analyses, and complicated by the fact that the area of contact between the flanges changes upon application of loads. Such analyses can be done using commercial software, which can incorporate geometrical nonlinearities as well as contact nonlinearities. Engineering intuition suggests that the role of geometrical nonlinearities might be small for such problems. However, many engineers continue to use the fully nonlinear analyses. Our aim in this paper is simply to put on record that significant savings in time can be obtained by “turning off” geometric nonlinearities in such analyses, with negligible loss of accuracy. To this end, a nonautomated implementation of the basic ideas is first demonstrated for a simple geometry; more automated analyses for a more general geometry follow.     

How many Enrons? Mark-ups in the stated capital cost of independent power producers' (IPPs') power projects in developing countries

I analyze the determinants of the stated capital cost of IPPs' power projects which significantly influences their price of power. I show that IPPs face a strong incentive to overstate their capital cost and argue that effective competition or regulatory scrutiny will limit the extent of the same. I analyze the stated capital costs of combined cycle gas turbine (CCGT) IPP projects in eight developing countries which became operational during 1990–2006 and find that the stated capital cost of projects selected without competitive bidding is 44–56% higher than those selected with competitive bidding, even after controlling for the effect of cost differences among projects. The extent to which the stated capital costs of projects selected without competitive bidding are higher compared those selected with competitive bidding, is a lower bound on the extent to which they are overstated. My results indicate the drawbacks associated with a policy of promoting private sector participation without an adequate focus on improving competition or regulation.     

Analysis of exoskeleton triglycerides ofLeptinotarsa decemlineata say

The exoskeleton triglyceride fraction isolated from the Colorado beetle,Leptinotarsa decemlineata Say, was studied. Analysis of the hydrolysis products and direct capillary column gas chromatography showed that, apart from triglycerides, the fraction contained no diol lipids. The composition of the natural triacylglccerol mixture was assessed by gas chromatography and by field desorption and electron impact mass spectrometry. Triglycerides isolated from the Colorado beetle are typical glycerol triesters, with long chain (mainly oleic or palmitic) fatty acids. The structures of two major components (91%), i.e., trioleoyl glycerol and 1,2-dioleoyl-3-palmitoyl glycerol, were determined.     

Functionalized oligopolysiloxanes by heterogeneously catalyzed equilibration polymerization reactions

Summary A new general procedure for preparation of functionalized oligopolysiloxanes of predetermined molecular weight is described. It utilizes heterogeneously catalyzed siloxane equilibration polymerization reactions which do not require troublesome and sometimes difficult post-preparative work-up procedures usually encountered with the well known homogeneously catalyzed corresponding reactions. The method is described using as example the preparation of , -telechelic vinyldimethylsiloxy-oligopolydimethylsiloxanes from octamethylcyclotetrasiloxane and 1,3-divinyltetramethyldisiloxane, but reference to the preparations of trimethylsiloxy-, dimethylsiloxy-and carboxypropyldimethylsiloxyoligopolydimethylsiloxanes, oligopolymethylhydridosiloxanes or their copolymers is also made.     

Model-based approximate querying in sensor networks

Declarative queries are proving to be an attractive paradigm for interacting with networks of wireless sensors. The metaphor that “the sensornet is a database” is problematic, however, because sensors do not exhaustively represent the data in the real world. In order to map the raw sensor readings onto physical reality, a model of that reality is required to complement the readings. In this article, we enrich interactive sensor querying with statistical modeling techniques. We demonstrate that such models can help provide answers that are both more meaningful, and, by introducing approximations with probabilistic confidences, significantly more efficient to compute in both time and energy. Utilizing the combination of a model and live data acquisition raises the challenging optimization problem of selecting the best sensor readings to acquire, balancing the increase in the confidence of our answer against the communication and data acquisition costs in the network. We describe an exponential time algorithm for finding the optimal solution to this optimization problem, and a polynomial-time heuristic for identifying solutions that perform well in practice. We evaluate our approach on several real-world sensor-network datasets, taking into account the real measured data and communication quality, demonstrating that our model-based approach provides a high-fidelity representation of the real phenomena and leads to significant performance gains versus traditional data acquisition techniques. This article includes and extends results that were previously published in VLDB 2004 [Desphande, A., Guestrin, C., Madden, S., Hellerstein, J.M., Hong, W.: Model-driven data acquisition in sensor networks. In {VLDB} (2004)], and combines these techniques with the conditional planning approach published in ICDE 2005 [Deshpande, A., Guestrin, C., Madden, S., Hong, W.: Exploiting correlated attributes in acquisitional query processing. In {ICDE} (2005)].