Frequently multivariate experimental data taken over multiple occasions is found to produce a multivariate multi-table experiment. Neither the separate analysis of each occasion, using MANOVA or canonical variate analysis, nor the joint analysis using the STATIS-ACT methodology for multiple tables, are adequate to capture the real structure of the data matrices, since the first account for group structure but not time evolution and the second confuses the “between” and “within” group variabilities. A method baptized Canonical STATIS, based on STATIS-ACT methodology, is proposed. The method permits to account for data group structure as well as time evolution on the various occasions by obtaining common or stable canonical variates across multiple occasions or data sets. A simultaneous representation of groups, variables and occasions (biplot) is obtained, thereby widening the capabilities of classical methods. 相似文献
The use of online analytical processing (OLAP) systems as data sources for data mining techniques has been widely studied and has resulted in what is known as online analytical mining (OLAM). As a result of both the use of OLAP technology in new fields of knowledge and the merging of data from different sources, it has become necessary for models to support imprecision. We, therefore, need OLAM methods which are able to deal with this imprecision. Association rules are one of the most used data mining techniques. There are several proposals that enable the extraction of association rules on DataCubes but few of these deal with imprecision in the process. The main problem observed in these proposals is the complexity of the rule set obtained. In this paper, we present a novel association rule extraction method that works over a fuzzy multidimensional model which is capable of representing and managing imprecise data. Our method deals with the problem of reducing the complexity of the result obtained by using fuzzy concepts and a hierarchical relation between them. 相似文献
A spectrometric method for the determination of L-carnitine has
been developed based on the reaction of the 5,5′ dithiobis-(2-nitrobenzoic) acid (DTNB) and adapted to a Technicon RA-2000 automatic analyser Química Farmacéutica Bayer, S.A.). The detection limit of the method is 13.2 μmol/l, with a measurement interval ranging from 30 to 320 μmoll1. Imprecision and accuracy are good even at levels close to the detection limit (coeffcient of variation of 5.4% for within-run imprecision for a concentration of 35 μmol/l). A good correlation was observed between the method studied and the radiometric method. The method evaluated has suffcient analytical sensitivity to diagnose carnitine deficiencies. The short time period required for sample processing (30 samples in 40min), the simple methodology and apparatus, the ease of personnel training and the low cost of the reagents make this method a good alternative to the classical
radiometric method for evaluating serum L-carnitine in clinical laboratories without radioactive installations. 相似文献
Sardine (Sardina pilchardus) is a species that for its abundance assumes great importance in the Portuguese fishing sector. In order to contribute for a better utilisation of this species, the aim of this study was to investigate the effect of the pre‐treatment with soluble gas stabilisation (SGS) (100% CO2 at 2 bar, during 15 and 30 min) on the quality and shelf‐life of sardine fillets, packed in air (AP), vacuum (VP) and modified atmosphere (MAP: 5% O2/35% CO2/60% N2). During the chilled storage, the quality changes were evaluated by sensory evaluation, chemical and microbiological analysis. The total volatile basic nitrogen content remained almost constant, between 16 and 19 mg N/100 g muscle, during the storage period, for all samples. The TBARs values increased with storage time, for all batches and storage conditions. The application of SGS treatment to sardine fillets, resulted in a bacteriostatic effect, contributing to the improvement of the microbiological quality of fillets. Considering a sensory criteria, the shelf‐life of SGS pre‐treated sardine fillets was found to be 5 days in AP and MAP while in VP‐treated fillets a shelf‐life of 8 days was reported. At sensory rejection, sardine fillets presented a K‐value of 30% in AP and MAP batches and 40% in VP batch. 相似文献
A study of the dynamic-mechanical relaxation spectrum in a series of commercial high and low density polyethylenes (Dow Chemical), irradiated as well as unirradiated, and subjected to different annealing process, has been performed. The effect of 20-Mrad dose of irradiation on the chemical structure has been analyzed and an increase in the number of aldehyde, ketone, and transvinylene groups and a decrease in the number of vinyl and vinylidene groups has been observed. The dynamic-mechanical spectrum of irradiated and unirradiated high and low density polyethylenes contains the γII-, γI-, β-, αI-, αII-, and αIII- relaxations, in order of increasing temperature. It has been observed that γ-irradiation followed by annealing modified the intensity and the position of relaxations in these polyethylenes. 相似文献
A convenient ligand‐free catalytic system has been developed for the chemoselective cyclization reaction of various α‐allenol derivatives by palladium nanoparticles (PdNPs) in an aqueous reaction medium.
In the present work, we have analysed the yeast microbiota present in a manufacturing plant of candied fruits and nougats. Four yeasts species (Zygosaccharomyces bailii, Zygosaccharomyces rouxii, Sporobolomyces roseus, and Debaryomyces hansenii) and a filamentous fungi (Nectria mauriiticola) were identified according to restriction analysis of 5.8S-ITS rDNA. These identifications were subsequently confirmed by sequencing the D1/D2 domain of the 26S rRNA gene. Z. rouxii and Z. bailii were isolated at high frequency along the whole manufacturing process. Since food alteration by Z. bailii and Z. rouxii is the cause of important economic losses for the food industry, there is a need for differentiating yeasts at the strain level as an essential part of quality control programs in this industry. For this purpose, we have tested the performance of three molecular techniques (RFLP mtDNA, RAPD-PCR, and microsatellite with (GAC)5 and (GTG)5 primers) to differentiate strains belonging to these two Zygosaccharomyces species. Those techniques with the best discriminatory power were applied to differentiate Zygosaccharomyces species isolates. The results of this analysis indicate that one strain of Z. bailii and two strains of Z. rouxii were involved in the spoilage of candied fruits. Moreover, the Z. bailii strain was also present in the spoiled nougat, hence being responsible of this alteration. 相似文献