Corrosion inhibition by naturally occurringsubstances—I. The effect of Hibiscus subdariffa (karkade) extract on the dissolution of Al and Zn

The thermometric, the weight-loss and the galvanostatic polarization techniques wereused to establish the inhibition of the dissolution of Al and Zn in HCl and NaOH by different concentrations of aqueous extract of Hibiscus subdariffa (Karkade). The extent of corrosion inhibition as measured by the three techniques is comparable. The results indicated that the additive acts by way of adsorption on both cathodic and anodic corrosion areas. Curves representing the variation of the reaction number (R.N.), in thermometric experiments, and the decrease in weight as a function of the concentration of the additive, are invariably sigmoid in nature. When present in enough amounts, the additive decreases the dissolution rate by as much as 85 per cent of the value recorded in its absence.     

Polymer complexes. XXXI. Potentiometric and thermodynamic studies of 2‐acrylamido‐2‐amino‐3‐hydroxy pyridine and its metal complexes

Proton ligand dissociation and metal ligand stability constants of 2‐acrylamido‐2‐amino‐3‐hydroxy pyridine (AAHP) with some transition metal ions in 0.1 M KCl and 50% (v/v) ethanol–water mixture were calculated potentiometrically. In the presence of 2,2′‐azobisisobutyronitrile as initiator the proton‐polymeric ligand dissociation and metal polymeric ligand stability constants were also evaluated. The influence of temperature on the dissociation of AAHP and the stability of its metal complexes in the monomeric and polymeric forms were critically studied. On the basis of the thermodynamic functions, the dissociation process of AAHP was found nonspontaneous, endothermic, and entropically unfavorable, although the formed metal complexes showed spontaneous, endothermic, and entropically favorable behavior. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 2552–2557, 2000     

Etude structurale du graphiture I de cesium

The metallic yellow compound CsC₈ belongs to the 1st stage. The formula CsC₈ involves the occupation, in each interlayer, of only one in four possible sites the compact structure would entail the composition CsC₂ (Fig. 1).From single crystal photographs, one can determine the c parameter as three times the identity period along the c axis: Ic.The structural determination is based on separate study of each family: 00l (Table 1, Fig. 2), hk0 and hkl (Table 2, Fig. 3) and powder diagrams (Table 3, Fig. 4). The hk0 family allows to determine the symmetry of the unit cell and the parameter; the systematic extinctions of the hkl reflections permit to determine the space group.The stacking of the cesium atoms: three in the four possible sites involves a screw axis 6₂ or 6₄. The position of the carbon and cesium atoms takes into account all the symmetries of the cells corresponding to the space group P6₂22 (or P6₄22) (Fig. 5). The foregone extinctions of those unit cells are respected, in particular, the 201, 202, 204…, reflexions are missed (Fig. 6).The two domains built on αβγ and αγβ are actually symmetric to a mirror and not superimposable. It is shown on Fig. 8 that there are two enantiomorphous structures: the stacking αβγ corresponds to an obverse screw axis for the cesium atoms.The presence of 6 different stacking zones even in a simple crystal involves a disorder in the compound which can explain the variations of intensity of the reflexions hk0 and hkl.The CsC₈ compound is described by an hexagonal unit cell belonging to the space group P6₂22 (or P6₄22) with 24 carbon atoms in position $\text{12k (x =}\text{1}\text{6}$, $\text{y =}\text{1}\text{3}$, $\text{z =}\text{1}\text{3}$) and $\text{6i (x =}\text{1}\text{6}$, z = 0 and $\text{x =}\text{1}\text{3}$, z = 0) and the cesium atoms in 3b. The parameters are $\text{a = 4.945 ± 0.01}\text{A}\text{?}$ and $\text{c = 17.76 ± 0.03}\text{A}\text{?}$.Two unit cells are mentioned, according to the direction of the screw axis. In fact, there are 6 different possible unit cells.We tried to imagine the different possibilities of stacking for the cesium atoms between the graphite layers. From an ideal graphite plane, one places the 1st cesium layer in position α. The second metallic layer can be placed on the β, γ or δ sites. Let us imagine a part in β position, an other in γ and the last one on δ. In the same graphite matrix, one can define three distinct domains spotted by the successions αβ, αγ and αδ. While the filling of the last cesium layer, each domain is divided in two and it appears 6 zones, which correspond to the stacking αβγ, αβδ; αγβ, αγδ; αδβ, αδγ (Fig. 7).Each of these domains is defined by an hexagonal unit cell. They differ one from each other.     

Effect of some plating variables on the electrodeposition of Cu-Zn alloys from alkaline tartrate baths

The electrodeposition of copper, zinc and copper-zinc alloys from alkaline tartrate solutions has been investigated under different conditions of bath composition, added ammonium chloride, current density and temperature. A detailed study has been made of the effect of the variables on the cathode potentials and cathode efficiencies of copper, zinc and Cu-Zn alloys; the compositions of the alloys were determined. The results were consistent with the behaviour of a regular alloy plating system with zinc being the less noble metal.     

Exploration of mesoporous structure of tunisian raw and acid-leached phosphate ore particles

Rock phosphate fractions were examined for their porous structure by nitrogen adsorption. The pore size distribution and the shape of pores does not seem to depend on the particle size. The specific surface area values present two regions, one above and one below that of the particles with 125 μrn diameter. Particles of a given size were leached with dilute phosphoric acid (1.5 mass% P₂O₅) at 25°C. It was observed that there is a widening of the initial pores during leaching. The particles collected at the initial period of the reaction are pitted and those collected at the final period are disintegrated.     

On the electrochemical behaviour of the anodic oxide film on tungsten in HCOOH and CH3COOH solutions

The electrochemical behaviour of the anodic oxide film on tungsten during, or after, interruption of current flow was studied in HCOOH and CH₃COOH solutions by galvanostatic and capacitance techniques. The results show the conditions under which enhancement of film growth occurs as revealed from its formation and dissolution characteristics. The results also show the possibility of the electrochemical oxidation of formic acid by the thick oxide film on tungsten. The importance of this electrocatalytic process is the occurrence of the oxidation process without appreciable oxygen evolution. The galvanostatic oxidation of tungsten in HCOOH as a reducing agent can be considered as a novel method for the preparation of a class of oxides; oxidation with simultaneous partial reduction.     

Synthesis and reactions of 2-(p-chloroanilino)-5- (D-galacto-1,2,3,4,5-pentahydroxypentyl)-1,3,4-thiadiazole

Oxidative cyclization of D -galactose (p-chlorophenyl)thiosemicarbazone gave 2-(p-chloroanilino)-5-( D -galacto-1,2,3,4,5-pentahydroxypentyl)-1,3,4-thiadiazole ( 1 ), whose acetylation afforded 2-[N-acetyl-N-(p-chlorophenyl)]-amino-5-( D -galacto-1,2,3,4,5-pentacetoxypentyl)- 1,3,4-thiadiazole ( 3 ). Its periodate oxidation of the glycol groups gave 2-(p-chloroanilino)-1,3,4-thiadiazole-5-carboxaldehyde ( 4 ), which can be transformed into 1,2-[2-(p-chloroanilino)-1,3,4-thiadiazol-5-yl]-1-hydroxy-2-oxoethane. A number of hydrazones of the formyl thiadiazole was prepared and its reduction with sodium borohydride gave 2-(p-chloroanilino)-5-hydroxymethyl-1,3,4-thiadiazole ( 6 ), whose acetylation gave a mono-O-acetyl derivative ( 7 ). Oxidation of the formyl thiadiazole gave 2-(p-chloroanilino)-1,3,4-thiadiazole ( 9 ). The spectral data of the compounds were discussed.     

Crystallization of calcium sulphate hemihydrate in concentrated phosphoric acid solutions

We aim to show the existence of agglomeration by measuring and modelling secondary nucleation and crystal growth rates of calcium sulphate hemihydrate, CaSO₄-0.5 H₂O, in concentrated phosphoric acid solutions. Using a batch crystallizer we measured the evolution of the population density as a function of supersaturation, H₂SO₄ excess and stirring rates. All experiments were carried out at 90 °C in solutions at 40 wt.% of P₂O₅, simulating the usual conditions for crystallizing hemihydrate in the industrial processes of phosphoric acid production. Nucleation and growth rates were calculated from the population number densities, using the moments analysis method. A model is presented for describing the crystallization process of hemihydrate. It is shown that secondary nucleation and growth rates are quadratic functions of supersaturation. H₂SO₄ concentrations affect supersaturation but at the same supersaturation the growth rates are not significantly different. Nucleation is independent of the stirring rate, whereas growth rates are slightly affected for stirring rates up to 500 rpm. Taking agglomeration into account, the moments method fits very well the experimental data.     

Synthesis and evaluation of the inhibitor effect of a new class of triazole compounds

In this work, a new class of triazole molecules, containing heteroatoms such as nitrogen and sulphur, is prepared. The effect of these molecules on the corrosion behaviour of iron was investigated. Electrochemical studies were performed in aerated chloride acid solution (1 M) by potentiodynamic polarisation curves. Surfaces were characterised by scanning electron microscopy.

The recorded electrochemical data showed that the corrosion resistance was greatly enhanced in the presence of inhibitor. The maximal protection efficiency exceeded 94%. The corrosion protection could be explained by the adsorption of inhibitor through the S- or N-atom and formation of a protective layer attached to the metal surface.     

Solvent-free glycerolysis catalyzed by acetone powder of Nigella sativa seed lipase

The solvent-free glycerolysis of used sunflower oil catalyzed by acetone powder of Nigella sativa seeds was investigated. The highest partial acylglycerols yield was obtained at 60°C. The glycerolysis reactions, conducted at molar ratios of 1:1, 2:1, and 3:1 of oil to glycerol keeping the acetone powder content at 30% based on oil weight and the temperature at 60°C, approached equilibrium after 2 h. The highest partial acylglycerol content of the products was 66% (1:1 molar ratio) and 60% (2:1 molar ratio).