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61.
佛手凉果是具有功能特性的岭南特色凉果品种,探究佛手凉果制作过程中功能性成分及其体外抗氧化活性变化规律,可为佛手凉果产业工艺优化与改良提供依据。结果表明,加工提高了佛手中总酸、多糖、黄酮和膳食纤维含量,导致多酚含量下降。制作过程中,1,1-二苯基-2-三硝基苯(DPPH)自由基、2,20 -联氮- 2 -三硝基苯肼(ABTS)自由基清除能力和铁离子还原抗氧化能力(Ferric Reducing Antioxidant Power, FRAP)呈现先下降后上升的趋势,效果分别是新鲜佛手的1.35倍、1.57倍和2.16倍。总黄酮与FRAP之间呈现极显著相关性(P<0.01);与DPPH、ABTS呈显著相关性(P<0.05);有机酸、总多糖分别与ABTS和FRAP之间相关性(P<0.05)。为此,在佛手凉果的制作过程中,糖制和干燥工艺对功能性成分的转化与浓缩起关键作用,可作为工艺优化的重点。 相似文献
62.
Chuanming Tian Bin Li Yichuan Rui Hao Xiong Yu Zhao Xuefei Han Xinliang Zhou Yu Qiu Wei An Kerui Li Chengyi Hou Yaogang Li Hongzhi Wang Qinghong Zhang 《Advanced functional materials》2023,33(41):2302270
Despite the outstanding power conversion efficiency (PCE) of perovskite solar cells (PSCs) achieved over the years, unsatisfactory stability and lead toxicity remain obstacles that limit their competitiveness and large-scale practical deployment. In this study, in situ polymerizing internal encapsulation (IPIE) is developed as a holistic approach to overcome these challenges. The uniform polymer internal package layer constructed by thermally triggered cross-linkable monomers not only solidifies the ionic perovskite crystalline by strong electron-withdrawing/donating chemical sites, but also acts as a water penetration and ion migration barrier to prolong shelf life under harsh environments. The optimized MAPbI3 and FAPbI3 devices with IPIE treatment yield impressive efficiencies of 22.29% and 24.12%, respectively, accompanied by remarkably enhanced environmental and mechanical stabilities. In addition, toxic water-soluble lead leakage is minimized by the synergetic effect of the physical encapsulation wall and chemical chelation conferred by the IPIE. Hence, this strategy provides a feasible route for preparing efficient, stable, and eco-friendly PSCs. 相似文献
63.
Thanh Hai Nguyen Phan Khanh Linh Tran Van An Dinh Duy Thanh Tran Nam Hoon Kim Joong Hee Lee 《Advanced functional materials》2023,33(7):2210101
Development of multifunctional electrocatalysts with high efficiency and stability is of great interest in recent energy conversion technologies. Herein, a novel heteroelectrocatalyst of molecular iron complex (FeMC)-carbide MXene (Mo2TiC2Tx) uniformly embedded in a 3D graphene-based hierarchical network (GrH) is rationally designed. The coexistence of FeMC and MXene with their unique interactions triggers optimum electronic properties, rich multiple active sites, and favorite free adsorption energy for excellent trifunctional catalytic activities. Meanwhile, the highly porous GrH effectively promotes a multichannel architecture for charge transfer and gas/ion diffusion to improve stability. Therefore, the FeMC–MXene/GrH results in superb performances towards oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) in alkaline medium. The practical tests indicate that Zn/Al–air batteries derived from FeMC–MXene/GrH cathodic electrodes produce high power densities of 165.6 and 172.7 mW cm−2, respectively. Impressively, the liquid-state Zn–air battery delivers excellent cycling stability of over 1100 h. In addition, the alkaline water electrolyzer induces a low cell voltage of 1.55 V at 10 mA cm−2 and 1.86 V at 0.4 A cm−2 in 30 wt.% KOH at 80 °C, surpassing recent reports. The achievements suggest an exciting multifunctional electrocatalyst for electrochemical energy applications. 相似文献
64.
Mobile Networks and Applications - Artificial fish swarm algorithm (AFS) is used in the field of function optimization problems widely. The traditional AFS algorithm has some problems such as long... 相似文献
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Multicolor Photo‐Crosslinkable AIEgens toward Compact Nanodots for Subcellular Imaging and STED Nanoscopy 下载免费PDF全文
Xiaofeng Fang Xuanze Chen Rongqin Li Zhihe Liu Haobin Chen Zezhou Sun Bo Ju Yifei Liu Sean Xiao‐An Zhang Dan Ding Yujie Sun Changfeng Wu 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(41)
Aggregation induced emission (AIE) has attracted considerable interest for the development of fluorescence probes. However, controlling the bioconjugation and cellular labeling of AIE dots is a challenging problem. Here, this study reports a general approach for preparing small and bioconjugated AIE dots for specific labeling of cellular targets. The strategy is based on the synthesis of oxetane‐substituted AIEgens to generate compact and ultrastable AIE dots via photo‐crosslinking. A small amount of polymer enriched with oxetane groups is cocondensed with most of the AIEgens to functionalize the nanodot surface for subsequent streptavidin bioconjugation. Due to their small sizes, good stability, and surface functionalization, the cell‐surface markers and subcellular structures are specifically labeled by the AIE dot bioconjugates. Remarkably, stimulated emission depletion imaging with AIE dots is achieved for the first time, and the spatial resolution is significantly enhanced to ≈95 nm. This study provides a general approach for small functional molecules for preparing small sized and ultrastable nanodots. 相似文献
68.
Mesoporous NiS2 Nanospheres Anode with Pseudocapacitance for High‐Rate and Long‐Life Sodium‐Ion Battery 下载免费PDF全文
Ruimin Sun Sijie Liu Qiulong Wei Jinzhi Sheng Shaohua Zhu Qinyou An Liqiang Mai 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(39)
It is of great importance to exploit electrode materials for sodium‐ion batteries (SIBs) with low cost, long life, and high‐rate capability. However, achieving quick charge and high power density is still a major challenge for most SIBs electrodes because of the sluggish sodiation kinetics. Herein, uniform and mesoporous NiS2 nanospheres are synthesized via a facile one‐step polyvinylpyrrolidone assisted method. By controlling the voltage window, the mesoporous NiS2 nanospheres present excellent electrochemical performance in SIBs. It delivers a high reversible specific capacity of 692 mA h g?1. The NiS2 anode also exhibits excellent high‐rate capability (253 mA h g?1 at 5 A g?1) and long‐term cycling performance (319 mA h g?1 capacity remained even after 1000 cycles at 0.5 A g?1). A dominant pseudocapacitance contribution is identified and verified by kinetics analysis. In addition, the amorphization and conversion reactions during the electrochemical process of the mesoporous NiS2 nanospheres is also investigated by in situ X‐ray diffraction. The impressive electrochemical performance reveals that the NiS2 offers great potential toward the development of next generation large scale energy storage. 相似文献
69.