CTAB-caped Cu nanoparticles doped on zeolitic imidazolate framework-ZIF-67 as bifunctional catalysts for oxygen-reduction and evolution reactions in alkaline media

Journal of Porous Materials - In order to facilitate the large-scale applications of rechargeable Zn–air batteries, non-noble-metal based materials with high activity for oxygen reduction...     

On the flash sintering behavior of Li:ZnO—Evidence of electrode asymmetry driven by electrochemical reactions

The synthesis, subsequent flash sintering (FS) characteristics and microstructures of pure and Li-incorporated ZnO powders are reported. At low concentrations, Li is a substitutional occupant in ZnO but becomes an amphoteric dopant (substitutional and interstitial occupant) at higher concentrations inferred from a contraction reversal of the unit cell volume. Increasing Li reduces the average flash temperature of ZnO modestly by 15°C, and a doubling of the linear shrinkage. A discernible color smear (yellow–white–dark) stretching from the anode to cathode imputable to strong electromigration is also observed. Microanalyses of the electrode regions establish clear evidence of electrochemical (EC) lithiation into ZnO and the formation of Li–Zn compounds not observed in conventional sintering (CS). Interestingly, in contrast to CS, the addition of Li enhances coarsening during FS, suggestive of a dissolution–reprecipitation process concurrent with the EC lithiation process. Evidence for considerable (local) yet tangible temperature, chemical and microstructural asymmetry among electrodes driven by EC reactions is presented. Probable mechanisms, leading to these observations, are discussed.     

Design of Cationic Lipids with Acetal Linkers: Conformational Preferences,Hydrolytic Stability,and High Drug-Loading Abilities

Lipids are key constituents of numerous biomedical drug delivery technologies. Here, we present the design, synthesis and biophysical characterizations of a library of cationic lipids containing an acetal residue in their linker region. These cationic acetal lipids (CALs) were conveniently prepared through a trans-acetalization protocol from commercially available precursors. NMR studies highlighted the conformational rigidity at the acetal residue and the high hydrolytic stability of these CALs. Fluorescence anisotropy studies revealed that the CAL with a pyridinium headgroup (CAL1) formed highly cohesive vesicular aggregates in water. These structural and self-assembly features of the CAL1 allowed up to 196 % w/w loading of curcumin (Cur) as a representative hydrophobic drug. A reconstitutable formulation of Cur was obtained as a result, which could deliver the drug inside mammalian cells with very high efficiency. The hemocompatibility and cytocompatibility of CAL1 was significantly enhanced by creating a coating of polydopamine (PDA) onto its vesicular assemblies to produce hybrid lipid-polymer nanocapsules. This work demonstrates rapid access to the useful synthetic lipid formulations with high potential in drug and gene delivery applications.     

How to Select Phase Change Materials for Tuning Condensation and Frosting? (Adv. Funct. Mater. 3/2023)

Synthetic surfaces engineered to regulate phase transitions of matter and exercise control over its undesired accrual (liquid or solid) play a pivotal role in diverse industrial applications. Over the years, the design of repellant surfaces has transitioned from solely modifying the surface texture and chemistry to identifying novel material systems. In this study, selection criteria are established to identify bio-friendly phase change materials (PCMs) from an extensive library of vegetable-based/organic/essential oils that can thermally respond by harnessing the latent heat released during condensation and thereby delaying ice/frost formation in the very frigid ambient that is detrimental to its functionality. Concurrently, a comprehensive investigation is conducted to elucidate the relation between microscale heat transport phenomena during condensation and the resulting macroscopic effects (e.g., delayed droplet freezing) on various solidified PCMs as a function of their inherent thermo-mechanical properties. In addition, to freeze protection, many properties that are responsive to the thermal reflex of the surface, such as the ability to dynamically tune optical transparency, moisture harvesting, ice shedding, and quick in-field repairability, are achievable, resulting in the development of protective coatings capable of spanning a wide range of functionalities and thereby having a distinctive edge over conventional solutions.     

Integration of textual cues for fine-grained image captioning using deep CNN and LSTM

Neural Computing and Applications - The automatic narration of a natural scene is an important trait in artificial intelligence that unites computer vision and natural language processing. Caption...     

Condition monitoring of steam turbine-generator through contamination analysis of used lubricating oil

The objective of this paper is to present a systematic analysis of wear particles contained in used lubricant of steam turbine-generator of a thermal power station. The turbogenerator was condition-monitored over a period of two years through wear debris and particulate contamination analysis of the oil. Various sophisticated techniques such as automatic particle counter, ferrography, inductively coupled plasma atomic emission spectrometry (ICPAES), scanning electron microscopy and energy dispersive X-ray analysis (SEM/EDAX) have been employed to extract the relevant information about the health of the machine. Eventually, a correlation of different techniques of wear debris monitoring on the basis of current investigation ascertains the significance of the collective approach of various techniques to avoid catastrophic breakdowns and expensive component replacements.     

Surface modification of low density polyethylene in a fluorine gas plasma

Low density polyethylene was fluorinated in a glow discharge generated from a dilute mixture of fluorine in helium. The effects of pressure, flow rate, power and time of treatment have been examined. The fluorinated polymers were characterized using e.s.c.a. to identify the species present in the surface layer and to estimate the depth of fluorination. For typical plasma treatment of polyethylene films the fluorination depth was about 40 Å; a competition of ablation and ion-assisted etching processes with chemical reaction was observed. The depth of fluorination was increased to values above 60 Å by carrying out the reaction within a metal screen. The presence of the screen also reduced the reaction rate by about a factor of two. Other features of the treated polyethylene were determined by contact angle measurements, surface infra-red spectroscopy, solvent sorption and differential scanning calorimetry. Some early results of treatment of polyethylene powders in a fluidized bed reactor are also presented.     

Ideality and noise figure characteristics of r.f. sputtered millimetre GaAs diodes

Refractory Schottky barriers have been incorporated in millimetre GaAs mixer diodes to improve r.f. performance and burnout resistance. It is shown that low power r.f. sputter deposition of TiW and Ti-Mo refractories results in degradation of noise temperature ratio and to a first approximation does not affect d.c. parameters, especially the ideality factor.     

Modeling Errors in Sampling Inspection: Effect of Degraded Performance

Studies have shown that inspection is not error-free and is systematically influenced by such factors as time available, the payoffs, complexity of the task, the decision goal, defect rate, and so on. This study shows how models of decision-making can be used to obtain better designs of sampling plans in the presence of human inspection error. This study also outlines a methodology to develop sampling plans under different levels of degraded human performance. Results revealed that sampling plans are sensitive to decision goals and the level of degradation.