Syngas production from H2O and CO2 over Zn particles in a packed‐bed reactor

The solar thermochemical production of H₂ and CO (syngas) from H₂O and CO₂ is examined via a two‐step cycle based on Zn/ZnO redox reactions. The first, endothermic step is the thermolysis of the ZnO driven by concentrated solar energy. The second, nonsolar step is the exothermic reaction of Zn with a mixture of H₂O and CO₂ yielding syngas and ZnO; the latter is recycled to the first step. A series of experimental runs of the second step was carried out in a packed‐bed reactor where ZnO particles provided an effective inert support for preventing sintering and enabling simple and complete recycling to the first, solar step. Experimentation was performed for Zn mass fractions in the range of 33–67 wt % Zn‐ZnO, and inlet gas concentrations in the range 0–75% H₂O–CO₂, yielding molar Zn‐to‐ZnO conversions up to 91%. A 25 wt % Zn‐ZnO sample mixture produced from the solar thermolysis of ZnO was tested in the same reactor setup and exhibited high reactivity and conversions up to 96%. © 2011 American Institute of Chemical Engineers AIChE J, 2012     

Laser melting treatment by overlapping passes of preheated nickel electrodeposited coatings on Al−Si alloy

Microstructure improvements of a nickel electrodeposited Al−Si alloy were studied after high-power laser melting treatment through a single pass or partially overlapping successive adjacent passes. In some cases, laser melting treatment was preceded by a 5-hour heating of the specimens at 500°C in argon atmosphere furnace. Microstructure observations and microhardness measurements were carried out on the specimens before and after laser melting treatment with and without preheating. Best results concerning microhardness, microstructural homogeneity, and porosity elimination, as well as adhesion of the nickel coating on the Al−Si alloy, were achieved when the specimens were first subjected to heating at 500°C in an argon atmosphere furnace for 5 hours and then submitted to a laser melting treatment through successive adjacent laser passes with an overlapping rate of 70 pct. Microstructure studies were carried out employing X-ray diffraction analysis (XRD) and energy-dispersive spectrometry (EDS). AlNi and Al₃Ni phases were detected in the diffusion area which resulted from the 5-hour heating. AlNi, Al₃Ni, and Al₃Ni₂ phases were identified in the laser melted zones (LMZs). Each one of the above phase was found to be the main phase under different conditions.     

Laser-induced heterometallic phase deposition from solutions of supramolecular complexes

Heterometallic (Au–Cu) phase precipitation on the surface of soda-lime glass as a result of laser-induced chemical liquid phase deposition (LCLD) is demonstrated for the first time. The precipitation of heterometallic structures was carried out under Ar⁺ laser irradiation from the solutions of supramolecular complexes. Energy dispersive X-ray (EDX) analysis showed that the deposits consist of both Au and Cu. Morphology of the deposited structures was found to be dependent on the used solvents: delocalized sparse surface structures in the case of the dichloromethane solution, close packed nanoparticles for the dimethyl formamide and homogeneous phase with nano-pores for the acetone solution. In accordance to the SEM photos and scan EDX analysis the homogeneous heterometallic phase with fixed Au/Cu ratio was achieved for the acetone solution of supramolecular complex. The observed formation of the heterometallic phase was explained by the laser-initiated intramolecular reduction process of the supramolecular metal core.     

Characterization of the Impact of Hardware Islands on OLTP

Modern hardware is abundantly parallel and increasingly heterogeneous. The numerous processing cores have non-uniform access latencies to the main memory and processor caches, which causes variability in the communication costs. Unfortunately, database systems mostly assume that all processing cores are the same and that microarchitecture differences are not significant enough to appear in critical database execution paths. As we demonstrate in this paper, however, non-uniform core topology does appear in the critical path and conventional database architectures achieve suboptimal and even worse, unpredictable performance. We perform a detailed performance analysis of OLTP deployments in servers with multiple cores per CPU (multicore) and multiple CPUs per server (multisocket). We compare different database deployment strategies where we vary the number and size of independent database instances running on a single server, from a single shared-everything instance to fine-grained shared-nothing configurations. We quantify the impact of non-uniform hardware on various deployments by (a) examining how efficiently each deployment uses the available hardware resources and (b) measuring the impact of distributed transactions and skewed requests on different workloads. We show that no strategy is optimal for all cases and that the best choice depends on the combination of hardware topology and workload characteristics. Finally, we argue that transaction processing systems must be aware of the hardware topology in order to achieve predictably high performance.     

A study on Dual-Scale data charts

We present the results of a user study that compares different ways of representing Dual-Scale data charts. Dual-Scale charts incorporate two different data resolutions into one chart in order to emphasize data in regions of interest or to enable the comparison of data from distant regions. While some design guidelines exist for these types of charts, there is currently little empirical evidence on which to base their design. We fill this gap by discussing the design space of Dual-Scale cartesian-coordinate charts and by experimentally comparing the performance of different chart types with respect to elementary graphical perception tasks such as comparing lengths and distances. Our study suggests that cut-out charts which include collocated full context and focus are the best alternative, and that superimposed charts in which focus and context overlap on top of each other should be avoided.     

Contextualization as an independent abstraction mechanism for conceptual modeling

The notion of context appears in computer science, as well as in several other disciplines, in various forms. In this paper, we present a general framework for representing the notion of context in information modeling. First, we define a context as a set of objects, within which each object has a set of names and possibly a reference: the reference of the object is another context which “hides” detailed information about the object. Then, we introduce the possibility of structuring the contents of a context through the traditional abstraction mechanisms, i.e., classification, generalization, and attribution. We show that, depending on the application, our notion of context can be used as an independent abstraction mechanism, either in an alternative or a complementary capacity with respect to the traditional abstraction mechanisms. We also study the interactions between contextualization and the traditional abstraction mechanisms, as well as the constraints that govern such interactions. Finally, we present a theory for contextualized information bases. The theory includes a set of validity constraints, a model theory, as well as a set of sound and complete inference rules. We show that our core theory can be easily extended to support embedding of particular information models in our contextualization framework.     

Developmental phases in self-regulation: Shifting from process goals to outcome goals.

The effects of goal setting and self-monitoring during self-regulated practice on the acquisition of a complex motoric skill were studied with 90 high school girls. It was hypothesized that girls who shifted goals developmentally from process to outcome goals would surpass classmates who adhered to only process goals who, in turn, would exceed classmates who used only outcome goals in posttest dart-throwing skill, self-reactions, self-efficacy perceptions, and intrinsic interest in the game. Support for all hypotheses derived from the developmental model was found. The girls' self-reactions to dart-throwing outcomes and self-efficacy perceptions about dart skill were highly correlated with their intrinsic interest in the game. It was also found that self-recording, a formal form of self-monitoring, enhanced dart-throwing skill, self-efficacy, and self-reaction beliefs. (PsycINFO Database Record (c) 2010 APA, all rights reserved)