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81.
Chao-Hong Wang Sinn-Wen Chen Chia-Hua Chang Jen-Chin Wu 《Metallurgical and Materials Transactions A》2003,34(2):199-209
A series of Al-Cu-Ni alloys of various compositions were made and annealed at 800 °C. The equilibrium phases were studied
by metallography, X-ray diffraction (XRD) analysis, and electron probe microanalysis. The isothermal section of the ternary
Al-Cu-Ni system at 800 °C was then determined based on these experimental results and the available phase relationship knowledge
of the three constituent binary systems. No ternary compound was found. All three phases, AlNi3, AlNi, and Al3Ni2, have very high ternary solubility, especially the AlNi phase, which almost reaches the binary Al-Cu side. However, no continuous
solid solution was formed between the AlNi phase and any of the binary Al-Cu phases. Interfacial reactions of Al/Ni, Al/Cu,
Al-Cu/Ni, and Al-Ni/Cu at 800 °C were investigated by using reaction couple techniques. The results showed that Al3Ni and Al3Ni2 phases were formed in the Al/Ni couples; β-AlCu4, γ
1-Al4Cu9, and ɛ
2-Al2Cu3 phases were formed in the Al/Cu couples. As for the results in the Al-2 at. pct Ni/Cu, Al-5 at. pct Ni/Cu, and Al-2 at. pct
Cu/Ni, Al-4.5 at. pct Cu/Ni, and Al-6 at. pct Cu/Ni were similar to those in the binary Al/Cu and Al/Ni couples, respectively.
A different reaction path was found in the Al-7.5 at. pct Cu/Ni couples, and an AlNi solid solution layer was formed instead
of the Al3Ni and Al3Ni2 phases. 相似文献
82.
83.
A three-phase model for mixed columnar-equiaxed solidification 总被引:1,自引:0,他引:1
A three-phase model for mixed columnar-equiaxed solidification is presented in this article. The three phases are the parent
melt as the primary phase, as well as the solidifying columnar dendrites and globular equiaxed grains as two different secondary
phases. With an Eulerian approach, the three phases are considered as spatially coupled and interpenetrating continua. The
conservation equations of mass, momentum, species, and enthalpy are solved for all three phases. An additional conservation
equation for the number density of the equiaxed grains is defined and solved. Nucleation of the equiaxed grains, diffusion-controlled
growth of both columnar and equiaxed phases, interphase exchanges, and interactions such as mass transfer during solidification,
drag force, solute partitioning at the liquid/solid interface, and release of latent heat are taken into account. Binary steel
ingots (Fe-0.34 wt pct C) with two-dimensional (2-D) axis symmetrical and three-dimensional (3-D) geometries as a benchmark
were simulated. It is demonstrated that the model can be used to simulate the mixed columnar-equiaxed solidification, including
melt convection and grain sedimentation, macrosegregation, columnar-to-equiaxed-transition (CET), and macrostructure distribution.
The model was evaluated by comparing it to classical analytical models based on limited one-dimensional (1-D) cases. Satisfactory
results were obtained. It is also shown that in order to apply this model for industrial castings, further improvements are
still necessary concerning some details. 相似文献
84.
Jon T. Carter Paul E. Krajewski Ravi Verma 《JOM Journal of the Minerals, Metals and Materials Society》2008,60(11):77-81
The hot blow forming of magnesium sheet offers significant opportunity for forming complex, lightweight parts for automotive
applications. This paper characterizes the elevated-temperature formability of AZ31 magnesium sheet materials and the effect
of processing conditions on the performance of these materials. In addition, magnesium sheet application development at General
Motors Corporation is reviewed. 相似文献
85.
Toshihiko Hoshide Junpei Fujita 《Journal of Materials Engineering and Performance》2008,17(5):627-632
Strength of ground ceramics may be affected by residual stress as well as surface flaws induced by grinding. Strength prediction
for ground ceramics is convenient for mechanical design of ceramic components. In this article, a numerical procedure based
on fracture mechanics was proposed to estimate strength distribution of ground ceramics by considering grinding-induced residual
stress. Bending strength and residual stress of ground ceramics were measured for three grinding-conditions. By comparison
of simulated results with experimental ones, it was revealed that strength characteristics in experiments were well simulated
by using the proposed procedure. 相似文献
86.
87.
Zirconium(IV) tungstoiodophosphate has been synthesized under a variety of conditions. The most chemically and thermally stable
sample is prepared by adding a mixture of aqueous solutions of 0·5 mol L−1 sodium tungstate, potassium iodate and 1 mol L−1 orthophosphoric acid to aqueous solution of 0·1 mol L−1 zirconium(IV) oxychloride. Its ion exchange capacity for Na+ and K+ was found to be 2·20 and 2·35 meq g−1 dry exchanger, respectively. The material has been characterized on the basis of chemical composition, pH titration, Fourier
transform infrared spectroscopy (FTIR) and thermogravimetric analysis. The effect on the exchange capacity of drying the exchanger
at different temperatures has been studied. The analytical importance of the material has been established by quantitative
separation of Pb2+ from other metal ions. 相似文献
88.
Jonathan P. Belnoue Giang D. Nguyen Alexander M. Korsunsky 《International Journal of Fracture》2007,144(1):53-60
This paper presents a new 1-D non-local damage-plasticity deformation model for ductile materials. It uses the thermodynamic
framework described in Houlsby and Puzrin (2000) and holds, nevertheless, some similarities with Lemaitre’s (1971) approach.
A 1D finite element (FE) model of a bar fixed at one end and loaded in tension at the other end is introduced. This simple
model demonstrates how the approach can be implemented within the finite element framework, and that it is capable of capturing
both the pre-peak hardening and post-peak softening (generally responsible for models instability) due to damage-induced stiffness
and strength reduction characteristic of ductile materials. It is also shown that the approach has further advantages of achieving
some degree of mesh independence, and of being able to capture deformation size effects. Finally, it is illustrated how the
model permits the calculation of essential work of rupture (EWR), i.e. the specific energy per unit cross-sectional area that
is needed to cause tensile failure of a specimen. 相似文献
89.
Yewang Su Baohua Ji Yonggang Huang Kehchih Hwang 《Journal of Materials Science》2007,42(21):8885-8893
Wet adhesion is widely adopted in biological adhesion systems in nature. Wet adhesion is studied in this paper with the focus
on the effect of different contact shapes (flat, concave, convex, and ring-like) on the adhesion force. The evolution of the
liquid bridge between a fiber tip and substrate during the detaching process shows two transition points. The first transition
from the radius-controlled to the contact-angle controlled process is critical to influence the strength and robustness of
adhesion. We show that a concave shape is more effective than a flat one, while a convex shape has no advantage. A ring-like
contact shape has advantages in a hydrophobic environment and on a rough surface. 相似文献
90.
Jinting Jiu Seiji Isoda Motonari Adachi Hao Wang 《Journal of Materials Science: Materials in Electronics》2007,18(6):593-597
Nanocrystalline TiO2 with 3–10 nm in diameter was prepared with a surfactant-template method. Dye-sensitized solar cells were assembled using
the prepared nanocrystalline TiO2 with large surface area and high crystallinity, which achieved significant higher Jsc when compared to cells fabricated with
bigger particles of 25 nm in diameter. In the cells with nanocrystalline TiO2, the sintering temperature drastically affected the conversion performance of the cells. 相似文献