Action of chelators on solid iron in phosphate-containing aqueous solutions

To study the effect of strong iron-ligands on steel corrosion, mild steel electrodes were immersed in solutions containing 20 mM phosphate buffer (pH=7.2) and between 0.01 mM and 1 M of either the iron(II)-chelators 2,2^′-bipyridine or FerroZine, or the iron(III)-chelators citrate or acetylacetonate. Resulting surface reactions were investigated by quantifying the electrochemical potential (E), the electrochemical polarization resistance (R_p), the corrosion current (I_corr) and the release of iron into solution. The surface was further analyzed by scanning electron microscopy (SEM/SEM-EDAX) and atomic force microscopy. Concentrations of 0.1 mM of any of the chelators led to slight, temporary changes in E, I_corr and R_p. Concentrations of 10 mM resulted in characteristic changes of E, which were the same for all chelators and in the precipitation of FePO₄ in the case of citrate and acetylacetonate, or vivianite [Fe₃(PO₄)₂ · 8H₂O] in the case of bipyridine and FerroZine. Concentrations of 1 mM of both iron(III)-chelators led to a temporary drop of E similar to that found with 0.1 mM chelator. With iron(II)-chelators, E dropped to about −500 mV before oscillating for several days. The amplitudes of the oscillations were up to 200 mV with periods of 30 and 20-25 min for bipyridine and FerroZine, respectively.     

In-situ-Messung der Stickoxidkonzentration in turbulenten Diffusionsflammen

Zusammenfassung Die laserspektroskopischen Me?methoden laserinduzierte Fluoreszenz und spontane Ramanspektroskopie werden eingesetzt zur Messung der Konzentrationen von Stickoxid, Hydroxyl sowie der chemischen Hauptkomponenten und der Temperatur. Betrachtet wird die thermische Umsetzung von Wasserstoff mit Luftsauerstoff. Es wird die experimentelle Vorgehensweise und Problematik dargestellt. Ebenso wird der Weg der Modellierung und Berechnung turbulenter Verbrennungsvorg?nge am konkreten Beispiel skizziert. Die Annahme chemischen Gleichgewichts stellt sich als ungenügend in der Berechnung der Stickoxid- und Hydroxylkonzentrationen heraus. Eine deutlich bessere Vorhersage wird durch Einführen einer Reaktionsfortschrittsvariablen für das chemische Modell erreicht.     

Biapenem versus imipenem/cilastatin in the treatment of complicated intra-abdominal infections: report from a Swedish Study Group

The objective of this study is to describe usual medical management and costs associated with recurrent respiratory infections in subjects with chronic obstructive bronchitis in France. A prospective survey was performed in Autumn 1994 on a national sample of private practice pulmonologists (N = 71). Two hundred forty-four patients, presenting at least one infection of the lower respiratory tract, were included. Bronchitis was the most frequent acute exacerbation observed (94%). Pneumonia concerned 9% of the patients. Biological tests, X-rays and pulmonary function tests were prescribed for, respectively, 59, 65 and 45% of the patients. Following the visit, 15 patients were hospitalized (6%). The direct medical cost per acute exacerbation was estimated 3,289 francs (1994 value) of which 60% were hospital-related. An average 10.4 day sick-leave was prescribed to 21% of patients in employment. For those patients, this sick-leave was associated to an extra-cost of 1,264-1,876 francs for Social Security and of 0-2,553 francs out of pocket per episode varying according to their Benefit Regimen.     

Space-time finite elements for a simplified thermo-metallurgical problem relevant to casting

The non-linear thermo-metallurgical problem, relevant for the cooling of a molten metal including the macro-segregation that occurs during the cooling process, is studied here. Due to the strong non-linearities involved in phase transformations, it is necessary to use a fine resolution in space-time in a finite element approximation in order to meet accuracy requirements. We derive space-time FE-methods based on the discontinuous and continuous Galerkin method in time for the energy equation. This formulation integrates the stored energy exactly for a given heat flux. When macro-segregation is incorporated into the model, the problem can be formulated in such a way that the phase-transition drives a flow of species. In addition, diffusion is possible throughout the domain. The model can be further rewritten using a potential approach. By this approach for modelling macro-segregation, we are able to obtain discretizations that guarantee that the balance equations are satisfied, and it is possible to solve the phase-transition problem either as a field problem or as a local problem (defined by a local evolution rule).     

Heat transport and void fraction in granulated debris

The paper discusses the boiling heat transfer from a porous bed with internal heat sources and refers to the configuration in a nuclear reactor after a partial core melt. The flow of coolant, the temperature and the local liquid/vapor distribution were investigated in a two-dimensional configuration. Experiments were conducted using monodisperse beds as well as a mixture of two different particle sizes with a total porosity below 20%. In some tests the bed was supported by a shell of porous material to create a gap along the bottom of the test container. Water was used for tests up to 9% of the critical pressure, while other tests were made with R134a up to 44% of the critical pressure. The maximum heating rate realized inductively was 730 kW/m². The experiments have been compared to analytical results with a one-dimensional approach.It is shown that in contrary to the situation in small cylindrical configurations the heat transfer was increased by large buoyancy driven convective flows. If there was a gap along the container bottom an additional flow of liquid improved the coolability of the bottom region even if the upper part of the particle bed was already overheated. In case of high density ratios (water at low pressure), the measurements indicated a strong enhancement of the coolant flow above a certain minimum heating rate resulting in decreasing vapor fraction values which were nearly independent of the system pressure. This was assumed to be caused by the appearance of vertical channels through which the vapor could flow through the particle bed.