Dry Processing and Recycling of Thick Nacre–Mimetic Nanocomposites

Bioinspired nanocomposites with high levels of reinforcement hold great promise for future, green lightweight, and functional engineering materials, but they suffer from slow, tedious, and nonscalable preparation routes, that typically only lead to very thin films. A rapid and facile dry powder processing technique is introduced to generate bioinspired nanocomposite materials at high fractions of reinforcements (50 wt%) and with millimeter scale thickness. The process uses powder drying of vitrimer-coated nanoplatelets (nanoclay and MXene) from aqueous solution and subsequent hot-pressing. As a method of choice in industrial lightweight composite materials engineering, hot-pressing underscores a high potential to translate this approach to actual products. The use of the vitrimer chemistry with temperature-activated bond shuffling is important to facilitate smooth integration into the nanocomposite design, leading to layered nacre-inspired nanocomposites with nanoscale hard/soft order traced by X-ray diffraction and excellent mechanical properties investigated using flexural tests. Recycling by grinding and hot-pressing is possible without property loss. The compatibility with existing composite processing techniques, scalable thickness and dimensions, and recyclability open considerable opportunities for translating bioinspired nanocomposites to real-life applications.     

Toroidal Protein Adaptor Assembles Ferrimagnetic Nanoparticle Fibers with Constructive Magnetic Coupling

Inspired by nature, the synthesis of biohybrid nanocomposites containing inorganic nanoparticles (NPs) and biopolymers such as DNA and peptides as templates offers great potential for a wide range of applications. Using selective recognition schemes of 3D protein spaces for the assembly of magnetic nanocrystals is a challenge with great promise in the field of biomedicine and magnetic data storage. Here we apply the toroidal protein Hcp1 as an interparticle connector for the directed molecular assembly and ferrimagnetic coupling of biohybrid cobalt ferrite NP wires. The resulting biohybrid NP composites show bundles of nanofibers ranging from nano‐ to the microscale in length verified by TEM, EDX analysis and focused ion beam cut. Their magnetic characterization reveals an increase of the coercive field (+12%) reaching values of high‐end Nd₂Fe₁₄B bulk magnets, enhanced saturation (+28%) and remanence magnetization (+38%) at 2 K compared to NPs lacking the protein connector. Thus, the combination of the nanoscale alignment of magnetic NPs with the molecular precision of the protein connectors leads to constructive addition of the magnetization reversal energy. This approach can be used to control magnetic properties for the design of materials with enhanced coercivity applicable for magnetic data storage, hyperthermia and theranostics.     

Light‐Fueled,Spatiotemporal Modulation of Mechanical Properties and Rapid Self‐Healing of Graphene‐Doped Supramolecular Elastomers

Gaining spatially resolved control over the mechanical properties of materials in a remote, programmable, and fast‐responding way is a great challenge toward the design of adaptive structural and functional materials. Reversible, temperature‐sensitive systems, such as polymers equipped with supramolecular units, are a good model system to gain detailed information and target large‐scale property changes by exploiting reversible crosslinking scenarios. Here, it is demonstrated that coassembled elastomers based on polyglycidols functionalized with complementary cyanuric acid and diaminotriazine hydrogen bonding couples can be remotely modulated in their mechanical properties by spatially confined laser irradiation after hybridization with small amounts of thermally reduced graphene oxide (TRGO). The TRGO provides an excellent photothermal effect, leads to light‐adaptive steady‐state temperatures, and allows local breakage/de‐crosslinking of the hydrogen bonds. This enables fast self‐healing and spatiotemporal modulation of mechanical properties, as demonstrated by digital image correlation. This study opens pathways toward light‐fueled and light‐adaptive graphene‐based nanocomposites employing molecularly controlled thermal switches.     

On the Performance of TETRA DMO Short Data Service in Railway VANETs

In this paper we present the results of an empirical study investigating the performance of TETRA (TErrestrial Trunked RAdio) in a Vehicular Ad-hoc Network (VANET) for safety related railway traffic applications. The Short Data Service (SDS) of TETRA in the Direct Mode Operation (DMO) allows an infrastructure-less exchange of traffic relevant information between vehicles in range of the communication. The propagation channel in case of such a direct (base station free) communication between railway vehicles underlies specific effects, which are not equivalent to other well known terrestrial mobile scenarios. We will present measurements covering urban, suburban and rural environments along a regional railway network in the south of Bavaria. Beside different operational conditions such as front, rear, and flank approaches of trains, we investigated several topological scenarios on both, single and double track sections along the line. We will also discuss the observed characteristic changes in narrow band signal attenuation and Doppler spectra for passages through forests, hilly areas, stations and a tunnel. We determined statistics for the transmission delay of messages and the message erasure rates for single and multi user access on a single common carrier for different transmission intervals. Finally, the quality of service for the envisaged safety applications is assessed.     

CMOS image sensors for sensor networks

We report on two generations of CMOS image sensors with digital output fabricated in a 0.6 μm CMOS process. The imagers embed an ALOHA MAC interface for unfettered self-timed pixel read-out targeted to energy-aware sensor network applications. Collision on the output is monitored using contention detector circuits. The image sensors present very high dynamic range and ultra-low power operation. This characteristics allow the sensor to operate in different lighting conditions and for years on the sensor network node power budget. Eugenio Culurciello (S’97–M’99) received the Ph.D. degree in Electrical and Computer Engineering in 2004 from Johns Hopkins University, Baltimore, MD. In July 2004 he joined the department of Electrical Engineering at Yale University, where he is currently an assistant professor. He founded and instrumented the E-Lab laboratory in 2004. His research interest is in analog and mixed-mode integrated circuits for biomedical applications, sensors and networks, biological sensors, Silicon on Insulator design and bio-inspired systems. Andreas G. Andreou received his Ph.D. in electrical engineering and computer science in 1986 from Johns Hopkins University. Between 1986 and 1989 he held post-doctoral fellow and associate research scientist positions in the Electrical and Computer engineering department while also a member of the professional staff at the Johns Hopkins Applied Physics Laboratory. Andreou became an assistant professor of Electrical and Computer engineering in 1989, associate professor in 1993 and professor in 1996. He is also a professor of Computer Science and of the Whitaker Biomedical Engineering Institute and director of the Institute’s Fabrication and Lithography Facility in Clark Hall. He is the co-founder of the Johns Hopkins University Center for Language and Speech Processing. Between 2001 and 2003 he was the founding director of the ABET accredited undergraduate Computer Engineering program. In 1996 and 1997 he was a visiting professor of the computation and neural systems program at the California Institute of Technology. In 1989 and 1991 he was awarded the R.W. Hart Prize for his work on mixed analog/digital integrated circuits for space applications. He is the recipient of the 1995 and 1997 Myril B. Reed Best Paper Award and the 2000 IEEE Circuits and Systems Society, Darlington Best Paper Award. During the summer of 2001 he was a visiting professor in the department of systems engineering and machine intelligence at Tohoku University. In 2006, Prof. Andreou was elected as an IEEE Fellow and a distinguished lecturer of the IEEE EDS society. Andreou’s research interests include sensors, micropower electronics, heterogeneous microsystems, and information processing in biological systems. He is a co-editor of the IEEE Press book: Low-Voltage/Low-Power Integrated Circuits and Systems, 1998 (translated in Japanese) and the Kluwer Academic Publishers book: Adaptive Resonance Theory Microchips, 1998. He is an associate editor of IEEE Transactions on Circuits and Systems I.     

Merocyanine/C60 Planar Heterojunction Solar Cells: Effect of Dye Orientation on Exciton Dissociation and Solar Cell Performance

In this study the charge dissociation at the donor/acceptor heterointerface of thermally evaporated planar heterojunction merocyanine/C₆₀ organic solar cells is investigated. Deposition of the donor material on a heated substrate as well as post‐annealing of the complete devices at temperatures above the glass transition temperature of the donor material results in a twofold increase of the fill factor. An analytical model employing an electric‐field‐dependent exciton dissociation mechanism reveals that geminate recombination is limiting the performance of as‐deposited cells. Fourier‐transform infrared ellipsometry shows that, at temperatures above the glass transition temperature of the donor material, the orientation of the dye molecules in the donor films undergoes changes upon annealing. Based on this finding, the influence of the dye molecules’ orientations on the charge‐transfer state energies is calculated by quantum mechanical/molecular mechanics methods. The results of these detailed studies provide new insight into the exciton dissociation process in organic photovoltaic devices, and thus valuable guidelines for designing new donor materials.     

Preparation of Ring-Shaped Thermoelectric Legs from PbTe Powders for Tubular Thermoelectric Modules

Waste heat recovery—for example, in automotive applications—is a major field for thermoelectric research and future application. Commercially available thermoelectric modules are based on planar structures, whereas tubular modules may have advantages for integration and performance in the field of automotive waste heat recovery. One major drawback of tubular generator designs is the necessity for ring-shaped legs made from thermoelectric material. Cutting these geometries from sintered tablets leads to considerable loss of thermoelectric material and therefore high cost. Direct sintering of ring-shaped legs or tubes of thermoelectric material is a solution to this problem. However, sintering such rings with high homogeneity and density faces some difficulties related to the mechanical properties of typical thermoelectric materials such as lead telluride (PbTe)—particularly brittleness and high coefficient of thermal expansion. This work shows a process for production of thermoelectric rings made of p- and n-doped PbTe. Long tubes of PbTe have been sintered in a current-assisted sintering process with specially designed sintering molds, coated with a diffusion barrier, and finally cut into ring-shaped slices. To demonstrate the technology, a tubular thermoelectric module has been assembled using these PbTe rings.