Application limits and sensitisation behaviour of the manganese- and nitrogen-alloyed austenitic stainless steel P2000 (X13CrMnMoN18-14-3)

Nickel-free high-nitrogen-alloyed stainless steels like the P2000 (X13CrMnMoN18-14-3) were developed to enhance the strength and corrosion resistance of austenitic stainless steels like 304 and 316 while keeping the typical high ductility. The mechanical and corrosive properties of P2000 were investigated and compared with 304 and 316 to highlight the application opportunities of this new alloy. The microstructure of the solution-annealed condition was characterised by electron backscatter diffraction and the mechanical properties were studied by uniaxial tensile tests, Charpy impact tests and hardness measurements. The passivation behaviour was analysed using the electrochemical potentiodynamic reactivation, whereas the pitting corrosion resistance was compared by pitting potentials and pitting temperatures. However, secondary thermal influences or suboptimal heat treatment can impair the corrosion resistance due to the precipitation of secondary phases and the resulting sensitisation. Thermodynamic calculations and artificial ageing treatment in the range of 500–900°C for up to 100 h were used to determine critical time–temperature parameters for sensitisation. The microstructure of the various aged states was evaluated by scanning electron microscopy and compared with the degrading corrosion resistance characterised by the KorroPad method.     

Gas Chromatographic Enantioseparation of Fluorinated Anesthetics: Single‐Column Performance and Scale‐up Estimation

Results of a study devoted to provide the pure enantiomers of isoflurane and desflurane from racemic mixtures using gas chromatography are presented. For that purpose, a cyclodextrin‐based selector described in earlier work was immobilized on porous glass beads. The adsorption isotherms were determined and applied to predict operating parameters which provide the highest possible productivity of the separation. The analysis included evaluation of the performance of larger columns applying simplifying scale‐up considerations. Using repetitive batches, the method can provide per day with a laboratory scale column approximately 1 g pure enantiomer. Selected model predictions were validated experimentally.     

Autonomous allocation of wireless body-sensor networks to frequency channels: modeling with repeated “balls-in-bins” experiments

Wireless Networks - In this paper we model a situation where several wireless body sensor networks (WBSN) compete for occupation of a number of frequency channels. Each channel can host at most one...     

Fiscal decentralization and regional disparities: The importance of good governance

In this paper we consider how government quality mediates the relationship between fiscal decentralization and regional disparities. Previous work has argued that fiscal decentralization has the potential to reduce income differences across regions but that this potential may not be realized because of governance problems associated with sub-national authorities. Our empirical evidence based on a sample of 24 OECD countries over the period 1984 to 2006 lends a measure of support to this idea. We find that fiscal decentralization promotes regional convergence in high government quality settings but, worryingly, it leads to wider regional disparities in countries with poor governance.     

Optical study of twin‐tanked ICS solar heaters combined with asymmetrical CPC‐type reflectors

The distribution of solar irradiance on the absorbing surface of a typical integrated collector storage (ICS) system combined with reflector troughs is commonly studied by means of ray tracing techniques. A conceptually different alternative is offered by the method of the average number of reflections (ANR). In the present work, the latter is employed for the systematic optical study of realistic ICS models. In all cases, the solar devices consist of twin cylindrical storage tanks which are mounted on top of stationary asymmetrical CPC‐type reflectors. The emphasis of the current research is mainly placed on the evaluation of the ANR reliability for the calculation of the optical efficiency of the related twin‐tanked devices. Additionally, useful operational parameters, such as the optical performance of the proposed geometries, are also determined. The behavior of the tested ICS systems reveals that the optical efficiency may vary in the range of 0.75 to 0.91, exhibiting a strong dependence on the geometric parameters of the solar devices. The highest efficiency is achieved by the systems which combine large reflecting area and storage tanks in close proximity.     

Structural performance of a climbing cactus: making the most of softness

Climbing plants must reach supports and navigate gaps to colonize trees. This requires a structural organization ensuring the rigidity of so-called ‘searcher’ stems. Cacti have succulent stems adapted for water storage in dry habitats. We investigate how a climbing cactus Selenicereus setaceus develops its stem structure and succulent tissues for climbing. We applied a ‘wide scale’ approach combining field-based bending, tensile and swellability tests with fine-scale rheological, compression and anatomical analyses in laboratory conditions. Gap-spanning ‘searcher’ stems rely significantly on the soft cortex and outer skin of the stem for rigidity in bending (60–94%). A woody core contributes significantly to axial and radial compressive strength (80%). Rheological tests indicated that storage moduli were consistently higher than loss moduli indicating that the mucilaginous cortical tissue behaved like a viscoelastic solid with properties similar to physical or chemical hydrogels. Rheological and compression properties of the soft tissue changed from young to old stages. The hydrogel–skin composite is a multi-functional structure contributing to rigidity in searcher stems but also imparting compliance and benign failure in environmental situations when stems must fail. Soft tissue composites changing in function via changes in development and turgescence have a great potential for exploring candidate materials for technical applications.     

New methods for calculating the force distribution within belt grinding processes

In order to simulate belt grinding processes (e.g. for process planning or path planning) one usually needs information about the contact zone and contact forces. Typically, an unacceptable computational effort is required for good simulation results, since these contact problems are usually of a nonlinear nature. In this paper, the application of support vector machines (SVM) is presented. The SVM is a learning machine that aims at finding a function that optimally fits given observations. The main advantage of SVM is its fast evaluation during simulation. However, a single training phase with an extensive amount of observation data has to be done once before the simulation can take place. From a practical point of view, it is very often not feasible to sample these observation data by experiments. At this point special Finite element methods for contact problems can be applied very efficiently. In order to obtain as accurate as possible training data, an adaptive finite element method for contact problems has been developed.     

Comparison between pulsed laser and frequency-domain photoacoustic modalities: signal-to-noise ratio, contrast, resolution, and maximum depth detectivity

In this work, a detailed theoretical and experimental comparison between various key parameters of the pulsed and frequency-domain (FD) photoacoustic (PA) imaging modalities is developed. The signal-to-noise ratios (SNRs) of these methods are theoretically calculated in terms of transducer bandwidth, PA signal generation physics, and laser pulse or chirp parameters. Large differences between maximum (peak) SNRs were predicted. However, it is shown that in practice the SNR differences are much smaller. Typical experimental SNRs were 23.2 dB and 26.1 dB for FD-PA and time-domain (TD)-PA peak responses, respectively, from a subsurface black absorber. The SNR of the pulsed PA can be significantly improved with proper high-pass filtering of the signal, which minimizes but does not eliminate baseline oscillations. On the other hand, the SNR of the FD method can be enhanced substantially by increasing laser power and decreasing chirp duration (exposure) correspondingly, so as to remain within the maximum permissible exposure guidelines. The SNR crossover chirp duration is calculated as a function of transducer bandwidth and the conditions yielding higher SNR for the FD mode are established. Furthermore, it was demonstrated that the FD axial resolution is affected by both signal amplitude and limited chirp bandwidth. The axial resolution of the pulse is, in principle, superior due to its larger bandwidth; however, the bipolar shape of the signal is a drawback in this regard. Along with the absence of baseline oscillation in cross-correlation FD-PA, the FD phase signal can be combined with the amplitude signal to yield better axial resolution than pulsed PA, and without artifacts. The contrast of both methods is compared both in depth-wise (delay-time) and fixed delay time images. It was shown that the FD method possesses higher contrast, even after contrast enhancement of the pulsed response through filtering.     

Projection-based respiratory-resolved left ventricular volume measurements in patients using free-breathing double golden-angle 3D radial acquisition

Objective

To refine a new technique to measure respiratory-resolved left ventricular end-diastolic volume (LVEDV) in mid-inspiration and mid-expiration using a respiratory self-gating technique and demonstrate clinical feasibility in patients.

Materials and methods

Ten consecutive patients were imaged at 1.5 T during 10 min of free breathing using a 3D golden-angle radial trajectory. Two respiratory self-gating signals were extracted and compared: from the k-space center of all acquired spokes, and from a superior–inferior projection spoke repeated every 64 ms. Data were binned into end-diastole and two respiratory phases of 15% respiratory cycle duration in mid-inspiration and mid-expiration. LVED volume and septal–lateral diameter were measured from manual segmentation of the endocardial border.

Results

Respiratory-induced variation in LVED size expressed as mid-inspiration relative to mid-expiration was, for volume, 1 ± 8% with k-space-based self-gating and 8 ± 2% with projection-based self-gating (P = 0.04), and for septal–lateral diameter, 2 ± 2% with k-space-based self-gating and 10 ± 1% with projection-based self-gating (P = 0.002).

Discussion

Measuring respiratory variation in LVED size was possible in clinical patients with projection-based respiratory self-gating, and the measured respiratory variation was consistent with previous studies on healthy volunteers. Projection-based self-gating detected a higher variation in LVED volume and diameter during respiration, compared to k-space-based self-gating.