Hydrogen reduction kinetics of electrometallurgical slime

The interaction of hydrogen with the zinc-containing electrometallurgical slime of the Severstal’ metallurgical works has been studied. The sequence of transformations in the slime heated to 1100°C in hydrogen or air has been established. The experimental and calculated weight losses coincide. Some of the carbonates are shown to decompose in the temperature range 300–700°C, and most iron and zinc oxides are reduced to a metal. In the temperature range 650–850°C, zinc is almost completely sublimated. At temperatures above 800°C, complex oxides are reduced and calcium and magnesium carbonates and sulfates are likely to decompose. Experimental digital data on the zinc sublimation rate are processed by the least squares method with approximating equations used in thermal analysis. The kinetics of nonisothermal zinc sublimation is comprehensively analyzed using a unique procedure developed for taking into account the background of a peak and the effect of accompanying processes. An equation for the calculation of the zinc sublimation rate under experimental conditions (fluidized bed) is given and tested.     

Tensions in water management: Dutch tradition and European policy.

Present-day worldwide water problems require new management tools and sustainable system innovations. At Delft University of Technology research is being carried out into water resources and management development aimed at forming such tools and innovations, focused on Integrated River Basin Management (IRBM). One of the case-studies deals with Dutch water management and technology in the context of European IRBM in the form of the 2000 Water Frame Directive. The Netherlands experience many water problems and European IRBM could bring help by offering a framework for both international cooperation and technological innovations. To work as an adequate management tool European IRBM should be tailored to the Dutch water tradition, which recently culminated in Integrated Water Management. Both approaches are in some respects contradicting. Europe pursues, for example, centralized control; while the Dutch have their strongly water boards based decentralized administration. The tensions between both approaches require mutual adaptation, for which the concept of subsidiarity might offer points of departure. This paper describes the first results of the case-research into Dutch water management and technology in the context of Europe as well as the backgrounds and the set-up of the research as a whole.     

The effect of the textile industry dye bath additive EDTMPA on colour removal characteristics by ozone oxidation.

In this study, the effects of the phosphonic acid based sequestering agent EDTMPA used in the textile dye baths on colour and organic matter removal by ozone oxidation was experimentally investigated. Procion Navy HEXL dyestuff that has been commonly used for the reactive dyeing of cellulose fibers was selected as the model component. The organic matter oxidation by ozone was determined to obey the pseudo-first order kinetics as they are treated singly or in combination. COD removal rates obtained from pseudo-first order reaction kinetics showed that oxidation of Navy HEXL alone (0.0947 L/min) was faster than that of EDTMPA (0.0171 L/min) and EDTMPA with dye (0.0155 L/min) at pH 3.0. It was also found that reaction rates of single EDTMPA removal and EDTMPA and dye mixture removal increased as the reaction pH was increased from 3.0 to 10.5.     

Some modifications of the classification tree construction algorithm

The paper describes a few modifications of the classification tree construction algorithm that have proved to be useful for solving tasks of noise spectra processing with reference to NPP diagnostics. The article was translated by the authors.     

Characteristics of tunneling and impact ionization in ZnS:Mn-based thin-film electroluminescent structures

A method for measuring the characteristics of tunneling and impact ionization in thin-film electroluminescent emitters is suggested. This method makes it possible to find time dependences of the space-charge layer thickness near the anode and the length of the impact ionization region, to determine more exactly the time dependence of the field in the potential barrier at the cathode interface, the maximum depth of the surface states from which electron tunneling occurs, the minimum thickness of the barrier, and the electron tunneling probability, as well as the impact ionization rate for the deep centers related to structural defects of the phosphor layer.     

Functions for relative maximization

We introduce functions for relative maximization in a general context: the beta and alpha applications. After a systematic study of different kinds of regularities, we investigate how to approximate certain values of these functions using periodic orbits. We also show that the differential of an alpha application determines the asymptotic behavior of the optimal trajectories.     

Interaction of optical radiation with GaAs nanowhisker arrays

We have studied the reflectivity spectra of doped GaAs nanowhiskers (NWs) with various morphologies, which were grown by molecular-beam epitaxy. It is established that the character of the reflectivity spectra of NWs is determined by the shape of nanocrystals. NWs with droplike and pointlike vertices differently interact with electromagnetic radiation. Laser radiation produces a spectraly selective action on the NW array, which leads to a change in the NW height and induces “caking” of their vertices, thus modifying the reflectivity of the sample. This phenomenon can be used for the creation of local microstructures with preset characteristics in large NW arrays.     

Earing in cup drawing face-centered cubic single crystals and polycrystals

A simple model of flange behavior during cup drawing was used to predict the earing profile of deep-drawn cups. The relationship between yield surface shape and earing tendency was established, with plane stress yielding corresponding to no hold-down pressure on the flange and plane strain corresponding to no thickening. Using the Schmid law, the earing model was applied to the case of a single crystal in cube position and compared to Tucker’s well-known results.^[6] For the plane strain case, good agreement was obtained with the experiment; but for plane stress, the predicted profile did not agree with the experimental one. Using the Taylor/ Bishop and Hill (TBH) theory^[8,9] and measured crystallite orientation distribution functions (CODF), the model was applied to the case of high-purity aluminum sheet with various cold-rolling reductions (35, 60, 80, and 90 pct). The major experimental trends were again correctly predicted by the plane strain case.