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排序方式: 共有261条查询结果,搜索用时 15 毫秒
41.
Karen Valencia G. Alejandro López Agileo Hernández-Gordillo Rodolfo Zanella Sandra E. Rodil 《Ceramics International》2018,44(18):22329-22338
Stabilized tetragonal Bi2O3 nanoparticles (β-Bi2O3) were obtained by annealing treatments of amorphous Bi-based precursors, obtained by chemical precipitations, at temperatures between 350 and 450?°C. The formation of the stabilized β-Bi2O3 phase was possible by using (BiO)4CO3(OH)2 while other precursors such as amorphous bismuth carbonate ((BiO)2CO3) and amorphous basic bismuth nitrate (Bi6O6(OH)2(NO3)4·2H2O) led to the formation of the thermodynamically stable monoclinic α-Bi2O3 and Bi5O7NO3 phases. The Bi-based precursors were prepared by the chemical precipitation method at room temperature in ethylenediamine-solvent varying the HNO3/Bi3+ molar ratio (10, 26 and 56). The physicochemical properties of the three as-prepared amorphous precursors and the formed-after-calcination β-Bi2O3, α-Bi2O3 and Bi5O7NO3 phases were analyzed by X-ray diffraction, scanning electron microscopy, thermogravimetry, X-ray photoelectron spectroscopy (XPS), FTIR analysis, diffuse reflectance spectroscopy and surface area by BET method. The photocatalytic activity of all annealed solids containing the β-Bi2O3 phase was tested in the photodegradation of the indigo carmine (IC) dye under specific blue light. A schematic diagram of the Bi2O3 phases obtained as a function of the annealing conditions and initial amorphous precursor is proposed and explained in terms of the amount of CO32-, NO3- and amine (ENH22+ ? ENH+) ions present in each bismuth precursor. 相似文献
42.
Activated carbon (AC) is an adsorbent used in most adsorption processes related to micro removal of pollutants from the water phase, but the application is limited due to high costs and environmental issues related to the disposal after saturation. Different regeneration techniques, reducing costs and minimizing environmental impact, are reported for the reuse of saturated AC. These techniques can be performed via two separate strands: regeneration based only on desorption of adsorbed compounds in AC, or based on the decomposition of pollutants adsorbed on AC. Literature on the regeneration of saturated ACs is reviewed and promising techniques are highlighted. One of the most challenging bottlenecks preventing the commercial application of regeneration technologies is the difficulty of scaling‐up. 相似文献
43.
Extrusion of Rice,Bean and Corn Starches: Extrudate Structure and Molecular Changes in Amylose and Amylopectin 总被引:1,自引:0,他引:1 下载免费PDF全文
Nathan Levien Vanier Varatharajan Vamadevan Graziella Pinheiro Bruni Cristiano Dietrich Ferreira Vânia Zanella Pinto Koushik Seetharaman Elessandra da Rosa Zavareze Moacir Cardoso Elias Jose De J. Berrios 《Journal of food science》2016,81(12):E2932-E2938
The objective of this study was to evaluate the effects of starch source and amylose content on the expansion ratio, density, and texture of expanded extrudates, as well as to investigate the structural and molecular changes that occur in starch granules as a function of extrusion. The starches employed were rice starches (8%, 20%, and 32% amylose), carioca bean starch (35% amylose), and Hylon V® corn starch (55% amylose). The extrudates from rice starches containing 20% and 32% amylose exhibited the highest expansion ratio, while, extrudates from Hylon V® corn starch containing 55% amylose exhibited the lowest expansion ratio. The hardness values of the extrudates with 55% amylose were twice those of the extrudates with 20%, 32%, and 35% amylose. An additional finding was that although the amylopectin promoted the expansion of the gelatinized starch matrix, it failed to strengthen and sustain the walls of the extrudate bubbles during expansion. 相似文献
44.
Maria Quitrio Sandra Simes Andreia Ascenso Manuela Carvalheiro Ana Paula Leandro Isabel Correia Ana Silveira Viana Pedro Faísca Lia Ascenso Jesús Molpeceres Maria Manuela Gaspar Catarina Pinto Reis 《International journal of molecular sciences》2021,22(8)
Insulin is a peptide hormone with many physiological functions, besides its use in diabetes treatment. An important role of insulin is related to the wound healing process—however, insulin itself is too sensitive to the external environment requiring the protective of a nanocarrier. Polymer-based nanoparticles can protect, deliver, and retain the protein in the target area. This study aims to produce and characterize a topical treatment for wound healing consisting of insulin-loaded poly-DL-lactide/glycolide (PLGA) nanoparticles. Insulin-loaded nanoparticles present a mean size of approximately 500 nm and neutral surface charge. Spherical shaped nanoparticles are observed by scanning electron microscopy and confirmed by atomic force microscopy. SDS-PAGE and circular dichroism analysis demonstrated that insulin preserved its integrity and secondary structure after the encapsulation process. In vitro release studies suggested a controlled release profile. Safety of the formulation was confirmed using cell lines, and cell viability was concentration and time-dependent. Preliminary safety in vivo assays also revealed promising results. 相似文献
45.
46.
Cristina-Daniela Ghițulică Andreia Cucuruz Georgeta Voicu Andrei T. Cucuruz Sorina Dinescu Aida Selaru Marieta Costache 《International Journal of Applied Ceramic Technology》2020,17(1):342-353
In this study, chemical precipitation methods were used to obtain ceramic materials doped with magnesium ions in order to improve the regeneration properties of materials used for tissue engineering. Two different ratios of magnesium oxide were used to dope the ceramic powder, more precisely 5% and 10%. The synthesized materials were characterized to determine the calcination temperature of the precursor powder by means of thermal analysis; to determine the mineralogical composition, X-ray diffraction was employed and the scanning electron microscopy was used to determine the microstructure. To make use of these ceramics as biomaterials, viability and proliferation cell tests have been performed. Since synthetic materials have several limitations with regard to medical applications, the materials based on HAp substituted with Mg ions are a promising solution for the regeneration of bone defects because they have a similar bone structure. The presence of Mg in the material proves to be beneficial because this element plays an important role in bone cell regeneration, and more specifically, in stimulating osteoblast proliferation. The materials synthesized in this work present a suitable morphology for uses in bone regeneration because they offer to cells a friendly environment for growth and anchoring. 相似文献
47.
Adhan Pilon Prof. Julia Lorenzo Sergi Rodriguez-Calado Dr. Pedro Adão Prof. Ana M. Martins Dr. Andreia Valente Dr. Luis G. Alves 《ChemMedChem》2019,14(7):770-778
New cyclam derivatives (HOCH2CH2CH2)2(PhCH2)2Cyclam and (HOCH2CH2CH2)2( PhCH2)2Cyclam, as well as their CuII and FeIII complexes, were synthesized and characterized and their stability in cellular media was assessed. The cytotoxic effect of all compounds was examined on human cervical cancer (HeLa) cells, revealing strong anticancer activity. After 24 h, only complexes with the (HOCH2CH2CH2)2( PhCH2)2Cyclam ligand are cytotoxic, whereas after incubation for 72 h all compounds show significant antiproliferative effects. Notably, compounds containing PhCH2 pendant arms on the cyclam ring revealed the most activity, with cytotoxicity values up to 12 times higher than those of cisplatin. All metal complexes seem to induce cell death through the formation of reactive oxygen species. 相似文献
48.
On the capacity of spatially correlated MIMO Rayleigh-fading channels 总被引:10,自引:0,他引:10
Chiani M. Win M.Z. Zanella A. 《IEEE transactions on information theory / Professional Technical Group on Information Theory》2003,49(10):2363-2371
In this paper, we investigate the capacity distribution of spatially correlated, multiple-input-multiple-output (MIMO) channels. In particular, we derive a concise closed-form expression for the characteristic function (c.f.) of MIMO system capacity with arbitrary correlation among the transmitting antennas or among the receiving antennas in frequency-flat Rayleigh-fading environments. Using the exact expression of the c.f., the probability density function (pdf) and the cumulative distribution function (CDF) can be easily obtained, thus enabling the exact evaluation of the outage and mean capacity of spatially correlated MIMO channels. Our results are valid for scenarios with the number of transmitting antennas greater than or equal to that of receiving antennas with arbitrary correlation among them. Moreover, the results are valid for an arbitrary number of transmitting and receiving antennas in uncorrelated MIMO channels. It is shown that the capacity loss is negligible even with a correlation coefficient between two adjacent antennas as large as 0.5 for exponential correlation model. Finally, we derive an exact expression for the mean value of the capacity for arbitrary correlation matrices. 相似文献
49.
André Luís Andrade Menolli H. Sofia Pinto Sheila Reinehr Andreia Malucelli 《Behaviour & Information Technology》2017,36(4):364-389
Organisational learning (OL) helps companies to significantly improve their processes through the reuse of experiences, making knowledge accessible to the whole organisation. However, establishing learning in software development companies is not a trivial task, since it is an area in which processes and knowledge are usually hidden inside the employees’ mind. Generally, employees prefer to look for knowledge via Internet search engines rather than using the knowledge produced inside the company. Hence, we explored how better organising content produced within the company may minimise this problem. We investigated how a semantic collaborative environment, titled semantic collaborative environment for organisational learning (SECOL), based on social software, learning objects (LOs), and units of learning (UL) may assist to improve OL for software development companies. We defined an approach to generate LOs and UL from social software’s content used by companies. The environment was implemented based on ontologies in order to represent and organise acquired knowledge. Furthermore, an experiment was conducted using qualitative data analysis. The results indicated that the use of the environment is appropriate to improve OL in software development teams and the use of SECOL is efficient, particularly in order to acquire new knowledge, assisting the promotion of the use of organisational patterns and minimising repeated solutions. 相似文献
50.