Effects of interface roughness on the spectral properties of thin films and multilayers

We introduce two parameters, large-scale and small-scale rms roughness, to take into account the interface properties of thin films and multilayers in the calculation of their specular reflectance and transmittance. A theoretical motivation for the introduction of these two parameters instead of a standard single rms roughness is provided. Experimental power spectral density functions of several samples are used to illustrate ways in which the parameters introduced can be evaluated.     

Judgments of synchrony between auditory and moving or still visual stimuli.

The flash-lag effect is a visual illusion wherein intermittently flashed, stationary stimuli seem to trail after a moving visual stimulus despite being flashed synchronously. We tested hypotheses that the flash-lag effect is due to spatial extrapolation, shortened perceptual lags, or accelerated acquisition of moving stimuli, all of which call for an earlier awareness of moving visual stimuli over stationary ones. Participants judged synchrony of a click either to a stationary flash of light or to a series of adjacent flashes that seemingly bounced off or bumped into the edge of the visual display. To be judged synchronous with a stationary flash, audio clicks had to be presented earlier--not later--than clicks that went with events, like a simulated bounce (Experiment 1) or crash (Experiments 2-4), of a moving visual target. Click synchrony to the initial appearance of a moving stimulus was no different than to a flash, but clicks had to be delayed by 30-40 ms to seem synchronous with the final (crash) positions (Experiment 2). The temporal difference was constant over a wide range of motion velocity (Experiment 3). Interrupting the apparent motion by omitting two illumination positions before the last one did not alter subjective synchrony, nor did their occlusion, so the shift in subjective synchrony seems not to be due to brightness contrast (Experiment 4). Click synchrony to the offset of a long duration stationary illumination was also delayed relative to its onset (Experiment 5). Visual stimuli in motion enter awareness no sooner than do stationary flashes, so motion extrapolation, latency difference, and motion acceleration cannot explain the flash-lag effect. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Influences of the insertion method in glass ionomer cement porosity

The aim of this study was to evaluate the presence of porosities inside the glass ionomer cement (GIC) after different techniques of material insertion. MATERIAL AND METHOD: Specimens were prepared with high‐viscosity GIC Ketac Molar Easymix and divided into three groups according to the insertion method: spatula (PI), Centrix injector (CI), and low‐cost syringe (LCS). The specimens were fractured and observed with scanning electronic microscopy to quantitatively evaluate porosity inside the material using Image J Software. RESULTS: Statistical analysis, ANOVA application, and Tukey test to significance level of 5%, revealed that there was no statistical difference between the groups. CONCLUSION: Although the use of LCS has not decreased the porosity of the material, this insertion method is easy, accessible, and low cost, which makes it a viable alternative of use in the ART technique and in others bucal health programs. Microsc. Res. Tech., 2012. © 2012 Wiley Periodicals, Inc.     

Effects of Oxide Content on the Glass-Forming Ability of the Ga2S3-Na2S System

Gallium–sodium–sulfide glasses have been shown to be the most promising host for the 1.3 μm fiber optic amplifier so far. However, the current study has revealed that the formation of stable glasses in this system relies on the existence of a certain amount of oxide in the composition. A glass-forming region was identified when 3 mol% Ga₂O₃ was introduced into the melts. Both bulk crystallization and surface crystallization can take place in this system. The thermal behavior of the glasses obtained was studied by DTA and characteristic infrared and UV/visible transmission spectra are presented. The current results are discussed and compared with those previously reported.     

SOCIO-ECONOMIC ASPECTS OF THE AUSTRIAN 200 kWp-PHOTOVOLTAIC-ROOFTOP PROGRAMME

Between 1992 and 1994 a 200 kWp-rooftop programme to promote small grid-connected Photovoltaic (PV) systems was conducted in Austria. Within this programme about 100 PV systems with an average capacity of 2.28 kWp were installed. This paper investigates the socio-economic aspects of this programme and the prospects for a further dissemination of this technology. The major conclusions of this investigation are as follows: (1) The motives to invest in a PV system are: (i) environmental protection; (ii) an alternative to nuclear power; (iii) technical interest. Yet, it is also important that the public supports this purchase by means providing subsidies. (2) The purchase of a PV system leads to different changes in consumer behaviour. Consumers with low initial consumption increased their electricity demand slightly, while the majority of consumers with high initial electricity demand saved electricity. (3) The financial incentives in the programme were not optimally designed. With the same amount of total subsidies it would have been possible to promote more PV systems. (4) The key factors for a further dissemination of PV systems are: (i) financial incentives; (ii) a reduction of the investment costs; (iii) increase in reliability; (iv) distribution of information; (v) enhancement of environmental awareness.     

Tribocorrosion and corrosion behavior of stainless steel coated with DLC films in ethanol with different concentrations of water

There has been a recent increase in both the production and consumption of ethanol due to the numerous environmental advantages that it offers, such as the fact that it can be produced from a variety of renewable materials, for instance corn and cellulose, or it can be obtained from sugarcane bagasse and biomass (2nd and 3rd generation ethanol). The result of this is that nowadays ethanol is widely seen as the dominant biofuel – or as a blend component in gasoline or pure fuel - in many countries.However, one disadvantage of the use of ethanol is the high corrosive behavior that occurs when its hygroscopic properties are exposed to a large number of materials. Xiaoyuan Lou and Preet Singh showed that the increase of water concentration in ethanol induces pitting and metal loss. Diamond-Like Carbon (DLC) films may be a solution to this problem due to the fact that they can be deposited inside tubes, offer good protection levels against corrosion, and reduce the friction coefficient and wear.This paper shows the tribocorrosion and corrosion studies of DLC films deposited on stainless steel grade 304 (SS304) substrates in order to gauge its appropriateness usage in the construction of pipelines and fuel storage tanks. The surface morphology was analyzed before and after 14 days of immersion. The tribocorrosion, friction coefficient, and wear rate were studied in ethanol to see the effects of water concentration. The films showed good adherence to the substrates. Corrosion and tribocorrosion results showed that for bare Stainless Steel 304 the increase of the water content increases the corrosion and the friction coefficient. DLC coated samples presented few points of delamination, and the friction coefficient and open circuit potentials were very low compared with the bare sample which was water concentration independent.     

Histone Deacetylase Inhibitors as Multitarget Ligands: New Players in Alzheimer's Disease Drug Discovery?

Histone deacetylase inhibitors (HDACIs) are responsible for controlling gene expression by modulating the acetylation status of histone proteins. Furthermore, they modulate the activity of cytoplasmic non-histone proteins. Due to the involvement of HDACs in neurodevelopment, memory formation, and cognitive processes, HDACIs have been suggested as innovative agents for the treatment of neurodegenerative disorders such as Alzheimer's disease (AD). Given their mechanisms of action and the complex nature of AD, HDACIs have been proposed for the design of novel multitarget ligands (MTLs). To this aim, the fragment responsible for HDAC inhibition has been coupled with other structures that are able to provide additional biological actions, such as antioxidant activity or the inhibition of phosphodiesterase 5, transglutaminase 2, and glycogen synthase kinase 3β. Herein we discuss recent efforts to design HDACI-based MTLs as potential disease-modifying entities.     

Low gallium-content,dysprosium III-doped,Ge–As–Ga–Se chalcogenide glasses for active mid-infrared fiber optics

A systematic investigation is presented, for the first time, of a 1000 ppmw (parts per million, by weight) Dy³⁺-doped Ge–As–Ga–Se chalcogenide glass series, with a fixed low Ga content of 1 atomic% (at. %), suitable for active mid-infrared fiber optics. Seven glasses constitute the series, which have increasing average coordination number from 2.49 to 2.61, in steps of 0.02, with the GeSe₂, As₂Se₃, and Ga₂Se₃ stoichiometries kept. Glass formation is confirmed using X-ray diffraction and differential scanning calorimetry. Fourier transform infrared spectroscopy is reported for the series. Parallel plate viscometry enables prediction of fiber-drawing temperatures and, with differential thermal analysis, determines the potential for fiber fabrication. X-ray diffraction of samples after parallel-plate viscometry shows that Ge₂₅As₉Ga₁Se₆₅ (at. %) alone, in the glass-series, devitrifies to form the single-crystalline phase: monoclinic-GeSe₂; scanning electron microscope imaging suggests that this phase is both surface and bulk grown. Overall, the recommended host glass at. % compositions for doping with rare-earth ions and drawing to active mid-infrared fiber are: Ge_17.5As₁₈Ga₁Se_63.5, Ge₁₅As₂₁Ga₁Se₆₃, and Ge_12.5As₂₄Ga₁Se_62.5.     

Techno-economic assessment of providing control energy reserves with a biogas plant

Grid stability is being challenged by the increasing integration of power plants with volatile power generation into the energy system. Power supply fluctuations must be compensated by energy system flexibility. The storability of the energy carrier enables biogas plants to generate power flexibly. In this study, the technical and economic effects of providing positive secondary control energy reserves with an Austrian biogas plant were assessed. The plant’s main focus lies in biomethane production with the option of heat and power generation through combined heat and power (CHP) units. A detailed simulation model of the investigated biogas plant was developed, which is presented in this work. Ex-post simulations of one year of flexible plant operation were conducted with this model. The findings show that the installed biogas storage capacity is sufficient to provide control energy reserves while simultaneously producing biomethane. Profitability of providing control energy reserves largely depends on the prices at the control energy market and on CHP unit start-up costs. A cost efficiency analysis demonstrated that investing in a hot water tank with a volume of 5 m³ for short-term heat storage turned out to be economically viable.

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Bioengineering of Anti-Inflammatory Natural Products

Inflammatory processes occur as a generic response of the immune system and can be triggered by various factors, such as infection with pathogenic microorganisms or damaged tissue. Due to the complexity of the inflammation process and its role in common diseases like asthma, cancer, skin disorders or Alzheimer's disease, anti-inflammatory drugs are of high pharmaceutical interest. Nature is a rich source for compounds with anti-inflammatory properties. Several studies have focused on the structural optimization of natural products to improve their pharmacological properties. As derivatization through total synthesis is often laborious with low yields and limited stereoselectivity, the use of biosynthetic, enzyme-driven reactions is an attractive alternative for synthesizing and modifying complex bioactive molecules. In this minireview, we present an outline of the biotechnological methods used to derivatize anti-inflammatory natural products, including precursor-directed biosynthesis, mutasynthesis, combinatorial biosynthesis, as well as whole-cell and in vitro biotransformation.