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61.
The thermal crystallization from the glassy state of different samples of Poly(ethyleneterephthalate) (PET) was investigated with different techniques, such as infrared and x-ray analysis and polarized optical microscopy. The different samples of PET were obtained by ageing the glassy PET films at room temperature and at 60 °C; the behaviour of these films was compared with that of the fresh sample, put at the crystallization temperature as soon as prepared. The temperature of crystallization was 120 °C. All the techniques, investigated to follow the crystallization phenomenon, show that the fresh sample crystallizes with longer times than the others. This result was correlated with the initial structural organization of the glassy amorphous films. Received: 13 February 1997/Accepted: 10 March 1997  相似文献   
62.
The nose cap demonstrator named Nose_2 has been tested for the second time in the plasma wind tunnel (PWT) facility which is part of the sharp hot structure (SHS) technology project, focused on the assessment of the applicability of ultrahigh temperature ceramics (UHTC) to the fabrication of high performance vehicles and SHS for reusable launch vehicles. In this paper the FEM based thermal analyses, carried out for the rebuilding of this PWT test, are presented. Experimental data measured in the PWT have been compared with numerical ones in order to validate the FEM model and to help in interpreting the experimental test itself. The knowledge on the physical phenomenon under investigation has been greatly improved, thanks to the synergy between numerical and experimental activities. In particular, a qualitative study of the modeling of the tip-dome interface has been performed in order to estimate the thermal contact resistance that heat flux encounters in passing through the demonstrator. The correlation between numerical and experimental temperature curves has been found to be satisfactory for both internal and surface temperature distribution, and the FEM model was found reliable in reproducing the thermal behavior of the nose cap.  相似文献   
63.
Buckling is a critical failure phenomenon for structures, and represents a threat for thin shells subjected to compressive forces. The global buckling load, for a conical structure, depends on the geometry and material properties of the shell, on the stacking sequence, on the type of applied load and on the initial geometric imperfections. Geometric imperfections, occurring inevitably during manufacturing and assembly of thin-walled composite structures, produce a reduction in the carrying load capability with respect to the design value. This is the reason why investigating these defects is of major concern in order to avoid over-conservative design structures. In this paper, the buckling behavior a conical structure with 45° semi-vertical angle is numerically investigated. The initial imperfections are taken into account by using different strategies. At first, the Single Perturbation Load Approach (SPLA), which accounts for defects in the form of a lateral load, normal to the surface, has been adopted. Then, the actual measured defects have been applied to the structure by using the Real Measured Mid-Surface Imperfections (MSI) approach. Investigations on cylindrical shells using the first strategy have already shown the occurrence of a particular phenomenon called “local snap-through”, which represents a preliminary loss of stiffness. In order to better understand this phenomenon for conical shells, both the aforementioned techniques have been used to provide an exhaustive overview of the imperfections sensitiveness in conical composite shells. This study is related to part of the work performed in the frame of the European Union (EU) project DESICOS.  相似文献   
64.
    
Broadband communication via satellite systems finds applications in several contexts where other technologies are not available or economically not convenient. Examples are remote areas, disaster struck areas, or vessels/ships. The scarce availability and the high cost of the bandwidth impose to improve flexibility in bandwidth management and dynamic allocation, especially on the shared return link. Typically, this capability is available only to the satellite operator (SO). An innovative dynamic bandwidth management of satellite capacity for the return link has been developed and prototyped as an Internet protocol‐based solution. This solution allows small operators renting bandwidth from the satellite operator and providing services to final customers, managing the permanently assigned resources in a flexible and efficient way. The scope of the paper is to illustrate this technique to achieve the dynamic bandwidth management for a subgroup of satellite terminals (subdomain) by using a centralized controller and distributed software with IP shaping capabilities, without interacting with the satellite operator. This approach has been applied in particular to a satellite maritime ship owner, which is thus able to dynamically distribute capacity among satellite terminals installed onboard of its ship fleet as required, as a network operator. The presented results are the outputs of simulations performed with the NS2 simulator and tests by using real hardware. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
65.
    
In the search for high-energy cathode materials for Na-ion batteries (NIBs), Fe-doped layered transition metal oxides have been recently proposed as promising systems that can ensure improved reversible capacity at high working voltage. Exploiting the anionic redox chemistry in this class of materials represents a great advance for the energy storage community, but uncontrolled oxidation process can lead to the formation of unbound molecular oxygen, with detrimental effects on overall capacity and stability upon cycling. The higher TM–O covalency provided by Fe doping seems to prevent oxygen loss and ensure full capacity recovery. Understanding anionic processes and the underlying mechanism with atomistic details can reinforce the experimental efforts and help to outline rational design strategies for novel high-performing NIB cathodes. To this end, we present a state-of-the-art first-principles study on the P2-type NaxTMO2 (TM = Fe, Ni, and Mn—NFNMO) oxide. We compare structural and electronic features of stoichiometric (NaxFe0.125Ni0.125Mn0.75O2) and Mn-deficient (NaxFe0.125Ni0.125Mn0.68O2) NFNMO to identify and discuss the contribution of each element sublattice on charge compensation processes. Although Mn deficiency is predicted to increase the cathode working voltage, we find the charge compensation being mostly exerted by the Ni and Fe sublattices. Oxygen redox is unfold via the formation of superoxide species at low Na loads with a preferential breaking of more labile Ni–O bonds and binding to Fe atoms. Our calculations predict no release of molecular O2 upon desodiation, thus highlighting the key role of Fe dopant that provides a good TM–O bond strength, preventing oxygen loss while still enabling anionic redox reactions at high voltages with extra reversible capacity.  相似文献   
66.
67.
Numerical procedures based on the combined use of the Virtual Crack Closure Technique and of a fail release approach have been widely used to simulate delamination growth phenomena of composite material structures. This paper starts explaining why this kind of methodologies might not be robust due to mesh and load step size dependency and introduces a novel approach able to cope with the problems identified. Finally the effectiveness and robustness of the proposed procedure, implemented into a commercial finite element software by means of user subroutines, are assessed by comparing the obtained numerical results for a delamination growth phenomenon against literature experimental data on a stiffened panel with a circular embedded delamination under compressive load.  相似文献   
68.
An existing procedure based on the combined use of the Virtual Crack Closure Technique and of a fail release approach for the analysis of delamination growth phenomena in composite structures has been enhanced with a front-tracing algorithm and suitable expressions for the evaluation of the Strain Energy Release Rate when dealing with non-smoothed delamination fronts. The enhanced procedure has been implemented into a commercial finite element software by means of user subroutines and applied to the analysis of a composite stiffened panel with an embedded delamination under compressive load. The effectiveness and robustness of the enhanced procedure have been assessed by comparing literature experimental data and numerical results obtained by using different mesh densities in the damaged area (global/local approach).  相似文献   
69.
Big Data processing architectures are now widely recognized as one of the most significant innovations in Computing in the last decade. Their enormous potential in collecting and processing huge volumes of data scattered throughout the Internet is opening the door to a new generation of fully distributed applications that, by leveraging the large amount of resources available on the network will be able to cope with very complex problems achieving performances never seen before. However, the Internet is known to have severe scalability limitations in moving very large quantities of data, and such limitations introduce the challenge of making efficient use of the computing and storage resources available on the network, in order to enable data-intensive applications to be executed effectively in such a complex distributed environment. This implies resource scheduling decisions which drive the execution of task towards the data by taking network load and capacity into consideration to maximize data access performance and reduce queueing and processing delays as possible. Accordingly, this work presents a data-centric meta-scheduling scheme for fully distributed Big Data processing architectures based on clustering techniques whose goal is aggregating tasks around storage repositories and driven by a new concept of “gravitational” attraction between the tasks and their data of interest. This scheme will benefit from heuristic criteria based on network awareness and advance resource reservation in order to suppress long delays in data transfer operations and result into an optimized use of data storage and runtime resources at the expense of a limited (polynomial) computational complexity.  相似文献   
70.
A 2935-bp cDNA clone encoding glutamine synthetase (GS) was isolated from a cDNA library prepared from four-blastomere Paracentrotus lividus sea urchin embryos. The sequence consists of a 75-bp 5' untranslated region (5'-UTR) followed by a 1095-bp coding region corresponding to a 365-amino-acid (aa) protein, a 1747-bp 3'-UTR and a terminal 18-bp poly(A) tail. The encoded protein shows about 66% identical residues, as compared with human and lobster class-II GS. The sequence contains the Mn(2+)-binding aa and the highly conserved aa regions observed in other GS. Northern blot analyses show that the GS mRNA is present in the sea urchin egg and is developmentally regulated in the embryo.  相似文献   
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