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121.
The influence of gel and molecular weight on the properties of natural rubber has been described. Crystallization, stress relaxation and orientation properties of different samples have been studied. Samples having different gel contents but similar molecular weights and samples having the same gel content with varying molecular weights have been prepared by extracting whole natural rubber. The gel content was varied from 1.5 to 29% and molecular weight from 1 × 105 to 9.9 × 105 g mol−1. The gels reduce the overall crystallinity measured by differential scanning calorimetric experiments after freezing the samples for different time periods at −15°C. They also have a stiffening effect on the tensile relaxation modulus and decrease the rate of relaxation significantly. Birefringence, which measures the orientation and stress-induced crystallization, increases with time at high elongation for samples containing gels. At lower elongation, however, the birefringence of unvulcanized samples decreases with time. This decrease is less for gel samples. Natural rubbers of high molecular weight behave similarly in the above properties when compared to low molecular weight samples. The effect of gel is more predominant than that of molecular weight. 相似文献
122.
123.
S.P. Nehra M.K. Jangid Subodh Srivastava Anil Kumar Balram Tripathi M. Singh Y.K. Vijay 《International Journal of Hydrogen Energy》2009,34(17):7306
Bilayer thin films of diluted magnetic semiconductor CdTe/Mn have been prepared using vacuum thermal evaporation method at pressure of 10−5 torr. Annealing of bilayer thin films has been performed in atmospheric condition at constant temperature 400 °C for 1 hour. Hydrogenation of as-grown and annealed bilayer thin films has been performed by keeping these in hydrogenation cell. Structural characteristics of as-grown and heat treated thin films have been performed by X-ray diffractometer. Current–voltage characteristics of both as-grown hydrogenated and annealed hydrogenated bilayer thin films have been studied to find out the effect of hydrogenation. Surface topography of as-grown and annealed bilayer thin films has been confirmed by optical microscopy. 相似文献
124.
Indu Bhushan Anil Kumar Gourav Modi Subika Jamwal 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2011,86(2):315-318
In the present investigation a Lipase producing strain, Bacillus subtilis (MTCC‐121) was grown on various media containing different sources of carbon, nitrogen and other nutrients. The best media found for the production of lipase was M2 media containing 0.4% peptone, 0.2% beef extract and 1% NaCl. Lipase produced from this culture was used for the kinetic resolution of racemic acetyl‐1‐phenyl ethanol and its derivatives, which are important as chiral auxiliaries and intermediates in the synthesis of natural products, pharmaceuticals and agrochemicals. The lipase resolved these substrates after 48 h with enantiomeric excess of 90–98% and conversion 40–48%. Copyright © 2010 Society of Chemical Industry 相似文献
125.
Anne Makena Dr. Sander S. van Berkel Dr. Clarisse Lejeune Dr. Raymond J. Owens Dr. Anil Verma Ramya Salimraj Dr. James Spencer Dr. Jürgen Brem Prof. Dr. Christopher J. Schofield 《ChemMedChem》2013,8(12):1923-1929
Serine‐ and metallo‐β‐lactamases present a threat to the clinical use of nearly all β‐lactam antibiotics, including penicillins, cephalosporins, and carbapenems. Efforts to develop metallo‐β‐lactamase (MBL) inhibitors require suitable screening platforms to allow the rapid determination of β‐lactamase activity and efficient inhibition. Unfortunately, the platforms currently available are not ideal for this purpose. Further progress in MBL inhibitor identification requires inexpensive and widely applicable assays. Herein the identification of an inexpensive and stable chromogenic substrate suitable for use in assays of clinically relevant MBLs is described. (6R,7R)‐3‐((4‐Nitrophenoxy)methyl)‐8‐oxo‐7‐(2‐phenylacetamido)‐5‐thia‐1‐azabicyclo[4.2.0]oct‐2‐ene‐2‐carboxylic acid 5,5‐dioxide (CLS405) was synthesised in a three‐step protocol. CLS405 was then characterised spectroscopically, and its stability and kinetic properties evaluated. With a Δλmax value of 100 nm between the parent and hydrolysis product, a higher analytical accuracy is possible with CLS405 than with commonly used chromogenic substrates. The use of CLS405 in assays was validated by MBL activity measurements and inhibitor screening that resulted in the identification of N‐hydroxythiazoles as new inhibitor scaffolds for MBLs. Further evaluation of the identified N‐hydroxythiazoles against a panel of clinically relevant MBLs showed that they possess inhibitory activities in the mid‐ to low‐micromolar range. The findings of this study provide both a useful tool compound for further inhibitor identification, and novel scaffolds for the design of improved MBL inhibitors with potential as antibiotics against resistant strains of bacteria. 相似文献
126.
The present paper deals with the synthesis of conducting ferrimagnetic polyaniline nanocomposite embedded with γ-Fe2O3 (9–12 nm) and titanium dioxide (70–90 nm) nanoparticles via a micro-emulsion polymerization. The microwave absorption properties of nanocomposite in 12.4–18 GHz (Ku-band) frequency range shows shielding effectiveness due to absorption (SEA) value of ?45 dB, which is much higher than polyaniline composite with iron oxide and polyaniline–TiO2 composites. The higher EMI shielding is mainly arising due to combined effect of γ-Fe2O3 and TiO2 that leads to more dielectric and magnetic losses which consequently contributed to higher values of shielding effectiveness. XRD analysis of the nanocomposite reveals the incorporation of nanoparticles in the conducting polymer matrix while the thermal gravimetric analysis (TGA) demonstrates that the nanocomposite is stable up to 250 °C. 相似文献
127.
Athabasca bitumen was characterized by dividing it into sixteen pseudo components. Using mean boiling point, molecular weight and specific gravity data, the critical properties of the pseudo components were estimated from available correlations. Two approaches for the prediction of bitumen surface tension were investigated. It was found that the surface tensions predicted by the principle of corresponding states and the Rice-Teja correlations were in general agreement with the published experimental data. In addition, these models successfully predicted the effect of temperature on surface tension at temperatures greater than about 60°C. 相似文献
128.
Purnima Dhall Anil Kumar Abha Joshi Tushya Kumar Saxsena Angamuthu Manoharan Santosh Dayal Makhijani Rita Kumar 《Sensors and actuators. B, Chemical》2008,133(2):478-483
An amperometric biosensor for determination of biochemical oxygen demand in wastewater has been developed to overcome the time consuming monitoring procedures. The performance and stability of the immobilized membrane have been investigated at 37 °C and pH 6.8. Immobilized microbial membranes maintain their stability and activity after intermittent use for 400 cycles when stored at 4 °C in sodium phosphate buffer pH 6.8. The response time of the BOD sensor was only 90 min, being independent of the concentration, and the lower detection limit was 1 mg/l. The obtained BOD values showed correlation with that of the conventional method for BOD determination (BOD5) with a deviation of ±10%. Moreover, the sensor exhibits good repeatability (3.39–4.45%) and reproducibility (1.85–2.25%). Software was added to upgrade this sensor and to make it a promising candidate for online monitoring. 相似文献
129.
Anil G. Khadakkar K. Ravi Sankar P. Rathinam R. Narayanan S. P. Rao J. K. Popli 《Strain》1997,33(2):57-60
This paper describes an experimental investigation carried out involving instrumentation, measurement and monitoring of stresses in a large diameter gas pipeline during its lowering operations. It also highlights the ingenious techniques developed and adopted to overcome the difficulties pertaining to long leadwires, measurement of existing strains on the curved surface of a pipeline and protection of strain gauge installations. These novel methods were used to ensure smooth and proper functioning of strain gauge instrumentation even under the severe field conditions at site for more than two weeks, till the lowering operations and pipeline monitoring was successfully completed. 相似文献
130.
Anil Kumar Mandeep Kaur Rajeev Kumar Pinaki Ranjan Sengupta Vasantha Raman Gopal Bhatia Kedar Nath Sood 《Journal of Materials Science》2010,45(5):1393-1400
Carbon–copper composites with varying copper to carbon ratio of 0.66–1.5 (by weight) were developed from coal-tar-pitch-derived
green coke (as such or modified with natural graphite) as carbon source and electrolytic grade copper powder at different
heat treatment temperatures (HTTs) of 1000–1400 °C. The physical, mechanical, and electrical properties differ depending upon
the HTT and also on copper to carbon ratio (Cu/C). The composites prepared at HTT of 1100 °C having Cu/C ratio of 0.66 and
0.9 exhibited a high bending strength of 150 and 140 MPa, bulk density of 2.63 and 2.81 gm/cm3, electrical resistivity of 1.6 and 0.96 m Ω cm and shore hardness of 88 and 84, respectively, in spite of well-known inadequate
wettability between copper and carbon. Increasing the temperature from 1100 °C for processing of the composites deteriorated
the properties mainly due to the loss of copper through melting above 1100 °C as revealed by X-ray, scanning electron microscopy,
thermal analysis and EDAX studies. 相似文献