NiO hollow microspheres as efficient bifunctional electrocatalysts for Overall Water-Splitting

Development of efficient, earth-abundant and low-cost electrocatalyst for effective water electrolysis is highly demanding for production of sustainable hydrogen energy. In this paper, we report the cost-effective synthetic protocol for porous NiO hollow spheres in large scale through a simple spray drying strategy, using aqueous nickel ammonium carbonate complex solution, followed by calcination. The synthesized NiO hollow spheres calcined at 300 °C (NiO-300) are porous, made of nanoparticles in size range of 10–16 nm with a size range of 2.5–4 μm and total surface area of 120 m²/g. The NiO-300 exhibited excellent bifunctional electrocatalytic water splitting characteristic, both OER, and HER, in basic solution. NiO-300 modified glassy carbon electrode showed superior water electrolysis kinetics and to achieve 10 mA cm^?2 current density, it required 370 mV overpotential for OER and 424 mV overpotential for HER in 1 M KOH. It is also worked well with cost-effective plastic chip electrode. An assembled two-electrode system by pairing NiO modified plastic chip electrode as both anode and cathode in a 1.0 M KOH electrolyte for overall water splitting exhibit clear bubble formation at 1.6 V potential.     

Asymmetric twin-waveguide 1.55-μm wavelength laser with adistributed Bragg reflector

We demonstrate a single frequency, 1.55 μm wavelength laser based on an asymmetric twin-waveguide structure using a single growth step and a simple fabrication process. The external Bragg grating is formed on the passive ridge waveguide, optically coupled to the twin-guide gain section using a low loss, tapered mode transformer. The grating is produced by near-field holographic printing using a phase mask. Output powers >11 mW in a small-spot waveguide with a side-mode suppression ratio >40 dB and a slope efficiency of 0.11 W/A are obtained under pulsed operation. These performance characteristics are comparable to conventional, nonintegrated, conventional discrete DBR lasers, although the twin-waveguide design is compatible with photonic integrated circuits such as monolithic transmitters and WDM coherent receivers     

Role of Temperature and SiC<Subscript>P</Subscript> Parameters in Stability and Quality of Al-Si-Mg/SiC Foams

Composites of Al-Si-Mg (A356) alloy with silicon carbide particles were synthesized in-house and foamed by melt processing using titanium hydride as foaming agent. The effects of the SiC_P size and content, and foaming temperature on the stability and quality of the foam were explored. It was observed that the foam stability depended on the foaming temperature alone but not on the particle size or volume percent within the studied ranges. Specifically, foam stability was poor at 670°C. Among the stable foams obtained at 640°C, cell soundness (absence of/low defects, and collapse) was seen to vary depending on the particle size and content; For example, for finer size, lower particle contents were sufficient to obtain sound cell structure. It is possible to determine a foaming process window based on material and process parameters for good expansion, foam stability, and cell structure.     

Physicomechanical properties of wollastonite (CaSiO3)/styrene butadiene rubber (SBR) nanocomposites

The purpose of this study was to investigate the effect of bare wollastonite (BW) and modified wollastonite (MW) nano‐rods into the styrene butadiene rubber (SBR). SBR nanocomposites were prepared by the incorporation of different wt % (0.3–4.5) of BW and MW nanorods. All nanocomposites were characterized by thermal gravimetric analyzer (TGA) and differential scanning calorimeter (DSC). The particle size and morphology of BW and MW nanorods were characterized by field‐emission scanning electron microscope (FE‐SEM), transmission electron microscope (TEM), and Fourier transform infrared (FTIR) spectrophotometer, while FE‐SEM and AFM analyses were performed for BW/SBR and MW/SBR nanocomposites. The obtained results revealed the existence of stronger interaction between the SBR and MW nanorods into MW/SBR as compared to BW/SBR nanocomposites. FE‐SEM and AFM images showed a perfect dispersion of the MW nanorods in SBR matrix at 3 wt % loading. Thermal stability of MW/SBR nanocomposites was also increased significantly by the addition of MW nanorods. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42811.     

Operational experience with a mathematical model for temperature prediction in secondary steelmaking

A previous study has reported the development of flow and thermal model for gas purged ladle and validation of the same by comparison with literature. This paper presents further development of an integrated process model from tapping at LD to teeming at tundish location. The model was tuned and validated with plant data. The model shows a match of temperature within (± 5°C) between prediction and measurement for most of heat data. The model was then used to carry out sensitivity test for the various important process parameters in order to find out quantitative influence of these on steel temperatures. The findings have been reported here.     

Comparing Reliability-Redundancy Tradeoffs for Two von Neumann Multiplexing Architectures

Nanoelectronic systems are anticipated to be highly susceptible to computation and communication noise. Interestingly, von Neumann addressed the issue of computation in the presence of noisy gates in 1952 and developed a technique called multiplexing. He proposed multiplexing architectures based on two universal logic functions, nand and maj. Generalized combinatorial models to analyze such multiplexing architectures were proposed by von Neumann and extended later by others. In this work, we describe an automated method for computing the effects of noise in both the computational and interconnect hardware of multiplexing-based nanosystems-a method employing a probabilistic model checking tool and extending previous modeling efforts, which only considered gate noise. This method is compared with a recently proposed automation methodology based on probabilistic transfer matrices and used to compute and compare the reliability of individual nand and maj multiplexing systems, both in the presence of gate and interconnect noise. Such a comparative study of nand and maj multiplexing is needed to provide quantitative guidelines for choosing one of the multiplexing schemes. The maximum device failure probabilities that can be accommodated by multiplexing-based fault-tolerant nanosystems are also computed by this method and compared with theoretical results from the literature. This paper provides a framework that can capture probabilistically quantified fault models and provide quick reliability evaluation of multiplexing architectures     

Accelerating Molecular Dynamics Simulations with Reconfigurable Computers

With advances in reconfigurable hardware, especially field-programmable gate arrays (FPGAs), it has become possible to use reconfigurable hardware to accelerate complex applications such as those in scientific computing. There has been a resulting development of reconfigurable computers, that is, computers that have both general-purpose processors and reconfigurable hardware, as well as memory and high-performance interconnection networks. In this paper, we describe the acceleration of molecular dynamics simulations with reconfigurable computers. We evaluate several design alternatives for the implementation of the application on a reconfigurable computer. We show that a single node accelerated with reconfigurable hardware, utilizing fine-grained parallelism in the reconfigurable hardware design, is able to achieve a speedup of about two times over the corresponding software-only simulation. We then parallelize the application and study the effect of acceleration on performance and scalability. Specifically, we study strong scaling, in which the problem size is fixed. We find that the unaccelerated version actually scales better, because it spends more time in computation than the accelerated version does. However, we also find that a cluster of P accelerated nodes gives better performance than a cluster of 2P unaccelerated nodes.     

Effect of solvents on properties of the ultrasound assisted synthesized ceria nanoparticles and its performance as an adsorbent

The present study revealed a facile, ultrasound assisted ceria nanoparticle synthesis route by the reduction of cerium nitrate hexahydrate in different solvents at room temperature. The different solvents employed were methanol (MeOH), ethylene glycol (EG), water (aq) and isopropyl alcohol (IPA). The ceria nanoparticles were synthesized without the use of any capping agent in 20?min. The yield obtained was around 90% for the synthesized ceria samples. As synthesized ceria nanoparticles were characterized by X-ray diffraction (XRD), Field emission gun scanning electron microscopy (FEG-SEM), Brunauer Emmett Teller (BET) and zeta (ζ) potential in order to determine the influence of solvent on the physical properties of ceria nanoparticles. All the ceria samples illustrated a predominant spherical shape with the size in the range of 5–20?nm. It was found that interaction of the solvent with ceria nanoparticles in the presence of ultrasound plays an important role in modulating crystallite size, surface charge and its adsorption performance for a xylene milling yellow 6G dye. Among all the sonicated ceria samples, IPA mediated ceria exhibited highest positive zeta potential and hence was found to be proficient for the complete removal of dye in 15?min. Furthermore, the adsorption of the yellow milling dye on the surface of (IPA mediated) sonicated ceria sample has shown to follow pseudo-first order kinetic model. The non-sonicated sample (prepared in MeOH solvent without ultrasound) shows negligible dye adsorption while sonicated sample reveals 50% removal of XMY dye due to the difference in zeta potential values resulted from the cavitation effects.     

Designing ergonomic interventions for EMS workers - part II: lateral transfers

The objective of the current work was to test ergonomic interventions aimed at reducing the low back musculoskeletal loads experienced by firefighters/paramedics (FFPs) providing emergency medical services (EMS) when performing lateral transfers between a bed and a stretcher or between a stretcher and a hospital gurney. The interventions, developed using focus groups, were a bridgeboard to reduce the frictional force resisting the lateral sliding of the patient, the use of rods along each side of the patient to facilitate the grasping and handling of the bedsheet on which the patient is typically transferred, and a single rod that, when rolled in the bedsheet, resulted in the task being changed from a lifting task to a pulling task. Eleven two-person teams laterally transferred a 75 kg dummy with each intervention between a bed and simulated stretcher. Two roles were defined. For the two-sided transfers, the FFP roles were termed "stretcher-side" and "bed-side." Surface electromyographic (EMG) data were collected from 8 trunk muscles from each participant along with spine kinematic data. Additionally, kinetic data were obtained for the FFP in the stretcher-side role. Trunk flexion moments and Erector Spinae activity were reduced for the FFP in the stretcher-side role when using the bridgeboard and the single rod both individually and in combination. The single rod reduced the Erector Spinae activity in the FFP who typically would have been on the bed. For FFPs in both roles the single rod increased Latissimus Dorsi activation relative to the standard bedsheet transfer condition, although, this effect was moderated when the single rod was used in combination with the bridgeboard. Ratings of perceived exertion also supported the use of the single rod relative to the corresponding control condition.