Preparation of gold nanoparticles (GNP) aqueous suspensions by a new method involving Tiron

A new method is proposed to produce gold nanoparticles (GNP) by in situ reduction of a gold salt dissolved in water. The reducing agent used is Tiron instead of the citrate anion most often mentioned in literature. The influence of various parameters has been investigated, such as the content of Tiron with respect to that of the precursor of gold HAuCl₄, or the initial pH of the solution after mixing of reactants. It is shown that Tiron also exerts a positive influence as a dispersant, which impedes agglomeration of gold nanoparticles. The typical average size of GNP synthesized in the present work is close to 7 nm.     

Stimulation of negative magnetoresistance by an electric field and light in silicon doped with boron and manganese

It is experimentally ascertained that light stimulates the negative magnetoresistance observed in a high electric field in silicon doped with boron and manganese. The optimum conditions (the electric field, temperature, illumination, and resistivity of the material) for observation of the largest magnitude of negative magnetoresistance in (Si:B):Mn are determined. The dependence of the negative magnetoresistance on the concentration of compensating impurity is established.     

The stress intensity factors for a short crack partially penetrating an inclusion of arbitrary shape

Some approximate solutions for predicting the stress intensity factor of a short crack penetrating an inclusion of arbitrary shape have been developed under mode I and mode II loading conditions. The derivation of the fundamental formula is based on the transformation toughening theory. The transformation strains in the inclusion are induced by the crack-tip field and remotely applied stresses, and approximately evaluated by the Eshelby equivalent inclusion theory. As validated by detailed finite element (FE) analyses, the developed solutions have good accuracy for different inclusion shape and for a wide range of modulus ratio between inclusion and matrix material.     

Evidence of High Vertical Wave-Number Behavior in a Continuously Stratified Reservoir: Boadella, Spain

High vertical wave-number modes clearly dominate the internal wave field during the stratification period in Boadella reservoir in northeast Spain. In this period, the extraction of hypolimnetic water, due to summer irrigation, brought the surface level down by 6 m in one month and the epilimnetic water progressively occupied the whole water column. The temperature profile, with the exception of a few meters at the surface layer, presented an almost constant temperature gradient of about 0.7°C/m. The period of the main vertical mode is 24 h with an amplitude of around 1 m. Thermistor chain records and meteorological data allow us to deduce that this mode is, at least, a third vertical mode forced by the wind, which normally has a typical periodicity of 24 h. However, when the wind changes direction from south to north, the circulation cells developed due to this forced nonstationary oscillation are destroyed. When this occurs, the Bulk Richardson number is Rib ～ 1. Similar vertical structures as a response to wind forcing should be expected in similar systems, although this has not been reported in the literature.     

An overview of nondestructive evaluation methods

ondestructive evaluation is described as nondestructive testing (NDT), nondestructive inspection (NDI), and nondestructive examination (NDE). The activities associated with the evaluation include testing, inspection, and examination and primarily involve looking at (or through) and/or measuring some characteristic of an object. Frequently there is a desire to determine some characteristic of the object or to determine whether the object contains irregularities, discontinuities, or flaws. These examinations, inspections, or tests are used to determine the physical soundness of a material without impairing its usefulness. Nondestructive evaluation is a powerful tool that can help assure safety, quality, and reliability; increase productivity; decrease liability; protect the environment; and save money. In this article, nondestructive evaluation is represented by the acronym NDE.     

Influence of the preparation conditions on the size and morphology of nanocrystalline lanthanum orthoferrite

Nanocrystalline LaFeO₃ is prepared by the dehydration of coprecipitated lanthanum and iron(III) hydroxides. It is shown that the behavior of the samples during heating and the size distribution of LaFeO₃ nanocrystals can be considerably different depending on the scheme used for coprecipitation of lanthanum and iron hydroxides; independently of the method employed for coprecipitation of the initial compounds, sintering of the samples at 950°C leads to the formation of lanthanum orthoferrite crystals up to 100 nm in size.     

Synthesis of polyanilines with pendant fluorescent units

Functionalized polyanilines containing biphenyl, terphenyl, carbazole, anthracene, and 4-n-hexylphenyl moieties were synthesized though the reaction of polyaniline in emeraldine base form with sodium salt of corresponding vinylketoaromatics with quantitative yields. Polymers were characterized with Fourier transform infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, and thermogravimetry. The emission characteristics of these polymers in N-methyl-2-pyrrolidone solution were examined. The functionalized polyanilines exhibited an intense green emission.