Transient operation of a solid oxide electrolysis cell

In order to investigate the transient behaviour of a solid oxide electrolysis cell, tests were carried out on a single SOEC both under steady-state and transient conditions for 600 h. Steady-state operation was performed at the reference current of −20 A, corresponding to the thermoneutral voltage (1.28 V), whereas transient tests consisted in 1800 square waves applied over 140 cumulated hours, with a current of −1 A and −20 A as well as 0 A and −20 A. Independently from the operating conditions, the measured voltage degradation rate of 5% (70 mV)/1000 h was stable for the entire experiment. Consequently, it was concluded that an SOEC can be operated under on–off conditions with no increase of the degradation rate. This result paves the way for modular operation of a high temperature electrolyser fed with intermittent electrical energy.     

Nonlinear theory of a free-electron laser exploiting media with aperiodically modulated refractive index

The nonlinear theory of a free-electron laser (FEL) exploiting media with a periodically modulated refractive index is presented. The gain and the saturation parameters are found for different operating regimes of such a FEL. The system discussed could be used for the amplification of light in the optical and ultraviolet regions of the spectrum     

Luminal bacteria and small-intestinal permeability

BACKGROUND: The influence of luminal bacteria on small-intestinal permeability has not been fully assessed. This study addressed this issue. METHODS: Thirty-four subjects (mean age 64 years; range 22-95 years) were investigated for possible small-intestinal bacterial overgrowth (SIBO) with culture of a small-intestinal aspirate. A lactulose/mannitol small-intestinal permeability test was performed, small-intestinal histology assessed and serum vitamin B12 concentrations measured in all subjects. Permeability was also assessed in a control group of 34 asymptomatic volunteers. RESULTS: Urinary lactulose/mannitol ratios were significantly increased in subjects with SIBO with colonic-type flora (P < 0.0005), even in the absence of villous atrophy. Urinary lactulose/mannitol ratios were increased in this group due to significantly increased urinary lactulose concentrations (P < 0.0005) rather than reduced urinary mannitol levels, after correcting for inter-subject variations in renal function. Counts of intraepithelial lymphocytes of CD8 phenotype were significantly increased in this group (P = 0.003). Although a significant correlation was found between intraepithelial lymphocyte counts and small-intestinal permeability overall (P < 0.002), these counts were not significantly different in subjects with SIBO with colonic-type flora whose permeability values were < or = > 0.028, the upper limit of normal in asymptomatic controls. Serum vitamin B12 concentrations did not differ significantly between groups (P > 0.5). Ageing did not independently influence small-intestinal permeability (P > 0.5). CONCLUSIONS: Small-intestinal permeability is increased in subjects with SIBO with colonic-type bacteria. This effect is independent of ageing and not mediated by vitamin B12 deficiency. Although counts of intraepithelial lymphocytes of CD8 phenotype are increased in this disorder, it is also unlikely that these cells play an important causative role in this process. Routine light microscopic assessment underestimates the prevalence of small-intestinal functional disturbance in this disorder.     

Water waves in the time domain

The initial-value problem for a structure floating on the surface of the sea is investigated under the assumptions of linear theory. Fourier transforms are used to connect the time- and frequency-domain representations of the coupled motion of the fluid and body. This allows the large-time asymptotics of the motion to be obtained from the singularity structure of the frequency-domain potential in the complex plane. Under certain initial conditions, the free motion of a body about a fixed, equilibrium position is shown not to exist for all time, and in this case the assumptions behind the linear theory are violated. For suitably moored structures, motion is found which is purely exponentially decaying in time and does not involve any oscillations.     

Frequency-tunable optically pumped carbon monoxide laser

Single-line frequency-tunable lasing was observed in an optically pumped, repetitively pulsed, room-temperature CO laser for the first time. The R(0) and R(7) ro-vibrational transitions in the (2,0) overtone of CO at 2.3 μm were optically pumped with a high-energy optical parametric oscillator. Single-line lasing was observed on (2,1) P(2)-P(17) transitions and R(0)-R(11) transitions (covering wavelengths within the range 4.6-4.9 μm) when using a diffraction grating as the spectrally selective reflector of the laser resonator. The observed CO laser pulse lengths were ~10^-7 s with peak power up to 10⁴ W. The influence of CO pressure, the addition of buffer gas (He, Ar), Q-factor of the laser resonator, and the pump pulse energy on CO laser pulse temporal characteristics and output energy spectral distribution was studied experimentally     

Control over topological insulator photocurrents with light polarization

Three-dimensional topological insulators represent a new quantum phase of matter with spin-polarized surface states that are protected from backscattering. The static electronic properties of these surface states have been comprehensively imaged by both photoemission and tunnelling spectroscopies. Theorists have proposed that topological surface states can also exhibit novel electronic responses to light, such as topological quantum phase transitions and spin-polarized electrical currents. However, the effects of optically driving a topological insulator out of equilibrium have remained largely unexplored experimentally, and no photocurrents have been measured. Here, we show that illuminating the topological insulator Bi(2)Se(3) with circularly polarized light generates a photocurrent that originates from topological helical Dirac fermions, and that reversing the helicity of the light reverses the direction of the photocurrent. We also observe a photocurrent that is controlled by the linear polarization of light and argue that it may also have a topological surface state origin. This approach may allow the probing of dynamic properties of topological insulators and lead to novel opto-spintronic devices.     

Bloch equations and completely positive maps

Abstract

The phenomenological dissipation of the Bloch equations is re-examined in the context of completely positive maps. Such maps occur if the dissipation arises from a reduction of a unitary evolution of a system coupled to a reservoir. In such a case the reduced dynamics for the system alone will always yield completely positive maps of the density operator. We show that, for Markovian Bloch maps, the requirement of complete positivity imposes some Bloch inequalities on the phenomenological damping constants. For non-Markovian Bloch maps some kind of Bloch inequalities involving eigenvalues of the damping basis can be established as well. As an illustration of these general properties we use the depolarizing channel with white and coloured stochastic noise.