Highly Crystalline Soluble Acene Crystal Arrays for Organic Transistors: Mechanism of Crystal Growth During Dip‐Coating

The preparation of uniform large‐area highly crystalline organic semiconductor thin films that show outstanding carrier mobilities remains a challenge in the field of organic electronics, including organic field‐effect transistors. Quantitative control over the drying speed during dip‐coating permits optimization of the organic semiconductor film formation, although the kinetics of crystallization at the air–solution–substrate contact line are still not well understood. Here, we report the facile one‐step growth of self‐aligning, highly crystalline soluble acene crystal arrays that exhibit excellent field‐effect mobilities (up to 1.5 cm V^?1 s^?1) via an optimized dip‐coating process. We discover that optimized acene crystals grew at a particular substrate lifting‐rate in the presence of low boiling point solvents, such as dichloromethane (b.p. of 40.0 °C) or chloroform (b.p. of 60.4 °C). Variable‐temperature dip‐coating experiments using various solvents and lift rates are performed to elucidate the crystallization behavior. This bottom‐up study of soluble acene crystal growth during dip‐coating provides conditions under which one may obtain uniform organic semiconductor crystal arrays with high crystallinity and mobilities over large substrate areas, regardless of the substrate geometry (wafer substrates or cylinder‐shaped substrates).     

Open‐Shell Donor–Acceptor Conjugated Polymers with High Electrical Conductivity

Conductive polymers largely derive their electronic functionality from chemical doping, processes by which redox and charge‐transfer reactions form mobile carriers. While decades of research have demonstrated fundamentally new technologies that merge the unique functionality of these materials with the chemical versatility of macromolecules, doping and the resultant material properties are not ideal for many applications. Here, it is demonstrated that open‐shell conjugated polymers comprised of alternating cyclopentadithiophene and thiadiazoloquinoxaline units can achieve high electrical conductivities in their native “undoped” form. Spectroscopic, electrochemical, electron paramagnetic resonance, and magnetic susceptibility measurements demonstrate that this donor–acceptor architecture promotes very narrow bandgaps, strong electronic correlations, high‐spin ground states, and long‐range π‐delocalization. A comparative study of structural variants and processing methodologies demonstrates that the conductivity can be tuned up to 8.18 S cm^?1. This exceeds other neutral narrow bandgap conjugated polymers, many doped polymers, radical conductors, and is comparable to commercial grades of poly(styrene‐sulfonate)‐doped poly(3,4‐ethylenedioxythiophene). X‐ray and morphological studies trace the high conductivity to rigid backbone conformations emanating from strong π‐interactions and long‐range ordered structures formed through self‐organization that lead to a network of delocalized open‐shell sites in electronic communication. The results offer a new platform for the transport of charge in molecular systems.     

提供过电流和过电压保护的断路器

图1中的断路器仅需几个廉价的元件,即可对过电流和过电压故障状态进行反应.电路的核心是可调节的精密分路电压调节器D2,置在一只3引脚的封装中,提供了电压参考、比较器和集电极开路输出.     

Automatic detection and quantification of tree-in-bud (TIB) opacities from CT scans

This study presents a novel computer-assisted detection (CAD) system for automatically detecting and precisely quantifying abnormal nodular branching opacities in chest computed tomography (CT), termed tree-in-bud (TIB) opacities by radiology literature. The developed CAD system in this study is based on 1) fast localization of candidate imaging patterns using local scale information of the images, and 2) M?bius invariant feature extraction method based on learned local shape and texture properties of TIB patterns. For fast localization of candidate imaging patterns, we use ball-scale filtering and, based on the observation of the pattern of interest, a suitable scale selection is used to retain only small size patterns. Once candidate abnormality patterns are identified, we extract proposed shape features from regions where at least one candidate pattern occupies. The comparative evaluation of the proposed method with commonly used CAD methods is presented with a dataset of 60 chest CTs (laboratory confirmed 39 viral bronchiolitis human parainfluenza CTs and 21 normal chest CTs). The quantitative results are presented as the area under the receiver operator characteristics curves and a computer score (volume affected by TIB) provided as an output of the CAD system. In addition, a visual grading scheme is applied to the patient data by three well-trained radiologists. Interobserver and observer-computer agreements are obtained by the relevant statistical methods over different lung zones. Experimental results demonstrate that the proposed CAD system can achieve high detection rates with an overall accuracy of 90.96%. Moreover, correlations of observer-observer (R(2)=0.8848, and observer-CAD agreements (R(2)=0.824, validate the feasibility of the use of the proposed CAD system in detecting and quantifying TIB patterns.     

Three-dimensional segmentation and growth-rate estimation of small pulmonary nodules in helical CT images

Small pulmonary nodules are a common radiographic finding that presents an important diagnostic challenge in contemporary medicine. While pulmonary nodules are the major radiographic indicator of lung cancer, they may also be signs of a variety of benign conditions. Measurement of nodule growth rate over time has been shown to be the most promising tool in distinguishing malignant from nonmalignant pulmonary nodules. In this paper, we describe three-dimensional (3-D) methods for the segmentation, analysis, and characterization of small pulmonary nodules imaged using computed tomography (CT). Methods for the isotropic resampling of anisotropic CT data are discussed. 3-D intensity and morphology-based segmentation algorithms are discussed for several classes of nodules. New models and methods for volumetric growth characterization based on longitudinal CT studies are developed. The results of segmentation and growth characterization methods based on in vivo studies are described. The methods presented are promising in their ability to distinguish malignant from nonmalignant pulmonary nodules and represent the first such system in clinical use.     

Energetics of Donor‐Doping,Metal Vacancies,and Oxygen‐Loss in A‐Site Rare‐Earth‐Doped BaTiO3

The energetics of La‐doping in BaTiO₃ are reported for both (electronic) donor‐doping with the creation of Ti³⁺ cations and ionic doping with the creation of Ti vacancies. The experiments (for samples prepared in air) and simulations demonstrate that ionic doping is the preferred mechanism for all concentrations of La‐doping. The apparent disagreement with electrical conduction of these ionic doped samples is explained by subsequent oxygen‐loss, which leads to the creation of Ti³⁺ cations. Simulations show that oxygen‐loss is much more favorable in the ionic‐doped system than undoped BaTiO₃ due to the unique local structure created around the defect site. These findings resolve the so‐called “donor‐doping” anomaly in BaTiO₃ and explain the source of semiconductivity in positive temperature coefficient of resistance (PTCR) BaTiO₃ thermistors.     

Handover approaches for seamless mobility management in next generation wireless networks

Next generation wireless networks (NGWN) will be an integration of heterogeneous wireless access networks that will interwork over an IP‐based infrastructure. This all‐IP vision has led to the development of handover mechanisms to support seamless mobility for active network services among the different interworking wireless networks in order to ensure network access ubiquity in NGWN. These handover mechanisms need to ensure that mobile devices continue to receive ongoing communication without any noticeable disruption during handover events among the heterogeneous networks. This paper gives a qualitative and quantitative review of current handover approaches of IP mobility management protocols for NGWN with an objective to introduce a new way of further optimizing the handover performance. In particular, the paper focuses on handover approaches of mobile IPv6 (MIPv6) based mobility management protocols. Thus, the need, benefits, and limitations of these handover approaches are explored. Thereafter, dynamic handover coordination is introduced as a new viable solution that exploits the benefits and mitigates the limitations of these handover approaches hence improving handover performance in terms of handover delay, packet loss, and signaling overhead. Copyright © 2011 John Wiley & Sons, Ltd.     

Power Control for Link Quality Protection in Cellular DS-CDMA Networks with Integrated (Packet and Circuit) Services

The problem of admission control in a DS-CDMA network carrying a heterogeneous mix of traffic is addressed. In an interference limited system such as DS-CDMA, admission of a new user impacts the performance of all other users, as well as the system capacity. The admission process is concerned with two factors: (1) maintaining the QoS of active users, (2) allocating bandwidth to new users. We propose a simple power control algorithm and prove that it is optimal in the sense of maintaining active link quality while maximizing free capacity for new admissions. The algorithm scales the powers of active links appropriately to achieve link protection and improved tolerance of the link to new interference from bursty sources. This algorithm can be used to overlay bursty packet data services without compromising QoS of active circuits.     

Energy-Efficient Broadcast and Multicast Trees in Wireless Networks

The wireless networking environment presents formidable challenges to the study of broadcasting and multicasting problems. In this paper we focus on the problem of multicast tree construction, and we introduce and evaluate algorithms for tree construction in infrastructureless, all-wireless applications. The performance metric used to evaluate broadcast and multicast trees is energy-efficiency. We develop the Broadcast Incremental Power (BIP) algorithm, and adapt it to multicast operation by introducing the Multicast Incremental Power (MIP) algorithm. These algorithms exploit the broadcast nature of the wireless communication environment, and address the need for energy-efficient operation. We demonstrate that our algorithms provide better performance than algorithms that have been developed for the link-based, wired environment.