Pervaporation separation of IPA‐water mixtures through 4A zeolite‐filled sodium alginate membranes

Incorporation of zeolites into natural polymers has been shown experimentally to enhance both the flux and selectivity in pervaporative dehydration separation of organic compounds. Pervaporation is a promising membrane technique for separation of volatile organic compounds (VOCs)/water mixtures. In this study, hydrophilic sodium alginate (SA) mixed membranes were prepared using solution casting technique by incorporating zeolites into the polymer matrix. The prepared membranes were characterized by ATR‐Fourier transform infrared spectroscopy (FTIR), X‐ray diffraction (XRD), scanning electron microscopy (SEM), Thermal Gravimetric Analysis (TGA), and differential scanning calorimetry (DSC) were tested in a laboratory scale pervaporation experimental set‐up. The effect of experimental parameters such as the type and composition of zeolites on permeation flux and selectivity was investigated. When tested on IPA‐water mixtures, the zeolite‐filled membrane was found to give much higher selectivity. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Magnesium and iron loaded hollow glass microspheres (HGMs) for hydrogen storage

The development of a safe and efficient method for hydrogen storage is essential for the use of hydrogen with fuel cells for vehicular applications. Hollow glass microspheres (HGMs) have characteristics suitable for hydrogen storage and are expected to be a potential hydrogen carrier to be used for energy release applications. The HGMs with 10–100 μm diameters, 100–1000 Å pore width and 3–8 μm wall thicknesses are expected to be useful for hydrogen storage. In our research we have prepared HGMs from amber glass powder of particle size 63–75 μm using flame spheroidisation method. The HGMs samples with magnesium and iron loading were also prepared to improve the heat transfer property and thereby increase the hydrogen storage capacity of the product. The feed glass powder was impregnated with calculated amount of magnesium nitrate hexahydrate salt solution to get 0.2–3.0 wt% Mg loading on HGMs. Required amount of ferrous chloride tetrahydrate solution was mixed thoroughly with the glass feed powder to prepare 0.2–2 wt% Fe loaded HGMs. Characterizations of all the HGMs samples were done using FEG-SEM, ESEM and FTIR techniques. Adsorption of hydrogen on all the Fe and Mg loaded HGMs at 10 bar pressure was conducted at room temperature and at 200 °C, for 5 h. The hydrogen adsorption capacity of Fe loaded sample was about 0.56 and 0.21 weight percent for Fe loading 0.5 and 2.0 weight percentage respectively. The magnesium loaded samples showed an increase of hydrogen adsorption from 1.23 to 2.0 weight percentage when the magnesium loading percentage was increased from 0 to 2.0. When the magnesium loading on HGMs was increased beyond 2%, formation of nano-crystals of MgO and Mg was seen on the HGMs leading to pore closure and thereby reduction in hydrogen storage capacity.     

A direct borohydride fuel cell employing Prussian Blue as mediated electron-transfer hydrogen peroxide reduction catalyst

A direct borohydride-hydrogen peroxide fuel cell employing carbon-supported Prussian Blue (PB) as mediated electron-transfer cathode catalyst is reported. While operating at 30 °C, the direct borohydride-hydrogen peroxide fuel cell employing carbon-supported PB cathode catalyst shows superior performance with the maximum output power density of 68 mW cm⁻² at an operating voltage of 1.1 V compared to direct borohydride-hydrogen peroxide fuel cell employing the conventional gold-based cathode with the maximum output power density of 47 mW cm⁻² at an operating voltage of 0.7 V. X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and Energy Dispersive X-ray Analysis (EDAX) suggest that anchoring of Cetyl-Trimethyl Ammonium Bromide (CTAB) as a surfactant moiety on carbon-supported PB affects the catalyst morphology. Polarization studies on direct borohydride-hydrogen peroxide fuel cell with carbon-supported CTAB-anchored PB cathode exhibit better performance with the maximum output power density of 50 mW cm⁻² at an operating voltage of 1 V than the direct borohydride-hydrogen peroxide fuel cell with carbon-supported Prussian Blue without CTAB with the maximum output power density of 29 mW cm⁻² at an operating voltage of 1 V.     

Optimal design of customised hip prosthesis using fiber reinforced polymer composites

The need for new materials in orthopaedic surgery arises from the recognition of the stress-shielding effect of bone by high-modulus implants presently made of engineering alloys. A lower modulus implant material will result in the construction of a more biomechanically compatible prosthesis. In this respect, composite materials are gaining importance because they offer the potential for implants with tailor-made stiffness in contrast to metals. In the present study, the bending stiffness of composite prosthesis is matched with that of bone in both the longitudinal and radial directions by choosing optimal carbon fiber reinforced polyether ether ketone (PEEK) matrix lay-up. A numerical optimization algorithm is developed to deduce the optimal composite femoral prosthesis lay-up that matches the stiffness properties of the femoral bone in both the transverse and longitudinal directions. Effective bending moments and compressive forces acting on the hip joint are considered in the design of the optimal length and diameter of the prosthesis. The optimization algorithm was implemented, by using MATLAB(R)™ for designing the composite prosthesis to a patient’s specific requirement. Finally the efficiency of the composite stem is compared with that of metallic alloy stems in terms of stress shielding using a finite element program.     

The Impact of Mobility on Cellular Network Configuration

This paper proposes a model for configuring cellular networks to study the dynamics of mobility between a single cell and its adjacent cells. It differs from most models considered in the literature by explicitly incorporating the dependency between the handoff rate and the system state. Besides, the handoff rate is also a function of cell size and subscriber mobility. Extensive computational experiments were done to study the impact of various input parameters on specific performance measures. Several observations are made regarding the system performance and as to how they are affected by the complex interaction between subscriber mobility, cell size, number of channels and the mean call initiation rate. The results of these experiments show that the proposed model, where handoff rates are state-dependent, captures additional traffic due to mobility when compared to the traditional method of modeling handoffs using information about the average behavior. Finally, the economic impact of mobility on system configuration decisions is analyzed. Though an approximation, the above work provides interesting insights about the impact of mobility in configuring cellular networks.     

Time-varying system identification using modulating functions and spline models with application to bio-processes

Time dependent parameters are frequently encountered in many real processes which need to be monitored for process modeling, control and supervision purposes. Modulating functions methods are especially suitable for this task because they use the original continuous-time differential equations and avoid differentiation of noisy signals. Among the many versions of the method available, Pearson–Lee method offers a computationally efficient alternative. In this paper, Pearson–Lee method is generalized for non-stationary continuous-time systems and the on-line version is developed. The time dependent parameters are modeled as polynomial splines inside a moving data window and recursion formulae using shifting properties of sinusoids are formulated. The simple matrix update relations considerably reduce the number of computations required when compared with repeatedly using FFT. The method is illustrated for estimating the kinetic rates and yield factors as time-varying parameters in a fermentation process. The Monod law along with temperature dependency models were used to simulate the data. The simulation study shows that it is not necessary to assume a growth model in order to estimate the kinetic rate parameters.     

Waveguide Cross Section and Background Magnetic Field Tapers for Broadbanding a Gyro-TWT

The gyro-TWT in a cylindrical waveguide of linearly-tapered cross section was analyzed for the gain-frequency response, using the Pierce-type gain equation. The taper in the waveguide cross section was adjusted for wide device bandwidths, either by changing the taper angle, while keeping the interaction length to be constant, or by changing the interaction length, while keeping the initial and final radii of the waveguide constant. Tapering led to the prediction of wide bandwidths, though at the cost of gain, as compared to a non-tapered device. The range of the DC background magnetic flux density relative to its grazing-point value was identified as a crucial parameter for large gains, with appreciable bandwidths, and minimum mode mixing in a tapered device, the latter in general facing more mode competition than a non-tapered device.     

Risk intermediation in supply chains

This paper demonstrates that an important role of intermediaries in supply chains is to reduce the financial risk faced by retailers. It is well known that risk averse retailers when faced by the classical single-period inventory (newsvendor) problem will order less than the expected value maximizing (newsboy) quantity. We show that in such situations a risk neutral distributor can offer a menu of mutually beneficial contracts to the retailers. We show that a menu can be designed to simultaneously: (i) induce every risk averse retailer to select a unique contract from it; (ii) maximize the distributor's expected profit; and (iii) raise the order quantity of the retailers to the expected value maximizing quantity. Thus inefficiency created due to risk aversion on part of the retailers can be avoided. We also investigate the influence of product/market characteristics on the offered menu of contracts.     

Modeling pipeline crevice corrosion under a disbonded coating with or without cathodic protection under transient and steady state conditions

Underground steel pipelines are protected by coatings and cathodic protection (CP). The pipeline corrosion occurs when the coating is disbonded away from a defect or holiday to form a crevice and the corrosion rate varies temporally and spatially in the crevice. In the presence of dissolved oxygen (O₂) in soil ground water, a differential O₂ concentration cell may develop in the crevice because O₂ diffuses more readily into the crevice through the holiday than through the disbonded coating. CP can decrease or eliminate the O₂ concentration cell depending on the potential applied at the holiday. Since the coatings are usually non-conductive, CP is unable to protect the steel surface deep inside the crevice. The transport of dissolved O₂, and that of dissolved carbon dioxide (CO₂) if present, into the crevice through holiday can be key to determining the crevice corrosion rate. In this work, the transient and steady state behavior of the corrosion process is investigated. The effect of the cathodic portion of iron vs. ferrous ion redox reaction on the crevice corrosion rate, which is often neglected traditionally, is further studied. At steady state, the effect of dissolved O₂ on the crevice corrosion rate and the added effect of dissolved CO₂ are mathematically modeled.     

Suspended aluminum nitride structures grown via metal organic vapor phase epitaxy

The development of III-Nitride suspended structures for Micro-Electro Mechanical Systems (MEMS) and Nano-Electro Mechanical Systems (NEMS) is challenging due to lack of selective etching techniques. Recent efforts have focused on the removal of sacrificial layers based on material properties, such as crystalline quality, bandgap, polarity, doping, etc. These techniques require several processing steps in addition to precise control over the sacrificial and functional layer properties. In this work, conditions have been identified for the growth of etch-resistant polycrystalline AlN films via Metal Organic Vapor Phase Epitaxy (MOVPE) on silicon oxide surfaces, thus allowing silicon oxide to be used as a sacrificial layer in a surface micro-machining process. The MOVPE growth conditions reported result in a well oriented crystal with superior mechanical strength demonstrated by the fabrication of unsupported AlN structures with widths from 5 μm to 110 μm and air gaps ranging from 200 nm to 800 nm. This technique simplifies the fabrication process of AlN suspended structures and is well suited for achieving group III-Nitride heteroepitaxial MEMS/NEMS systems.