The viscoelastic and mechanical properties of composites multi walled carbon nanotube (MWNT)/epoxy at different weight fractions (0.1, 0.5, 1 and 2 wt.%) were evaluated by performing tensile and dynamic-mechanical thermal analysis (DMTA) tests. The MWNT/epoxy composite were fabricated by sonication and a cast molding process. The results showed that addition of nanotubes to epoxy had significant effect on the viscoelastic and mechanical properties. However, the use of 0.5 wt.% increased the viscoelastic properties more significantly. Concerning viscoelastic modeling, the COLE–COLE diagram has been plotted by the results of DMTA test. These results show a good agreement between the Perez model and the viscoelastic behavior of the composite. 相似文献
Organic semiconductor to metal Schottky contacts have been widely used in electronic devices and to investigate the properties of organic semiconductors. In designing and characterizing these devices the full depletion approximation is used. The analytical and numerical simulations presented in this paper suggest that this approximation is not generally valid. Simulations of a Schottky contact between regioregular-poly 3 hexylthiophene (rr-P3HT) and aluminum show that this approximation becomes worse as molecular order decreases, with the potential profile increasingly deviating from the expected quadratic function of position. Also the depletion width decreasing well below that predicted using the approximation. In this work the slope of the band tail is used as a measure of disorder. 相似文献
In this study, the mechanical properties of the composite plate were considered Gaussian random fields and their effects on the buckling load and corresponding mode shapes were studied by developing a semi-analytical non-intrusive approach. The random fields were decomposed by the Karhunen−Loève method. The strains were defined based on the assumptions of the first-order and higher-order shear-deformation theories. Stochastic equations of motion were extracted using Euler–Lagrange equations. The probabilistic response space was obtained by employing the non-intrusive polynomial chaos method. Finally, the effect of spatially varying stochastic properties on the critical load of the plate and the irregularity of buckling mode shapes and their sequences were studied for the first time. Our findings showed that different shear deformation plate theories could significantly influence the reliability of thicker plates under compressive loading. It is suggested that a linear relationship exists between the mechanical properties’ variation coefficient and critical loads’ variation coefficient. Also, in modeling the plate properties as random fields, a significant stochastic irregularity is obtained in buckling mode shapes, which is crucial in practical applications. 相似文献
Objective: The objective of this study was to fabricate double-walled poly(lactide-co-glycolide) (PLGA) microspheres to increase encapsulation efficiency and avoid rapid release of hydrophilic drugs such as meglumine antimoniate.
Methods: In this study, double-walled and one-layered microspheres of PLGA were prepared using the emulsion solvent evaporation technique to better control the release of a hydrophilic drug, meglumine antimoniate (Glucantime®), which is the first choice treatment of cutaneous leishmaniasis. The effect of hydrophobic coating on microspheres' size, morphology, encapsulation efficiency and drug release characteristics was evaluated. Furthermore, the presence of antimony in meglumine antimoniate made it possible to observe the drug distribution within the microspheres' cross section by means of energy dispersive X-ray spectroscopy.
Results: Drug distribution images confirmed accumulation of the drug within the inner core of double-walled microspheres. In addition, these microspheres encapsulated the drug more efficiently up to 87% and demonstrated reduced initial burst and prolonged release compared to one-layered microspheres. These superiorities make double-walled microspheres an optimum candidate for sustained delivery of hydrophilic drugs.
Conclusion: Double-walled microspheres provide some advantages over traditional microspheres overcoming most of their limitations. Double-walled microspheres were found to be more efficient than their corresponding one-layered microspheres in terms of encapsulation efficiencies and release characteristics. 相似文献
This study examines the effect of random heterogeneity of soil properties on bearing capacity. The stochastic soil property considered is the undrained shear strength and two major sources of uncertainty are identified with it: inherent spatial variability (modeled as a non-Gaussian, homogeneous stochastic field) and uncertainty in the estimation of its expected value (modeled as a random variable). The two sources of uncertainty are treated separately, before being eventually combined. A Monte Carlo simulation approach is followed in combination with non-linear finite element analysis. It is demonstrated that the inherent spatial variability of soil shear strength can drastically modify the basic form of the failure mechanism in this bearing capacity problem. Consequently, there is no ‘average’ failure mechanism (surface) in this problem, leading to the conclusion that Monte Carlo simulation is the only methodology capable of providing a solution to this geomechanics problem. It is further demonstrated that this behavior of the failure mechanism translates into a substantial reduction in the ultimate bearing capacity (in an average sense), compared to the corresponding deterministic (homogeneous soil) case. In addition, differential settlements are computed in the stochastic analysis, something impossible in a deterministic analysis of a symmetric problem. A parametric study is performed using fragility curves to investigate the effects of various probabilistic parameters involved in the problem. It is found that the coefficient of variation and the marginal probability distribution of the soil's shear strength (both controlling the amount of loose pockets in the soil mass) are the two most important parameters in reducing the bearing capacity (in an average sense) and producing substantial differential settlements in heterogeneous soils (compared to homogeneous soils). A technique is finally introduced for determining ‘overall’ fragility curves that account for both inherent soil spatial variability and uncertainty in the expected value of soil strength. Based on such ‘overall’ fragility curves obtained at failure (ultimate bearing capacity), nominal values of the bearing capacity of a heterogeneous soil deposit corresponding to an exceedance probability of 5% are established for a range of probabilistic characteristics. 相似文献
The flow properties of ketchup were assessed upon addition of commonly used food thickeners: guar, xanthan and CMC gum at three different concentrations (0.5%, 0.75% and 1%) and four temperatures (25, 35, 45 and 55 °C). The ketchup without supplementation served as a control. All ketchup formulations exhibited non-Newtonian, pseudoplastic behaviour at all temperatures and hydrocolloid levels. The Power-law and Herschel-Buckley model were successfully applied to fit the shear stress versus shear rate data. The flow behaviour indices, n and n' , varied in the range of 0.189–0.228 and 0.216–0.263, respectively. The consistency coefficients, k and k' , were in the range of 8.42–27.22 and 6.56–20.10 Pa s n , respectively. The addition of hydrocolloids increased the yield point (τ0) and apparent viscosity of the ketchup in comparison to that of the control. The Arrhenius equation was successfully used to describe the effects of temperature on the apparent viscosity of the prepared formulations. The E a value appeared in the range between 5492.6 and 21475.8 J mol−1. 相似文献
Non-ideal explosives can have Chapman-Jouguet (C-J) detonation pressure significantly different from those expected from existing thermodynamic computer codes, which usually allows finding the parameters of ideal detonation of individual high explosives with good accuracy. A simple method is introduced by which detonation pressure of non-ideal aluminized explosives with general formula C(a)H(b)N(c)O(d)Al(e) can be predicted only from a, b, c, d and e at any loading density without using any assumed detonation products and experimental data. Calculated detonation pressures show good agreement with experimental values with respect to computed results obtained by complicated computer code. It is shown here how loading density and atomic composition can be integrated into an empirical formula for predicting detonation pressure of proposed aluminized explosives. 相似文献
The design of high-rise buildings often necessitates ground excavation, where buildings are in close proximity to the construction, thus there is a potential for damage to these structures. This paper studies an efficient user-friendly framework for dealing with uncertainties in a deep excavation in layers of cemented coarse grained soil located in Tehran, Iran by non-deterministic Random Set (RS) method. In order to enhance the acceptability of the method among engineers, a pertinent code was written in FISH language of FLAC2D software which enables the designers to run all simulations simultaneously, without cumbersome procedure of changing input variables in every individual analysis. This could drastically decrease the computational effort and cost imposed to the project, which is of great importance especially to the owners. The results are presented in terms of probability of occurrence and most likely values of the horizontal displacement at top of the wall at every stage of construction. Moreover, a methodology for assessing the credibility of the uncertainty model is presented using a quality indicator. It was concluded that performing RS analysis before the beginning of every stage could cause great economical savings, while improving the safety of the project. 相似文献