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61.
International Journal of Information Security - The growing number of Internet users and the prevalence of web applications make it necessary to deal with very complex software and applications in...  相似文献   
62.
Here, we propose a new method for estimating the extent of curing of thermosetting prepregs. In the proposed method, the extent of curing is estimated with the curing index (Ci), defined as the ratio of the glass‐transition temperature (Tg) to the ultimate glass‐transition temperature of the material. The advantages of this new method over the conventional degree of conversion (α) for estimating the extent of curing of thermosetting prepregs are discussed in detail. Ci and α of a toughened epoxy prepreg (977‐2 unidirectional) were obtained for a wide range of isothermal curing temperatures with a differential scanning calorimeter. The ultimate heat of reaction varied inconsistently with decreasing curing temperature; this resulted in erratic behavior of α. However, Ci provided a more consistent estimate of the extent of curing because Tg, unlike α, did not need to be modified on the basis of the curing history of the material and was measured directly with the heat‐flow data from differential scanning calorimetry. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011  相似文献   
63.
A Direct torque and flux control design for a sensorless induction motor, following a Lyapunov-based stator flux observer is presented. In this control scheme, the torque error signal and the amplitude of the stator flux reference vector are delivered to a PI predictive controller. The predictive controller also uses information on the amplitude and position of the actual stator flux vector and measured stator currents to determine the voltage command vector for space vector modulation inverter. In addition, a conventional PI speed controller is used to generate the torque reference signal. Using the fifth order model of the three-phase induction machines in a stationary two axes reference frame, a nonlinear stator flux observer is developed in order to estimate the rotor speed, rotor and stator resistances simultaneously. The stability of this observer is proved by Lyapunov theory. It is shown that if the persistancy of excitation condition is satisfied, the estimated quantities converge to their real values. The effectiveness of the proposed control scheme is verified by computer simulation and experimental results.  相似文献   
64.
Zinc sulfide semiconductor nanoparticles were synthesized in an aqueous solution of polyvinyl pyrrolidone via a simple microwave irradiation method. The effect of the polymer concentration and the type of sulfur source on the particle size and dispersion of the final ZnS nanoparticle product was carefully examined. Microwave heating generally occurs by two main mechanisms: dipolar polarization of water and ionic conduction of precursors. The introduction of the polymer affects the heating rate by restriction of the rotational motion of dipole molecules and immobilization of ions. Consequently, our results show that the presence of the polymer strongly affects the nucleation and growth rates of the ZnS nanoparticles and therefore determines the average particle size and the dispersion. Moreover, we found that PVP adsorbed on the surface of the ZnS nanoparticles by interaction of the C–N and C=O with the nanoparticle’s surface, thereby affording protection from agglomeration by steric hindrance. Generally, with increasing PVP concentration, mono-dispersed colloidal solutions were obtained and at the optimal PVP concentration (5%), sufficiently small size and narrow size distributions were obtained from both sodium sulfide and thioacetamide sulfur sources. Finally, the sulfur source directly influences the reaction mechanism and the final particle morphology, as well as the average size.  相似文献   
65.
Regarding the growth of global energy consumption and the paucity of light crude oil,extracting and using heavy and extra heavy crude oil has received much more attention,but the application of this kind ofoil is complicated due to its very high molecular weight.High viscosity and low flowability complicate the transportation of heavy and extra heavy crude oil.Accordingly,it is essential to reduce the viscosity of heavy and extra heavy crude oil through in-situ operations or immediate actions after extraction to reduce costs.Numerical simulations are influential methods,because they reduce calculation time and costs.In this study,the cracking of extra heavy crude oil using computational fluid dynamics is simulated,and a unique kinetic model is proposed based on experimental procedures to predict the behavior of extra heavy crude oil cracking reaction.Moreover,the hydrodynamics and heat transfer of the system and influence of nanocatalysts and temperature on the upgrading of crude oil are studied.The geometry of a reactor is produced using commercial software,and some experiments are performed to examine the validity and accuracy of the numerical results.The findings reveal that there is a good agreement between the numerical and experimental results.Furthermore,to investigate the main factors affecting the process,sensitivity analysis is adopted.Results show that type of catalyst and concentration of catalyst are the parameters that influence the viscosity reduction of extra heavy crude oil the most.The findings further revealed that when using a 25 nm SiO2 nanocatalyst,a maximum viscosity reduction of 98.67% is observed at 623 K.Also,a catalyst concentration of 2.28wt% is best for upgrading extra heavy crude oil.The results obtained through sensitivity analysis,simulation model,and experiments represent effectual information for the design and development of high performance upgrading processes for energy applications.  相似文献   
66.
Soltani M  Metzger P  Largeau C 《Lipids》2004,39(5):491-505
The lipids of the gram-negative bacterium Marinobacter hydrocarbonoclasticus grown in a synthetic seawater medium supplemented with various hydrocarbons as the sole carbon source were isolated, purified, and their structures determined. The hydrocarbons were normal, iso, anteiso, and mid-chain branched alkanes, phenylalkanes, cyclohexylalkanes, and a terminal olefin. According to the sequential procedure used for lipid extraction, three pools were isolated: unbound lipids extracted with organic solvents (corresponding to metabolic lipids and to the main part of membrane lipids), OH labile lipids [mainly ester-bound in the lipopolysaccharides (LPS)], and H+ labile lipids (mainly amide-bound in the LPS). Each pool contained FA, fatty alcohols, and β-hydroxy acids. The proportions of these lipids in the unbound lipid pools were 84–98%, 1.1–11.6%, and 0.1–3.6% (w/w), respectively. The chemical structures of the lipids were strongly correlated with those of the hydrocarbons fed; analytical data suggested a metabolism essentially through oxidation into primary alcohol, then into FA and degradation via the β-oxidation pathway. Subterminal oxidation of the hydrocarbon chains, α-oxidation of FA or double-bond oxidation in the case of the terminal olefin, were minor, although sometimes substantial, routes of hydrocarbon degradation. Cyclohexyldodecanedid not support growth, likely because of the toxicity of cyclohexylacetic acid formed in the oxidation of the alkyl side chain. In the OH and H+ labile lipid pools, β-hydroxy acids, the lipophilic moiety of LPS, generally dominated (28–72% and 64–98%, w/w, respectively). The most remarkable feature of these cultures on hydrocarbons was the incorporation in LPS of β-hydroxy acids with Codd, ω-unsaturated, iso, or anteiso alkyl chains in addition to the specific β-hydroxy acid of M. hydrocarbonoclasticus, 3-OH-n-12∶0. These β-hydroxy acids were tolerated insofar as their geometry and steric hindrance were close to those of the 3-OH-n-12∶0 acid.  相似文献   
67.
In this paper, an industrial ethylbenzene production unit has been simulated and the results are compared against five-day experimental data. According to prevailing unit condition, i.e. recycled ratio of benzene, benzene selectivity, and energy consumption, the unit is not working under its optimum conditions for minimum cost of ethylbenzene production. In the current design, high amount of benzene recycle (6:1) causes to have an additional cost due to fractionation of ethylbenzene from benzene. A new approach is proposed to modify the benzene alkylation process and reduce the unit's energy consumption. In the newly designed scheme, two double-bed alkylation reactors converted into four single-bed reactors. The amount of injected ethylene, alkylation reactors temperature, and recycled stream are regulated as adjustable parameters for the optimization of the process. In the modified process, the reflux ratio reduced to 1.87 and the benzene selectivity increased. The optimized process shows a considerable decrease in the unit's energy consumption in compare to the current process. Also, the mass fraction of ethylbenzene would reach to 99.12% of purity before entering to the transalkylation reactor for further purification. Therefore, if the presented purity is acceptable for the final application, the transalkylation reactor could be eliminated from the new design.  相似文献   
68.
G. H. Bower, S. Thompson-Schill, and E. Tulving (1994) found that when stimulus-response sets in A–B, A–C learning belong to unique categories (congruent-triads), learning appropriate responses appear rapid and memory performance on a modified modified free recall (MMFR) test is enhanced. Bower et al. assumed that category cues protect associations from interpair interference, allowing more rapid learning. However, unlike arbitrary pairs, congruent pairs also allow a reliance on preexperimental associations. As a result, MMFR test performance may not be an unbiased test of what was learned. In the present experiment, free recall (FR) demonstrated that responses were learned approximately equally in all conditions and that the pattern of clustering was compatible with the hypothesis that preexperimental associations continue to play a major role in FR test performance. (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
69.
70.
In this paper, a new methodology is introduced for the identification of the parameters of the multiple‐input–multiple‐output local linear Takagi‐Sugeno fuzzy models using the weighted recursive least squares (WRLS). The WRLS is sensitive to initialization, which leads to no convergence. In order to overcome this problem, adaptive chaos particle swarm optimization is proposed to optimize the initial states of WRLS. This new algorithm is improved versions of the original particle swarm optimization algorithm. Finally, comparative experiments are designed to verify the validity of the proposed clustering algorithm and the Takagi‐Sugeno fuzzy model identification method, and the results show that the new method is effective in describing a complicated nonlinear system with significantly high accuracies compared with approaches in the literature.  相似文献   
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