A non-linear masonry infill macro-model to represent the global behaviour of buildings under cyclic loading

The presence of masonry infill walls in RC buildings is very common. However, and even today, in the design of new buildings and in the assessment of existing ones, these infill walls are usually considered as non-structural elements and their influence in the structural response is generally ignored. For horizontal loading, infill panels can drastically modify the response, attracting forces to parts of the structure that have not been designed to resist them. This paper presents an improved non-linear numerical simulation model for the influence of the masonry infill walls in the seismic behavior of structure. The model is implemented in the PORANL program. After the implementation and calibration of the proposed masonry model, a series of non-linear dynamic analyses of a building representative of Modern Architecture in Europe were carried out. The main objective was to investigate the behavior of this type of building, and any weakness under seismic loading. The building geometry and the dimensions of the RC elements and infill walls were set in the original project, and confirmed in the technical visits. The building under study has nine storeys and the structure is mainly composed of 12 plane frames oriented in the transversal direction. The building was analyzed with a simplified plane model, for each direction, and the existing infill panels were looked at in accordance with their dimensions and location. The earthquake action adopted in this study was simulated through three series of artificially generated earthquakes, for a medium/high seismic risk scenario in Europe.     

Collapse analysis of steel jacket structures for offshore oil exploitation

This work describes the formulation of finite-element based numerical methods for global nonlinear collapse analyses of three-dimensional steel framed structures. Particular emphasis is dedicated to the reassessment and determination of residual strength of steel jackets that support offshore oil exploitation platforms. Two main aspects are considered: (1) the formulation for a three-dimensional geometric and material nonlinear frame element, and (2) the implementation of specialized techniques for the solution of the nonlinear problem. The formulation of the element combines a co-rotational approach to represent geometric nonlinearities, providing an accurate treatment of finite rotations, with the plastic hinge approach to represent material nonlinearities. The stiffness reduction due to yielding is performed through a smooth degradation, following a parabolic function. Effects of strain hardening, geometric imperfections and residual stresses are modeled in an efficient manner. In order to determine the full nonlinear equilibrium path and allow the correct determination of the collapse load, the solution strategies consider specialized “continuation” techniques such as the Arc-Length and the Generalized Displacement Control methods. Case studies are presented in order to demonstrate the accuracy, efficiency, and suitability of the implemented methods and techniques.     

Wireless Sensor Networks in IPv4/IPv6 Transition Scenarios

The wireless sensor networks (WSNs) concept was appeared in the middle of 90s and have been a subject under intensive research in the past few years. Several factors have contributed to this, but the potential for application of WSNs in almost every aspect of day-to-day life is the predominant one. This type of networks has been developed using proprietary solutions instead of standard solutions. More recently, the importance of standards motivated the use of IETF standards in WSNs, making the Internet integration easier. However, more efforts are necessary in order to provide a full integration. The WSNs use mainly IPv6 protocol, but the IPv4 is the predominant one in the Internet. As a consequence, IPv4 to IPv6 transition mechanisms must be provided to allow the interaction between all Internet connected devices independently of the supported IP version. It is also critical to provide a standard application interface to make easier the application development and independently of the hardware platform used. The RESTfull Web services can provide this standard interface. So, combine RESTfull Web services with IPv4 to IPv6 transition mechanisms can increase the WSN services dissemination. The transition mechanisms and the REST Web services are supported in the gateway in order to save the wireless sensor device resources’. The smartphone with Internet connectivity can also be the drive to the WSNs growth, because user-friendly applications can be used to retrieve and collect sensed data. This paper proposes a solution based on REST web services to permit the interaction between a mobile application and the IPv6 compliant WSN.     

Effect of colloidal silica on the mechanical properties of fiber–cement reinforced with cellulosic fibers

The effect of colloidal silica on the hydration reaction of the Portland cement system and its effect on the resulting mechanical properties are not completely understood. Silica nanoparticles can affect the behavior and performance of fiber–cement, such as the calcium–silicate–hydrate gel of the matrix and the fiber–matrix interface bonding. The main objective of this study is to evaluate the effects of various contents of colloidal silica (0, 1.5, 3, 5, and 10 % w/w) on the microstructure and mechanical performance of cement composites reinforced with cellulosic pulp. Fiber–cement composites with unbleached eucalyptus Kraft pulp as the micro-fiber reinforcement were produced by the slurry dewatering technique followed by pressing. The average values of the modulus of rupture of the fiber–cement decreased with increasing colloidal silica content. However, the pullout of the fibers increased significantly in the fiber–cement composites with additions between 3 and 10 % w/w of colloidal silica suspension, as indicated in the scanning electron microscopy images and by the improvement in the energy of fracture values.     

Spray-dried O-carboxymethyl chitosan as potential hydrophilic matrix tablet for sustained release of drug

Objective: The aim of the present investigation was to evaluate the use of spray-dried O-carboxymethyl chitosan (OCMCS) as potential hydrophilic matrix excipient for sustained release of drug.

Methods: The polymer was synthesized from chitosan, then spray-dried and characterized. Tablets with different OCMCS concentrations (80, 50, 30, 5 and 2% w/w), containing diltiazem (DTZ) as model drug, were prepared for direct compression (DC) and after the wet granulation method (WG).

Results: The spray-dried OCMCS powder was spherical, with a smooth surface and an average size of 2.2?µm. The tablets prepared for WG disintegrated in time less than 30?min. The tablets obtained for DC presented high retention of the drug, with zero order or Higuchi release kinetic. There was a direct relationship between the OCMCS concentration and the release ratio, swelling degree and water uptake behavior. DC tablets containing 80% OCMCS presented behavior as an effective swelling-control system. The DC tablets with 5% OCMCS showed a similar release profile at formulations with 30% HPMC.

Conclusion: Spray-dried OCMCS showed great potential as hydrophilic matrices for drug-sustained release.     

PMMA brush-containing two-solution bone cement: preparation, characterization, and influence of composition on cement properties

Two-solution bone cement consisting of poly (methyl methacrylate) (PMMA) brushes in methyl methacrylate has been developed as an alternative to the traditional two-solution (TSBC) and powder-liquid cements. It was hypothesized that the substitution of brushes, for the entire pre-polymer phase of the cement, would permit a decrease in solution viscosity at higher polymer fractions, and allow for physical entanglements with the cement matrix. Consequently, improved cement exothermal and mechanical properties could be expected with brush addition. PMMA brushes were grafted on the surface of cross-linked PMMA nanospheres following a multi-stage synthetic strategy. Brushes exhibiting optimal molecular weight for preparation of TSBC were used for characterization of cement viscosity, flexural and compressive mechanical properties, exothermal properties and residual monomer content. Interactions between grafts and free polymer formed during free radical polymerization of the cement were evaluated based on molecular weight measurements of the cement matrix and brushes. Brush-containing cements exhibited lower viscosity at significantly higher polymer fractions in comparison to TSBC. Cements with PMMA brushes had significantly lower polymerization temperatures and residual monomer content. Measurements of molecular weight revealed the existence of a dry brush regime when using the brush compositions selected in this study, which led to a reduction in the mechanical properties of some of the compositions tested. The optimal cement viscosity and maintenance of other important cement properties achieved with addition of PMMA brushes is expected to expand the use of the two-solution cements in a range of applications.     

On the performance of heterogeneous MANETs

Recent decades have witnessed the birth of major applications of wireless communication technology, further supported by the increasing capabilities of portable devices, low cost and ubiquitous presence. Despite radio technology diversity, a great deal of existing research focuses on a single and isolated wireless technology at a time, where homogeneous elements are identified by IP addresses. This work presents a heterogeneous technology routing (HTR) Framework, targeted towards scenarios where the heterogeneity of devices and networking technologies is present. Our contribution is many fold. It consists of a framework, which encompasses a process for bootstrapping networks, a routing protocol capable of dealing with multiple network interfaces, and a tuning with multipath extensions. We evaluate the performance of the bootstrap, routing and multipath mechanisms by way of simulation and an actual testbed implementation. The multipath evaluation simulates HTR networks with WiMAX, 3GPP LTE and Wi-Fi support. Results show that our proposal can effectively improve the data delivery ratio for ad-hoc networks and that it reduces the end-to-end delay without major impact on network energy consumption. As part of HTR tuning, we investigate next the impacts of tuning the HELLO refresh interval timer on route convergence and its subsequent energy consumption reduction during this phase. We also compare our tuned HTR with the widely used optimized link state routing protocol. Results show that varying the HELLO refresh interval can improve the convergence time and reduce the energy consumption without major impact on network behavior. Our proposal also includes a new distributed address allocation algorithm, namely, the dynamic node configuration protocol (DNCP). This paper conducts a comparative analysis between the Prime, Prophet and the DNCP schemes using static and dynamic topologies in terms of network setup time, energy consumption and control message overhead. Results show that the DNCP had a lower battery power consumption and less control message overhead while it slightly suffers with regard to setup.

     

Synthesis, hydration and durability of rice hull cements doped with chromium

This work describes the synthesis, hydration and durability behavior of β-Ca(2)SiO(4) doped with chromium. β-Ca(2)SiO(4) is a component of commercial cement. Rice hull is an agricultural residue containing about 10% of silica as inorganic constituent. The controlled burning of rice hull was used to obtain this biogenic silica, used as starting material. In many situations chromium is added during cement preparation in order to promote encapsulation, at temperatures around 1500°C. The synthesis presented here is completed at 800°C, causing a substantial reduction in energy consumption. Moreover, chromium is chemically bonded to cement crystal, which is safer than simple physical encapsulation. Results show that chromium can be inserted into the structure of β-Ca(2)SiO(4) up to 1% (molar ratio). Hydration degree and durability studies show that insertion of chromium causes no deleterious effects on physical and chemical properties of these doped materials when compared to β-pure Ca(2)SiO(4).     

Incidence and genetic variability of Listeria species from three milk processing plants

The presence of Listeria in three milk processing environments as a potential source of milk contamination was assessed. Swab samples (n = 210) taken from milk processing plants were examined. Sample sites included the milk processing equipment, besides areas handling raw and pasteurized milk. The USDA Listeria-selective enrichment procedure was used to process the samples. Forty one (19.52%) Listeria isolates were recovered. The isolates were further subjected to biochemical and genotypic characterization. Out of 41 isolates, 16 (7.62%) were confirmed as Listeria monocytogenes, 2 (0.95%) as L. ivanovii, 19 (9.05%) as L. innocua. 1 (0.48%) as L. seeligeri and 3 (1.43%) as L. grayi. All the L. monocytogenes isolates were positive for the hlyA gene. PCR based serotyping revealed all L. monocytogenes to be of 1/2a, 1/2c, 3a and 3c serovar group. AscI and ApaI restriction analysis yielded four PFGE clusters for 16 L. monocytogenes isolates obtained from raw milk collector, milk silos, buttermilk mixer, cheese and other milk product processor. No predominant PFGE cluster was observed among these L. monocytogenes isolates. The main sources of L. monocytogenes were found to be raw milk collector and milk silos. In the present study L. monocytogenes was isolated from milk and milk products processing plants which could cross-contaminate the processed products and may possess a potential threat to public health.     

Application of lysine, taurine, disodium inosinate and disodium guanylate in fermented cooked sausages with 50% replacement of NaCl by KCl

The effects of 50% replacement of NaCl by KCl and addition of the amino acids lysine and taurine and the 5'-ribonucleotide disodium inosinate and disodium guanylate on some sensory and physicochemical parameters of fermented cooked sausages were evaluated. The partial replacement of NaCl by KCl did not alter the manufacturing process; however, defects in the sensory quality were detected. Lysine at a concentration of 0.313% and a mixture of taurine (750 mg/kg) with disodium inosinate (300 mg/kg) and disodium guanylate (300 mg/kg) reduced the sensory defects caused by KCl, allowing the fermented cooked sausages to be elaborated with reduced sodium content and high sensory quality.