Qplus AFM driven nanostencil

We describe the development of a novel setup, in which large stencils with suspended silicon nitride membranes are combined with atomic force microscopy (AFM) regulation by using tuning forks. This system offers the possibility to perform separate AFM and nanostencil operations, as well as combined modes when using stencil chips with integrated tips. The flexibility and performances are demonstrated through a series of examples, including wide AFM scans in closed loop mode, probe positioning repeatability of a few tens of nanometer, simultaneous evaporation of large (several hundred of micron square) and nanoscopic metals and fullerene patterns in static, multistep, and dynamic modes. This approach paves the way for further developments, as it fully combines the advantages of conventional stenciling with the ones of an AFM driven shadow mask.     

40 years of Dogger aquifer management in Ile-de-France, Paris Basin, France

Geothermal energy has been supplying heat to district networks in the Paris Basin for more than 40 years. The most serious difficulties have been corrosion and scaling related problems that occurred in many geothermal loops in the mid-1980s. The main target of all exploration and exploitation projects has been the Dogger aquifer. Most of the operating facilities use the “doublet” technology which consists of a closed loop with one production well and one injection well. Injection of the cooled brines leads to the progressive exhaustion of the resource at the local doublet scale. Consequently, most of the research effort has been focused on quantifying the temporal evolution of the cooling, and to forecast the lifetimes of doublets and the occurrence of the “thermal breakthrough”. At the turn of the 21st century, there was a revival of geothermal energy development in France and new projects are presently being considered. The 40 years of experience in geothermal exploitation of the Paris basin constitutes a firm basis upon which to devise a sustainable regional management approach for the geothermal resource. Several governmental policies seek to promote further geothermal development of the Dogger aquifer with structures in place to facilitate technical studies.     

Probing the electronic properties of self-organized poly(3-dodecylthiophene) monolayers by two-dimensional scanning tunneling spectroscopy imaging at the single chain scale

Regioregular poly(3-dodecylthiophene) films self-organized on highly oriented pyrolytic graphite have been investigated by scanning tunneling microscopy and two-dimensional scanning tunneling spectroscopy (STS). Simulated spectra in very good agreement with the experimental data have been obtained by a method combining ab initio and semiempirical approaches, which allows a careful discussion of the polymer electronic states. From the experimental data, with the support of modeling, it is shown that the STS spectra give a direct access to the polymer semiconducting band gap without noticeable charge-transfer effects from the substrate. Spectroscopic images are achieved at the single chain scale, which allows scrutinizing the electronic consequences of chain folds and pi-stacking effects through spectroscopic contrasts. While chain folds do not locally increase the polymer band gap more than a few tens of millielectonvolt, a striking widening of the STS conductance gap is observed in the case of electronic tunneling through two interacting polymer layers. Scenarios based on nonplanar configuration of thiophene cycles within the second layer or variations of the charge screening effects are proposed to explain this phenomenon.     

Hard Macrocellular Silica Si(HIPE) Foams Templating Micro/Macroporous Carbonaceous Monoliths: Applications as Lithium Ion Battery Negative Electrodes and Electrochemical Capacitors

By using Si(HIPEs) as hard, exotemplating matrices, interconnected macro‐/microporous carbon monolith‐type materials with a surface area of around 600 m² g^?1 are synthesized and shaped. The carbonaceous foams exhibit a conductivity of 20 S cm^?1, addressed with excellent mechanical properties (Young's modulus of 0.2 GPa and toughness of 13 J g^?1, when the carbon core is optimized). The above‐mentioned specificities, combined with the fact that the external shape and size can be easily designed on demand, are of primary importance for applications. The functionality of these carbonaceous monoliths is tested as both an electrochemical capacitor and a lithium ion negative electrode. The electrochemical capacitors' voltage–current profiles exhibit a non‐ideal rectangular response, confirming the double‐layer behavior of the carbon studied, while the charge‐discharge current profile of the electric double‐layer capacitor is directly proportional to the scan where the current response during charge and discharge exhibits high reversibility. When acting as a lithium ion negative electrode, after initial irreversibility, a good cyclability is obtained, associated with a stable capacity of 200 mA h g^?1 during the first 50 cycles at a reasonable current density (C/10).     

Misfit Layer Compounds: A Platform for Heavily Doped 2D Transition Metal Dichalcogenides

Transition metal dichalcogenides (TMDs) display a rich variety of instabilities such as spin and charge orders, Ising superconductivity, and topological properties. Their physical properties can be controlled by doping in electric double-layer field-effect transistors (FET). However, for the case of single layer NbSe₂, FET doping is limited to ≈ 1 × 10¹⁴ cm⁻², while a somewhat larger charge injection can be obtained via deposition of K atoms. Here, by performing angle-resolved photoemission spectroscopy, scanning tunneling microscopy, quasiparticle interference measurements, and first-principles calculations it is shown that a misfit compound formed by sandwiching NbSe₂ and LaSe layers behaves as a NbSe₂ single layer with a rigid doping of 0.55–0.6 electrons per Nb atom or ≈ 6 × 10¹⁴ cm⁻². Due to this huge doping, the 3 × 3 charge density wave is replaced by a 2 × 2 order with very short coherence length. As a tremendous number of different misfit compounds can be obtained by sandwiching TMDs layers with rock salt or other layers, this work paves the way to the exploration of heavily doped 2D TMDs over an unprecedented wide range of doping.     

Experimental and numerical study of interactions between sprinklers and natural smoke vents

Real scale experimentations have been conducted in order to investigate interactions that may occur in a compartment where sprinklers and Smoke and Heat Exhaust Vent Systems coexist. Fuel oil spray was used as fire source with steady heat release rate of 400 and 800 kW. Both sprinkler system and natural Smoke and Heat Exhaust Vent Systems were designed according to the French standards. Effect of vent on sprinkler activation time was studied. An analysis of the temperature field inside the compartment was conducted while vent was opened prior or after sprinkler activation. Simulations of the experiments were also carried out with Fire Dynamics Simulator v.6 for validation purpose and also to provide supplementary data regarding soot flow rate and energy extracted at the vent.     

Rigorous analysis of the electronic properties of InP interfaces for gas sensing

A theoretical analysis of the surface Fermi level position (E_FS) at n-InP interfaces with different surface state density (N_SS(E)) and surface fixed charge (Q_FC) representing adsorbed ions or surface δ-doping has been performed in order to understand the InP-based gas sensor behaviour. Furthermore, the in-depth profiles of the potential barrier in equilibrium and under illumination (surface photovoltage) have been rigorously calculated. A U-shaped interface state continuum has been assumed in accordance with the Disorder Induced Gap State model. From the simulated dependencies of E_FS vs. the minimum surface state density N_SS0, the movement of E_FS in the energy band gap as well as its pinning position have been investigated. In addition, the analysis of the E_FS sensitivity to the negative and positive Q_FC has revealed the remarkable charge detection sensitivity of InP interfaces within different dynamic ranges.