Zusammenfassung Es wird eine spezifische und kochempfindliche Methode zur Bestimmung von 4-Methylimidazol (4-MeI) in Caramel und caramelgefärbten Lebensmitteln beschrieben. Nach der Extraktion wird 4-MeI gaschromatographisch mit einem stickstoffspezifischen elektrochemischen Detektor (Hall) bestimmt. Als weniger spezifische Alternative kann ein thermoionischer Detektor eingesetzt werden. Bei Zusätzen von 5–200 mg 4-MeI/kg Karamel beträgt die Wiederfindungsrate 90–94%.Die Nachweisgrenze der Methode liegt unterhalb 0,1 mg 4-MeI/kg Caramel; in karamelgefärbten Lebensmitteln können weniger als 0,01 mg/kg nachgewiesen werden.
4-methylimidazole in caramel and caramel-colored foodsDetermination by gas-liquid-chromatography with nitrogen-specific detectors
Summary A specific and highly sensitive method for the determination of 4-methylimidazole (4-MeI) in caramel and caramel-colored foods is described. After extraction the amount of 4-MeI is determined by gas-liquid chromatography with a nitrogen-specific electrochemical detector (Hall). As a less specific alternative a thermoionic detector can be used. With additions in the range of 5–200 mg 4-MeI/kg caramel, recoveries of 90–94% are obtained.The limit of detection is <0.1 mg 4-Mel/kg caramel; in caramel-colored foods less than 0.01 mg/kg can be detected.
The development of pressure sensors is crucial for the implementation of electronic skins and for health monitoring integrated into novel wearable devices. Tremendous effort is devoted toward improving their sensitivity, e.g., by employing microstructured electrodes or active materials through cumbersome processes. Here, a radically new type of piezoresistive pressure sensor based on a millefeuille‐like architecture of reduced graphene oxide (rGO) intercalated by covalently tethered molecular pillars holding on‐demand mechanical properties are fabricated. By applying a tiny pressure to the multilayer structure, the electron tunnelling ruling the charge transport between successive rGO sheets yields a colossal decrease in the material's electrical resistance. Significantly, the intrinsic rigidity of the molecular pillars employed enables the fine‐tuning of the sensor's sensitivity, reaching sensitivities as high as 0.82 kPa?1 in the low pressure region (0–0.6 kPa), with short response times (≈24 ms) and detection limit (7 Pa). The pressure sensors enable efficient heartbeat monitoring and can be easily transformed into a matrix capable of providing a 3D map of the pressure exerted by different objects. 相似文献
Van der Waals heterostructures (VDWHs), obtained via the controlled assembly of 2D atomically thin crystals, exhibit unique physicochemical properties, rendering them prototypical building blocks to explore new physics and for applications in optoelectronics. As the emerging alternatives to graphene, monolayer transition metal dichalcogenides and bottom-up synthesized graphene nanoribbons (GNRs) are promising candidates for overcoming the shortcomings of graphene, such as the absence of a bandgap in its electronic structure, which is essential in optoelectronics. Herein, VDWHs comprising GNRs onto monolayer MoS2 are fabricated. Field-effect transistors (FETs) based on such VDWHs show an efficient suppression of the persistent photoconductivity typical of MoS2, resulting from the interfacial charge transfer process. The MoS2-GNR FETs exhibit drastically reduced hysteresis and more stable behavior in the transfer characteristics, which is a prerequisite for the further photomodulation of charge transport behavior within the MoS2-GNR VDWHs. The physisorption of photochromic molecules onto the MoS2-GNR VDWHs enables reversible light-driven control over charge transport. In particular, the drain current of the MoS2-GNR FET can be photomodulated by 52%, without displaying significant fatigue over at least 10 cycles. Moreover, four distinguishable output current levels can be achieved, demonstrating the great potential of MoS2-GNR VDWHs for multilevel memory devices. 相似文献
The iron compounds (iron(III) oxide‐hydroxide monohydrate FeO(OH) × H2O, iron(III) oxide Fe2O3, and ascorbic acid) were used as oxygen scavengers modifiers in laminating of polymer films. This oxygen‐scavenging system was coated on preselected films (low density polyethylene [LDPE] and polyethylene terephthalate [PET]) from which the laminates were formed. It presents the new form of composite material packaging that has the function of oxygen scavenging, which could be suitable for food packaging. The scope of the research included studies of morphology of oxygen scavengers by scanning electron microscope and their average particle size distribution measure by particle size analyzer, the effect of type, and concentration of these substances on viscosity of adhesive and seal strength of laminates. The Fourier‐transform infrared spectroscopy (FTIR) of laminates was also performed to observe the potential interaction of functional groups of polyurethane adhesives with oxygen scavenger components. The most important ability of the developed system for oxygen scavenging was confirmed by measuring oxygen concentration (% vol) in a headspace with the prepared laminates. The concentrations of selected oxygen scavengers (4‐6 wt%) and their combinations were studied. The most effective oxygen scavenger system integrated within the PE/PET composite film consists of 6 wt% ascorbic acid and 1 wt% FeO(OH) × H2O, where the oxygen concentration of 1.0 vol% (±0.20 vol%) was obtained after 15 days of storage. It was found that in this system the oxygen scavenging reaction occurs through ascorbate oxidation to dehydroascorbic acid, which is catalyzed by reduction of Fe3+ to Fe2+ ions. 相似文献
Nanostructured erbium oxides (Er2O3) with coherent scattering length 26, 31, 62 and 65 nm were obtained using as a precursor of erbium chloride and erbium oleate. The influences of Er203 on the immune system and some animal tissues were carried out. The experiments have been made on white mouse's and outbred rats. Complex pharmaco-toxicological research presented erbium oxide nanostructure size of coherent scattering regions 26, 31, 56 and 65 nm showed that when administered orally no acute toxicity, no effect on the immune system of the body, has no effect on blood cells. But, long-term (30 day) intragastric administration shows toxicities on the internal organs of experimental animals, which lead to structural changes and functional impairment due to tissue accumulation of nanoparticles. 相似文献
Commonly used orthotropic Hill’s criterion of plastic flow initiation (Hill in Proc R Soc Lond A 193:281–297, 1948) suffers from some constraints and inconsistencies, which are of two different origins. Firstly, in case of high orthotropy degree, the quadratic form corresponding to Hill’s criterion may change type from convex and closed elliptic to concave and open hyperbolic in the deviatoric stress space (Ottosen and Ristinmaa in the mechanics of constitutive modeling, Elsevier, Amsterdam, 2005). Secondly, application of classical Hill’s criterion to transversely isotropic materials shows a discrepancy between Hill’s limit curves in the transverse isotropy plane and the Huber-von Mises prediction for isotropic materials (Huber 1904; von Mises 1913). The basic result of the present paper is to propose the new transversely isotropic von Mises–Hu–Marin’s-type criterion of hexagonal symmetry that is free from both constraints. The new enhanced Hu–Marin’s-type limit surface represents an elliptic cylinder, the axis of which is proportional to stress/strength, in contrast to Hill’s-type limit surface possessing the hydrostatic axis. Hence, this condition does not exhibit the deviatoricity property, which is a price for coincidence with the Huber–von Mises condition in the transverse isotropy plane, but with cylindricity ensured for an arbitrarily high orthotropy degree. The hybrid-type transversely isotropic Hu–Marin’s criterion of mixed symmetry based on additional biaxial bulge test, capable of fitting experimental findings for some complex composites, is also proposed. Application of this criterion has been verified for a unidirectional SiC/Ti composite examined by Herakovich (Thermal stresses V, Lastran Corp. Publ. Division, pp 1–142, 1999). 相似文献
A new efficient multicatalytic process involving a single catalyst to promote tandem hydroformylation/arylation reactions is disclosed. The effect of the rhodium ligand was evaluated and the rhodium/triphenylphosphine catalytic system was selected to apply the methodology to different olefins and boronic acids. High yields (up to 89%) and good to excellent isomer ratios (up to 98:2) were achieved using aryl olefins as starting materials. This new methodology allows the preparation of secondary alcohols, from simple olefins, and paves the way for the synthesis of high‐value products, namely vinylindole and anethole derivatives.