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61.
Satoshi Hayakawa Chikara Ohtsuki Syuji Matsumoto Akiyoshi Osaka Yoshinari Miura 《Computational Materials Science》1998,9(3-4):337-342
Chemical states of fluorine in fluorosilicate glasses in the system MF2-MO-SiO2 (M = Ca, Sr and Ba; SiO2 content < 60 mol%) have been investigated by molecular dynamic (MD) simulations with a perfect ionic two-body potential. Comparison of the results with those derived by X-ray photoelectron spectra of the actual glasses demonstrates that MD simulations reproduce well the bonding states of fluorine in the systems as well as the formation of M-F clusters. The MD generated structure of imaginary glasses, or glasses not obtained by the conventional melt-quench technique, with 70 mol% SiO2 indicates that an acidic environment induces a greater amount of F---Si bonds. Their M-F pair correlation functions plotted against normalized M-F distances suggest that relative ion positions in the clusters are very similar. 相似文献
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Wind flows over the 8.2-m Subaru Telescope at Mauna Kea in Hawaii were analyzed with a correlation method. Three or four wind flows were detected from our measurements. Spatial and temporal resolution of the wind-flow analysis across the 8.2 m pupil were investigated experimentally. A three-dimensional spatiotemporal-frequency analysis was also applied to the wind-flow data. 相似文献
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Satoh M Sakaguchi M Kobata M Sakaguchi Y Tanizawa H Miura Y Sasano R Nakanishi Y 《Shokuhin eiseigaku zasshi. Journal of the Food Hygienic Society of Japan》2003,44(1):7-12
We studied the effect of cleaning and cooking on the residues of flutolanil, fenobucarb, silafluofen and buprofezin in rice. The rice had been sprayed in a paddy field in Wakayama city, with 3 kinds of pesticide application protocols: spraying once at the usual concentration of pesticides, repeated spraying (3 times) with the usual concentration of pesticides and spraying once with 3 times the usual concentration of pesticides. The residue levels of pesticide decreased during the rice cleaning process. Silafluofen, which has a higher log Pow value, remained in the hull of the rice. Fenobucarb, which has a lower log Pow value, penetrated inside the rice. The residue concentration of pesticide in polished rice was higher than that in pre-washed rice processed ready for cooking. During the cooking procedure, the reduction of pesticides in polished rice was higher than that in brown rice. 相似文献
66.
Tomoyuki Kakigi Nozomi Miyoshi Kazuki Fujii Tatsuya Urakawa Akio Matsuura Takaharu Miura Masakazu Washio 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》2007,265(1):118-124
Poly (tetrafluoroethylene-co-perfluoroalkylvinylether) (PFA) was irradiated by soft electron beam (soft-EB) under nitrogen gas atmosphere in solid-state and its molten state, respectively. The changes of thermal property and chemical structures of irradiated PFA in solid-state and molten state were studied by differential scanning calorimetric analysis (DSC) and solid-state 19F magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy. By DSC analysis, the melting temperature shifted to lower temperatures, and crystallinity decreased with increasing soft-EB dose. By solid-state 19F MAS NMR spectroscopy, the new signals was observed and the detected new signals in irradiated PFA at 315 °C and at 30 °C were due to the tertiary carbon group with branching site (Y-type crosslinking site), perfluoro-propylene site and chain end methylene groups, respectively.Moreover, the molar ratio of perfluoroalkylvinylether (FAVE) structure to -CF2- units decreased with increasing dose. 相似文献
67.
Inductive coupling among stacked chips in a package enables 1 Gb/s/channel data communications. Array arrangement of the channel increases data bandwidth, while signal may be degraded by crosstalk. In this paper, crosstalk is measured and analyzed, and crosstalk countermeasures are discussed. Received signal waveforms through the inductive coupling are measured by embedded voltage detectors on a test chip. Interference-to-signal ratio (ISR) has good agreement between the measurements and calculations. It is found that crosstalk is reduced negligibly at a certain distance. If the channels are arranged at intervals of this distance, ISR is minimized. A technique based on time interleaving is also proposed to further reduce crosstalk. A 3times17 channel array is implemented with the crosstalk countermeasures. The channel pitch is taken down to 50 mum. Inter-chip communication with data rate of 1 Gb/s/channel and bit error rate (BER) lower than 10-9 is demonstrated 相似文献
68.
Molecular aspects of chemical and physical changes in adhesive joints caused by absorbed moisture were investigated. The focus was on the pre-damage stage that precedes the formation of voids and microcracks. A model and a commercial epoxy-amine formulation were studied. Local dynamics were monitored by broad-band dielectric relaxation spectroscopy (DRS). One portion of the absorbed water does not form hydrogen bonds with the network and gives rise to a fast relaxation process (termed γ) with activation energy of 28 kJ/mol. The local β dynamics are slowed down by the interactions between water and various sites on the network that include the ether oxygen, the hydroxyl group and the tertiary amine nitrogen. One particularly significant finding is that the average relaxation time for the β process above 20°C is of the order of nanoseconds or less and, hence, the detection and monitoring of this process hinges upon the ability to perform high-precision DRS at frequencies above 1 MHz. This is an important consideration in the ongoing efforts aimed at the implementation of DRS as nondestructive inspection (NDI) tool for adhesive joints. 相似文献
69.
Shingo Asamoto Ayumu Ohtsuka Yuta Kuwahara Chikako Miura 《Cement and Concrete Research》2011,(6):590-601
In this paper, the effects of actual environmental actions on shrinkage, creep and shrinkage cracking of concrete are studied comprehensively. Prismatic specimens of plain concrete were exposed to three sets of artificial outdoor conditions with or without solar radiation and rain to examine the shrinkage. For the purpose of studying shrinkage cracking behavior, prismatic concrete specimens with reinforcing steel were also subjected to the above conditions at the same time. The shrinkage behavior is described focusing on the effects of solar radiation and rain based on the moisture loss. The significant environment actions to induce shrinkage cracks are investigated from viewpoints of the amount of the shrinkage and the tensile strength. Finally, specific compressive creep behavior according to solar radiation and rainfall is discussed. It is found that rain can greatly inhibit the progresses of concrete shrinkage and creep while solar radiation is likely to promote shrinkage cracking and creep. 相似文献
70.