Gender differences in adolescents’ out-of-school literacy practices: A multifaceted approach

The present study examined the out-of-school literacy activities of 70 students in 7th grade of prevocational training schools in the Netherlands. Guttmann’s Facet Theory was applied to study literacy as a complex, multifaceted phenomenon. With the increasing influence of digital technologies, the facet design approach was found especially suited to track the many changes occurring in presentation modalities, functions, and productive versus consumptive uses of literacy. The study shows that the facet approach was useful in pinpointing how these shifts in literacy engagement turn out differently for boys and girls. Based on self-reports via an Internet questionnaire, the study shows that girls outscored boys in every aspect of literacy, including computer and Internet based literacy practices. However, while among girls a more balanced profile was found regarding the engagement in traditional and new literacy practices, the boys reported a high preference for the new digital media. Moreover, we found that girls, compared to boys, used new literacy activities more often for educational purposes. The findings suggest that, given this more balanced profile, girls, compared to boys, are less at risk of losing touch with traditional print-based educational literacy in school.     

The fast recursive computation of Tchebichef moment and its inverse transform based on Z-transform

The outputs of cascaded digital filters operating as accumulators are combined with a simplified Tchebichef polynomials to form Tchebichef moments (TMs). In this paper, we derive a simplified recurrence relationship to compute Tchebichef polynomials based on Z-transform properties. This paves the way for the implementation of second order digital filter to accelerate the computation of the Tchebichef polynomials. Then, some aspects of digital filter design for image reconstruction from TMs are addressed. The new proposed digital filter structure for reconstruction is based on the 2D convolution between the digital filter outputs used in the computation of the TMs and the impulse response of the proposed digital filter. They operate as difference operators and accordingly act on the transformed image moment sets to reconstruct the original image. Experimental results show that both the proposed algorithms to compute TMs and inverse Tchebichef moments (ITMs) perform better than existing methods in term of computation speed.     

Fracture Analysis of a Special Cracked Lap Shear (CLS) Specimen with Utilization of Virtual Crack Closure Technique (VCCT) by Finite Element Methods

Some of the most important characteristics due to a fracture investigation of a special specimen are taken into account. Debonding considerations for a composite/steel cracked lap shear (CLS) specimen by utilization of finite element methods (FEM) as well as a virtual crack closure technique (VCCT) approach have been investigated. Strain energy release rate, delamination load case and direct cycle fatigue analysis have taken into consideration in this study, and the corresponding simulations have been done by ABAQUS/Standard. Linear elastic fracture criteria are used for validation of numerical results from the simulation. For comparison of three different categories of analysis, some special characteristics such as effective energy release rate ratio, bond state, time at bond failure and opening behind crack tip at bond failure have been illustrated. In this work, a detailed analysis of a special CLS specimen debonding by using VCCT and FEM is presented and varied results for validation of this kind of combination are obtained and have been discussed.     

Comparison of digestion and solid sampling techniques for the determination of Pb and Cu in blackpepper

Copper and lead in blackpepper samples were determined by graphite furnace atomic absorption spectrometry using microwave‐assisted digestion and direct solid sampling technique. At first, the samples were dissolved by microwave‐assisted digestion method and directly pipetted into the graphite furnace for digestion technique. Secondly, the powdered samples were directly analysed by solid sampling technique. The experimental parameters were optimised for the two techniques. The two of the methods were applied for determination of copper and lead in pepper samples obtained commercially from markets in Istanbul, Turkey and results were statistically evaluated and compared. The limits of detections for microwave digestion and solid sampling techniques were 0.3 and 0.4 ng g^?1, for lead, and 5.1 and 11.3 ng g^?1, for copper, respectively. The advantages and disadvantages of the two sampling methods were discussed.     

Free Fatty Acids in Commercial Krill Oils: Concentrations,Compositions, and Implications for Oxidative Stability

The concentrations and pro-oxidative effects of free fatty acids in commercial krill oil are not well defined. We now report that krill oil free fatty acids account for 2–13% of total lipids in commercial krill oil (n = 8) that these compounds are enriched in eicosapentaenoic acid (+7.1%) and docosahexaenoic acid (+6.3%) relative to whole oils; and that this composition make them highly pro-oxidizing in marine triacylglycerol oils, but not in krill oil, which derives oxidative stability from both its phospholipids, and neutral lipids (the latter because of astaxanthin). Specific fatty acid esterification patterns showed that krill oil free fatty acids predominantly (88–93%) originated from phospholipids, mainly from the sn-2 position, which was eight-fold more hydrolyzed than the sn-1 position. Lipolysis was not ongoing in stored oils. Adding small amounts of krill oil (1–5%) to marine triacylglycerol oils significantly increased their oxidative stability and also their resistance to free fatty acid-mediated pro-oxidative effects.     

Morphological and impedance studies on electropolymerized 3,4-(2,2-dibenzylpropylenedioxy)thiophene nanostructures on micron sized single carbon fiber

Micron sized single carbon fibers were cyclovoltammetrically coated with poly[3,4-(2,2-dibenzylpropylenedioxy)thiophene] resulting in a nanofiber network at the surface. The method provides conjugated polymer nanostructures covalently and uniformly bound to micron sized substrates. When the electropolymerization is carried out with different electrolytes in acetonitrile the dopant influences the structure of the coating layer what is proved by electrochemical impedance spectroscopy and electron microscopy. Electrodes based on poly[3,4-(2,2-dibenzylpropylenedioxy)thiophene] on single carbon fiber microelectrodes (SCFMEs) prepared in Bu₄NPF₆/ACN show the best capacitance performance due to their higher surface area. The improvement is attributed to the formed nanofiber network structure which results in a more efficient charge transport and collection.     

An optimization and modeling approach for H2O2/UV‐C oxidation of a commercial non‐ionic textile surfactant using central composite design

BACKGROUND: Industrial surfactants are biologically complex organics that are difficult to degrade and may cause ecotoxicological risks in the environment. Until now, many scientific reports have been devoted to the effective treatment of surfactants employing advanced oxidation processes, but there is no available experimental study dealing with the optimization and statistical design of surfactant oxidation with the well‐established H₂O₂/UV‐C process. RESULTS: Considering the major factors influencing H₂O₂/UV‐C performance as well as their interactions, the reaction conditions required for the complete oxidation of a commercial non‐ionic textile surfactant, an alkyl ethoxylate, were modeled and optimized using central composite design‐response surface methodology (CCD‐RSM). Experimental results revealed that for an aqueous non‐ionic surfactant solution at an initial chemical oxygen demand (COD) of 450 mg L^?1, the most appropriate H₂O₂/UV‐C treatment conditions to achieve full mineralization at an initial pH of 10.5 were 47 mmol L^?1 H₂O₂ and a reaction time of 86 min (corresponding to a UV dose of 30 kWh m^?3). CONCLUSION: CCD allowed the development of empirical polynomial equations (quadratic models) that successfully predicted COD and TOC removal efficiencies under all experimental conditions employed in the present work. The process variable treatment time, followed by the initial COD content of the aqueous surfactant solution were found to be the main parameters affecting treatment performance, whereas the initial H₂O₂ concentration had the least influence on advanced oxidation efficiencies. The H₂O₂ concentration and surfactant COD were found to be more important for TOC abatement compared with COD abatement. Copyright © 2009 Society of Chemical Industry