Studies on Pyrodextrinization of Corn Starch

During pyrodextrinization of corn starch in the absence of any added catalyst under different experimental conditions, the changes of dextrinization might have two or threes stages and remarkable transformation would begin to occur at 190°C. At higher temperatures, many non-carbohydrates are found. At lower temperatures, side chains of amylopectin-like substances might be cleaved to produce the linear parts.     

Cooling Process and Cast Structure of Zr-Al-Ni-Cu–Based Bulk Metallic Glasses Produced in Various Atmospheres

Cooling process in the production of Zr₆₅Al_7.5Ni₁₀Cu_17.5-based bulk metallic glasses (BMGs) was investigated in various chamber atmospheres in Cu mold casting. Two different cooling modes, consisting of the direct heat transfer between the melt and Cu mold in the high temperature and indirect transfer via cavity in the low-temperature regions, are suggested. In the later case, the cooling effect should depend on the chamber atmosphere, which results in the formation of glassy structure with large relaxation enthalpy casting under the ambient Ar and He atmospheres due to a good thermal conductivity. The less relaxed BMGs produced by an improved cooling effect are also expected to contain a large amount of free volume for significant deformability. Actually, it is clarified that the compressive plastic deformation is improved with an increase of the relaxation enthalpy. The present study indicates a necessity of development of the glassy structure, i.e., relaxation state, and provides a new technique of the formation of less relaxed glassy structure for the improvement of plasticity in BMGs.     

Side-milling technique of preparing device cross-sections for electron holography based on a focused ion beam micro-sampling system

A new milling technique based on a focused ion beam (FIB) microsampling system is proposed to avoid the curtaining effect, commonly occurring in other FIB milling methods, in order to obtain a crosssectional device specimen with uniform thickness can be obtained for electron holographic observation.     

Studies on Effective Utilization of SOFC Exhaust Heat Using Thermoelectric Power Generation Technology

Solid oxide fuel cells (SOFCs) are being researched around the world. In Japan, a compact SOFC system with rated alternative current (AC) power of 700 W has become available on the market, since the base load electricity demand for a standard home is said to be less than 700 W AC. To improve the generating efficiency of SOFC systems in the 700-W class, we focused on thermoelectric generation (TEG) technology, since there are a lot of temperature gradients in the system. Analysis based on simulations indicated the possibility of introducing thermoelectric generation at the air preheater, steam generator, and exhaust outlet. Among these options, incorporating a TEG heat exchanger comprising multiple CoSb₃/SiGe-based TEG modules into the air preheater had potential to produce additional output of 37.5 W and an improvement in generating efficiency from 46% to 48.5%. Furthermore, by introducing thermoelectric generation at the other two locations, an increase in maximum output of more than 50 W and generating efficiency of 50% can be anticipated.     

"WEEE"和"RoHS"指令的对应策略

随着“WEEE”和“RoHS”指令实施的日益临近,国内许多企业苦于进展缓慢。本文提出了企业的对应策略。     

External-cavity semiconductor laser with focusing grating mirror

A novel external-cavity semiconductor laser with a focusing grating mirror (FGM), which enables a single-mode oscillation at a specified wavelength, is proposed. The optical properties of the FGM, which is a computer-generated holographic grating with chirp and bend structure, are numerically analyzed. An optimally designed FGM for realizing laser oscillation at a specific wavelength of 1.30 μm is fabricated by using a computer-controlled electron-beam writing system. The fabricated FGM with grating area of 1×1 mm² is combined as an external feedback mirror with an InGaAsP-InP semiconductor laser of 1.3 μm wavelength range, and the lasing characteristics are experimentally measured. Stable and single-mode oscillations with spectral line width less than 10 MHz are observed     

Constant-ratio-coupled multi-grain digital synchronizer with flexible input-output delay selection for versatility in low-power applications

The constant-ratio-coupled multi-grain digital synchronizer (CRC-MGsynchronizer) is proposed as a means for making high-speed connections with very low power consumption, both among multiple chips such as processors, controllers, and storage devices, and among on-chip modules. The synchronizer not only provides a wide range of operating frequencies, but is fast locking and only occupies a small area on chip. Therefore, it contributes to large reductions in power consumption and costs. It is suitable for use in various low-power systems (e.g., battery-hungry mobile appliances and low-cost consumer electronic products). Three major techniques were applied to the design: 1)a multi-grain structure for the delay elements, which greatly reduces the number of gates while facilitating locking in a very small number of clock cycles;2) constant-ratio-coupled (CRC) delay lines (measurement versus generation)for flexible selection of the input-output delay; and 3) a new lock stage decision circuit (LSDC) scheme, conferring excellent testability. Moreover,the architecture is all-digital, and thus it has high process portability. By applying these techniques to a DDR memory interface circuit for a mobile application processor fabricated in 130-nm technology, we were able to reduce power consumption by 42% and chip area by 65% compared with a conventional implementation. Furthermore, the novel design spans a frequency range covering 12 times the minimum frequency.     

Dispersion slope equaliser using bend-induced positive dispersionslope in coiled pure-silica fibre

The dispersion slope of a dispersion-shifted fibre has been successfully equalised by using a bend-induced positive dispersion slope in a singlemode fibre. We realised the bent fibre dispersion slope equaliser by using a 1.3 μm zero-dispersion pure silica core fibre (PSM). This equaliser provides a dispersion slope of -12.54 ps/nm² /km in the 1.5 μm region     

Metal Single-Atom Cocatalyst on Carbon Nitride for the Photocatalytic Hydrogen Evolution Reaction: Effects of Metal Species

Single-atom (SA) catalysts exhibit high activity in various reactions because there are no inactive internal atoms. Accordingly, SA cocatalysts are also an active research fields regarding photocatalytic hydrogen (H₂) evolution which can be generated by abundant water and sunlight. Herein, it is investigated whether 10 transition metal elements can work as an SA on graphitic carbon nitride (g-C₃N₄; i.e., gCN), a promising visible-light-driven photocatalyst. A method is established to prepare SA-loaded gCN at high loadings (weight of ≈3 wt.% for Cu, Ni, Pd, Pt, Rh, and Ru) by modulating the photoreduction power. Regarding Au and Ag, SAs are formed with difficulty without aggregation because of the low binding energy between gCN and the SA. An evaluation of the photocatalytic H₂-evolution activity of the prepared metal SA-loaded gCN reveals that Pd, Pt, and Rh SA-loaded gCN exhibits relatively high H₂-evolution efficiency per SA. Transient absorption spectroscopy and electrochemical measurements reveal the following: i) Pd SA-loaded gCN exhibits a particularly suitable electronic structure for proton adsorption and ii) therefore they exhibit the highest H₂-evolution efficiency per SA than other metal SA-loaded gCN. Finally, the 8.6 times higher H₂-evolution rate per active site of Pd SA is achieved than that of Pd-nanoparticles cocatalyst.