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31.
The molten globule state of α-lactalbumin is a partially denatured form with native-like secondary structure and disordered tertiary structure. Using circular dichroism measurements, it was demonstrated that the molten globule state was produced by decreasing the pH to 2.0 at 25°C or by removing bound Ca2+ by treatment with ethylenediamine—tetraacetic acid (EDTA) at pH 7.5 and 40°C. Tension measurements showed that α-lactalbumin in the molten globule state is more easily unfolded at liquid interfaces than is the native protein. Results of competitive adsorption experiments involving α-lactalbumin and β-lactoglobulin at the oil droplet surface in emulsions are consistent with preferential adsorption of α-lactalbumin during emulsification when it is in the molten globule state. In contrast to the difficulty of exchange between α-lactalbumin and β-lactoglobulin at the oil-water interface in emulsions at 25°C, it has been found that the two whey proteins are able partially to displace one another from the oil—water interface at 40°C. While native α-lactalbumin was found to be readily displaced from the oil—water interface by β-lactoglobulin at 40°C, it was found that α-lactalbumin in the molten globule state in the presence of EDTA at 40°C had itself the capacity for displacing β-lactoglobulin from the interface. 相似文献
32.
Atsushi Watarai Keigo Kubota Masaki Yamagata Takuya Goto Toshiyuki Nohira Rika Hagiwara Koichi Ui Naoaki Kumagai 《Journal of power sources》2008,183(2):724-729
The physicochemical properties of molten alkali bis(trifluoromethylsulfonyl)amide, MTFSI (M = Li, K, Cs), mixture (xLiTFSI = 0.20, xKTFSI = 0.10, xCsTFSI = 0.70) were studied to develop a new rechargeable lithium battery operating at intermediate temperature (100–180 °C). The viscosity and ionic conductivity of this melt at 150 °C are 87.2 cP and 14.2 mS cm−1, respectively. The cyclic voltammetry revealed that the electrochemical window at 150 °C is as wide as 5.0 V, and that the electrochemical deposition/dissolution of lithium metal occurs at the cathode limit. A Li/MTFSI (M = Li, K, Cs)/LiFePO4 cell showed an excellent cycle performance at a constant current rate of C/10 at 150 °C; 95% of the initial discharge capacity was maintained after 50 cycles. Except for the initial few cycles, the coulombic efficiencies were approximately 100% for all the cycles, indicating the stabilities of the molten MTFSI mixture and all the electrode materials. 相似文献
33.
Load-leveling hyper energy converting and utilization system (LHECUS) is a hybrid cycle which utilizes ammonia–water mixture as the working fluid in a combined power generation and refrigeration cycle. The power generation cycle functions as a Kalina cycle and an absorption refrigeration cycle is combined with it as a bottoming cycle. LHECUS is designed to utilize the waste heat from industry to produce cooling and power simultaneously. The refrigeration effect can be either transported to end-use sectors by means of a solution transportation absorption chiller (STA) as solution concentration difference or stored for demand load leveling. 相似文献
34.
Jos J. M. Lenders Harshal R. Zope Ayana Yamagishi Paul H. H. Bomans Atsushi Arakaki Alexander Kros Gijsbertus de With Nico A. J. M. Sommerdijk 《Advanced functional materials》2015,25(5):711-719
Control over magnetite (Fe3O4) formation is difficult to achieve in synthetic systems without using non‐aqueous media and high temperatures. In contrast, Nature employs often intrinsically disordered proteins to tightly tailor the size, shape, purity, and organization of the nanocrystals to optimize their magnetic properties. Inspired by such “flexible polyelectrolytes,” here random copolypeptides having different amino acid compositions are used as control agents in the bioinspired coprecipitation of magnetite through a ferrihydrite precursor, following a recently developed mineralization protocol. Importantly, the copolypeptide library is designed such that the amino acid composition can be optimized to simultaneously direct the size of the nanoparticles as well as their dispersibility in aqueous media in a one‐pot manner. Acidic amino acids are demonstrated to regulate the crystal size by delaying nucleation and reducing growth. Their relative content thus can be balanced to tune between the superparamagnetic and ferrimagnetic regimes, and high contents of negatively charged amino acids result in colloidal stabilization of superparamagnetic nanoparticles at high pH. Conversely, with positively charged lysine‐rich copolypeptides ferrimagnetic crystals are obtained which are stabilized at neutral pH and self‐organize in chains, as visualized by cryo‐transmission electron microscopy. Altogether, the presented findings give important insights for the future development of additive‐mediated nanomaterial syntheses. 相似文献
35.
Naohiko Shimada Ken Saito Takafumi Miyata Hiroki Sato Satoshi Kobayashi Atsushi Maruyama 《Advanced functional materials》2018,28(17)
The huge information storage capability of DNA and its ability to self‐assemble can be harnessed to enable massively parallel computing in a small space. DNA‐based logic gates are designed that rely on DNA strand displacement reactions; however, computation is slow due to time‐consuming DNA reassembly processes and prone to failure as DNA is susceptible to degradation by nucleases and under certain solution conditions. Here, it is shown that the presence of a cationic copolymer boosts the speed of DNA logic gate operations that involve multiple and parallel strand displacement reactions. Two kinds of DNA molecular operations, one based on a translator gate and one on a seesaw gate, are successfully enhanced by the copolymer without tuning of computing conditions or DNA sequences. The copolymer markedly reduces operation times from hours to minutes. Moreover, the copolymer enhances nuclease resistance. 相似文献
36.
Hiroyuki Yamada Atsushi Tsurumaki‐Fukuchi Masaki Kobayashi Takuro Nagai Yoshikiyo Toyosaki Hiroshi Kumigashira Akihito Sawa 《Advanced functional materials》2015,25(18):2708-2714
Tunnel electroresistance in ferroelectric tunnel junctions (FTJs) has attracted considerable interest, because of a promising application to nonvolatile memories. Development of ferroelectric thin‐film devices requires atomic‐scale band‐structure engineering based on depolarization‐field effects at interfaces. By using FTJs consisting of ultrathin layers of the prototypical ferroelectric BaTiO3, it is demonstrated that the surface termination of the ferroelectric in contact with a simple‐metal electrode critically affects properties of electroresistance. BaTiO3 barrier‐layers with TiO2 or BaO terminations show opposing relationships between the polarization direction and the resistance state. The resistance‐switching ratio in the junctions can be remarkably enhanced up to 105% at room temperature, by artificially controlling the fraction of BaO termination. These results are explained in terms of the termination dependence of the depolarization field that is generated by a dead layer and imperfect charge screening. The findings on the mechanism of tunnel electroresistance should lead to performance improvements in the devices based on nanoscale ferroelectrics. 相似文献
37.
Keishi Sakamoto Atsushi Kasugai Masaki Tsuneoka Koji Takahashi Yukiharu Ikeda Tsuyoshi Imai Takashi Nagashima Mitsuru Ohta Tsuyoshi Kariya Kenichi Hayashi Yoshika Mitsunaka Yosuke Hirata Yasuyuki Itoh Yukio Okazaki 《Journal of Infrared, Millimeter and Terahertz Waves》1997,18(9):1637-1654
A development of 170GHz/500kW level gyrotron was carried out as R&D work of ITER. The oscillation mode is TE31,8. In a short pulse experiment, the maximum power of 750kW was achieved at 85kV/40A. The efficiency was 22%. In the depressed collector operation, 500kW/36%/50ms was obtained. The maximum efficiency of 40% was obtained at PRF=470kW whereas the power decrease by the electron trapping was observed. Pulse extension was done up to 10s at PRF=170kW with the depressed collector operation. The power was limited by the temperature increase of the output window. 相似文献
38.
Pawel E. Malinowski Atsushi Nakamura Dimitri Janssen Yoshitaka Kamochi Ichiro Koyama Yu Iwai Anna Stefaniuk Ewelina Wilenska Caterin Salas Redondo David Cheyns Soeren Steudel Paul Heremans 《Organic Electronics》2014,15(10):2355-2359
We report on the fabrication of organic photodetectors (OPD) based on isolated islands of P3HT:PCBM. Pattern transfer to the active material was done with photolithography based on non-fluorinated solvents and the excessive organic semiconductor was removed with oxygen plasma reactive ion etching. The photoresist system used was found to be benign to the P3HT:PCBM layer as confirmed by absorption, thickness and roughness measurements. Current–voltage characteristics and external quantum efficiency (EQE) remained unchanged after the patterning process. It was demonstrated that it is possible to photolithographically pattern isolated islands with 200 μm edge length with the same dark current density (<10−5 A/cm2 at −2 V bias voltage) and photocurrent density (>5 × 10−3 A/cm2 at −2 V). Furthermore, concerning the solar cell performance, the patterned, small-area devices showed power conversion efficiency of 2.1% and fill-factor of 60%. Dark current was observed to depend on the size of the remaining semiconductor island, which was demonstrated on OPDs with diameter of 50 μm. The presented results show the feasibility of fabrication of isolated devices based on organic semiconductors patterned with non-fluorinated photolithography. 相似文献
39.
Complex hydrides have energy storage‐related functions such as i) solid‐state hydrogen storage, ii) electrochemical Li storage, and iii) fast Li‐ and Na‐ionic conductions. Here, recent progress on the development of fast Li‐ionic conductors based on the complex hydrides is reported. The validity of using them as electrolytes in all‐solid‐state lithium rechargeable batteries is also examined. Not only coated oxides but also bare sulfides are found to be applicable as positive electrode active materials. Results related to fast Na‐ionic conductivity in the complex hydrides are presented. In the last section, the future prospects for battery assemblies with high‐energy densities, and Mg ion batteries with the liquid and the solid‐state electrolytes are discussed. 相似文献
40.
Michio Tajima Masatoshi Ikebe Yoshio Ohshita Atsushi Ogura 《Journal of Electronic Materials》2010,39(6):747-750
We investigated the effect of Fe contamination on the electronic properties of dislocation clusters in relation to oxygen
precipitation in multicrystalline silicon (mc-Si). Photoluminescence (PL) spectroscopy and mapping were performed at room
and liquid-He temperatures on mc-Si wafers before and after Fe contamination. PL spectra consisted of the band-edge emission,
the 0.78-eV emission associated with oxygen precipitates, and the dislocation-related D-lines. The Fe contamination increased
the electrically active dislocation clusters. Part of these clusters acted as preferential oxygen precipitation sites, and
their electronic properties were not further influenced by the Fe contamination. 相似文献