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41.
Irshad Kammakakam Kathryn E O'Harra Grayson P Dennis Enrique M Jackson Jason E Bara 《Polymer International》2019,68(6):1123-1129
A new series of six imidazolium‐based ionenes containing aromatic amide linkages has been developed. These ionene‐polyamides are all constitutional isomers varying in the regiochemistry of the amide linkages (para, meta) and xylyl linkages (ortho, meta, para) along the polymer backbone. The physical properties as well as the gas separation behaviors of the corresponding membranes have been extensively studied. These ionene‐polyamide membranes show excellent thermal and mechanical stabilities, together with self‐healing and shape memory characteristics. Most importantly, [TC‐API(p)‐Xy][Tf2N] and [IC‐API(m)‐Xy][Tf2N] membranes (TC, terephthaloyl chloride; API, 1‐(3‐aminopropyl)imidazole; Xy, xylyl; Tf2N, bis(trifluoromethylsulfonyl) imide; IC, isophthaloyl chloride), where the amide and xylyl linkages are attached at para and meta positions, exhibit superior selectivity for CO2/CH4 and CO2/N2 gas pairs. We also demonstrate the transport properties and diverse applicability of our newly developed ionene‐polyamides, particularly [TC‐API(p)‐Xy][Tf2N], for various industrial applications. © 2019 Society of Chemical Industry 相似文献
42.
Muhammad Yasir Faheem Shun''an Zhong Abid Ali Minhas Muhammad Basit Azeem 《北京理工大学学报(英文版)》2018,27(4):584-591
Ultra-low power transceiver design is proposed for wireless sensor node used in the wireless sensor network (WSN). Typically, each sensor node contains a transceiver so it is required that both hardware and software designs of WSN node must take care of energy consumption during all modes of operation including active/sleep modes so that the operational life of each node can be increased in order to increase the lifetime of network. The current declared size of the wireless sensor node is of millimeter order, excluding the power source and crystal oscillator. We have proposed a new 2.4 GHz transceiver that has five blocks namely XO, PLL, PA, LNA and IF. The proposed transceiver incorporates less number of low-drop outs (LDOs) regulators. The size of the transceiver is reduced by decreasing the area of beneficiary components up to 0.41 mm2 of core area in such a way that some functions are optimally distributed among other components. The proposed design is smaller in size and consumes less power, <1 mW, compared to other transceivers. The operating voltage has also been reduced to 1 V. This transceiver is most efficient and will be fruitful for the wireless networks as it has been designed by considering modern requirements. 相似文献
43.
The teaching and learning of algebraic word problems is a basic component of elementary education. Recently, to facilitate its learning, a few approaches for automatically solving algebraic and arithmetic word problems have been proposed. These systems generally use either natural language processing (NLP) or a combination of NLP and machine learning. However, they have low accuracy due to their large feature sets, extracted using limited preprocessing techniques. In this research work, we propose a template‐based approach that was developed by following a two‐step process. In the first step, we predict an equation template from a training dataset using NLP and a classification mechanism. The next step is to instantiate the predicted template with nouns and numbers through reasoning. To validate the proposed methodology, a prototype system was implemented. We then compared the proposed system with the existing systems using their respective datasets and the proposed dataset. The experimental results show improvement in accuracy, with an average precision of 80.6% and average recall of 83.5%. 相似文献
44.
The security provisioning of increasing healthcare data is of critical importance. The e-health clouds can be seen as a move towards an efficient management of such a big volume of healthcare data. Many schemes have been presented to bring more security and privacy along with efficiency, in the handling of data for booming e-health industry. Recently, in this connection, Jiang et al. (J Supercomput 1–24 doi: 10.1007/s11227-015-1610-x, 2016) presented a three-factor authentication protocol for e-health clouds. In this letter, we identify a serious flaw in the mutual authentication phase of the scheme, since an adversary may launch a denial-of-service attack (DoS) against the service providing server. Finally, we suggest a modification in the scheme to overcome the DoS attack. 相似文献
45.
W Asghar M A Nasir F Qayyum M Shah M Azeem S Nauman S Khushnood 《Fatigue & Fracture of Engineering Materials & Structures》2017,40(7):1086-1100
Fibre metal laminates (FMLs) are being used to manufacture many structural components in aerospace industry because of their very high strength to weight ratios, yet the exact model for estimating fatigue crack propagation in FMLs cannot be developed because of many variable parameters affecting it. In this research, tensile strength, fatigue life and fracture toughness values of 2/1 configuration carbon reinforced aluminium laminate (CARALL), aramid reinforced aluminium laminate and glass laminate aluminium reinforced epoxy specimens have been investigated. Mechanical, chemical and electrochemical surface treatments were applied to AA 1050 face sheets to improve the adhesive properties of the laminates. The specimens were prepared using vacuum assisted resin transfer moulding technique and were cut to desired shapes. Fatigue tests were conducted on centre notched specimens according to ASTM Standard E399. Real time material data and properties of adhesive were used in definition of numerical simulation model to obtain the values of stress intensity factor at different crack lengths. It was observed that CARALL shows very superior tensile and fatigue strength because of stress distribution during failure. Numerical simulation model developed in this research accurately predicts fracture toughness of aramid reinforced aluminium laminate, CARALL and glass laminate aluminium reinforced epoxy with less than 2% error. An empirical analytical model using experimental data obtained during research was developed which accurately predicts the trend of FMLs fatigue life. 相似文献
46.
Azeem Irshad Muhammad Sher Omer Nawaz Shehzad Ashraf Chaudhry Imran Khan Saru Kumari 《Multimedia Tools and Applications》2017,76(15):16463-16489
The security for Telecare Medicine Information Systems (TMIS) has been crucial for reliable dispensing of the medical services to patients at distant locations. Security and privacy element needs to be there for any physician or caregiver to make certain an appropriate diagnosis, medical treatment or any other exchange of critical information. In this connection, many relevant TMIS-based authentication schemes have been presented, however various forms of attacks and inefficiencies render these schemes inapplicable for a practical scenario. Lately, Amin et al. proposed a scheme based on a multi-server authentication for TMIS. However, the Amin et al., scheme has been found vulnerable to user and server impersonation attacks. We have proposed an improved model with higher performance and efficiency, as evident from the forthcoming sections. Besides, the scheme has been backed up by formal security analysis using BAN logic to ensure the resilience of the proposed scheme. 相似文献
47.
Thermal degradation of urea‐formaldehyde cellulose composites filled with aluminum particles: Kinetic approach to mechanisms
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This article reports a study on structural characterization and thermal degradation kinetics of insulating/conducting urea‐formaldehyde cellulose (UFC) composites filled with aluminum particles. Structural characterization of UFC/Al composites carried out by SEM, XRD, and FTIR analyses reveals that composites are fairly homogenous, and the interactions between UFC and aluminum in UFC/Al composites are more probably physical in nature. Measurements of inherent thermal stabilities, probing reaction complexity, and thermal degradation kinetics of UFC and UFC/Al composites have been undertaken by thermogravimetric (TG)/differential thermogravimetric (DTG) analyses under nonisothermal conditions. The integral procedure decompositions temperature (IPDT) elucidates significant thermal stability of UFC, and higher aluminum contents in composites are capable of enhancing the thermal stability of UFC resin. TG/DTG analyses suggest highly complicated thermal degradation profiles of UFC and UFC/Al composites, which consist of various parallel/consecutive reactions. Generalized linear integral isoconversional method has been employed to determine the activation energies of thermal degradation processes. Substantial variations in activation energies of UFC and UFC/Al composites with the advancement of reaction verify their multi‐step reaction pathways. Advanced reaction model determination methodology with the help of a novel kinetic function F(α,T) reveals that the multi‐step thermal degradation of UFC goes to completion by principally following intricate nucleation/growth mechanisms. It is also found that aluminum more likely participates in the thermal degradation of resin and tends to alter its reaction mechanism. Detailed interpretations of the obtained kinetic parameters are given, and their probable physical significances are discussed. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 44826. 相似文献
48.
Zhengji Teng Hsi-Yung Feng Abdullahil Azeem 《The International Journal of Advanced Manufacturing Technology》2006,30(3-4):254-260
This paper presents a method of generating efficient three-axis ball-end milling tool paths directly from point cloud data. The primary objective is to achieve high efficiency in the machining of free-form surface geometry having isolated complex machining area. The high machining efficiency is attained by segmenting the entire machining domain into distinct areas according to the geometric complexity of the data points and by using cutters of different sizes for the segmented machining areas. An iterative numerical procedure is derived to determine the critical complexity that separates the data points with higher complexity (the complex points) from those with lower complexity (the non-complex points). A larger and more efficient ball-end mill is used to machine the area defined by the non-complex points. The gouging condition of all the data points is then evaluated with respect to the given ball-end mill. The isolated complex machining area is established by enclosing both the complex points and the gouge points. The smaller and gouge-free ball-end mill for the isolated complex machining area is subsequently selected from the standard commercial cutter series. Implementation of the presented method clearly demonstrates the high efficiency of the generated tool paths. 相似文献
49.
La méthode dite du «volume réduit» pour déterminer le dosage en ciment des éprouvettesde mortier ou de béton durci présente des inconvénients certains. Les auteurs décrivent, dans cet article, des améliorations apportées à I'appareillage qui ont permis des relevés d'une précision plus constante, allantjusqu'à 0,01 cm du volume de matière inerte demeurant après les procédures d'essai du VR habituelles. 相似文献
50.
Jian-Jun Wang Hao Ge Qigen Dai Irshad Ahmad Qixing Dai Guisheng Zhou 《International journal of remote sensing》2018,39(8):2079-2088
Wheat lodging significantly reduce the grain yield and quality. Mapping wheat lodging timely and accurately can help farmers get full compensatory damages in time. Therefore, the objective of this study was to employ a low-cost unmanned aerial vehicle (UAV) carrying a Red-Green-Blue camera to discriminate lodged from non-lodged wheat effectively. Low-cost UAV is easier to be accepted by Chinese farmers most of whom manage small-scale farms. After comparing a variety of colour features as well as their texture features, this study found that the texture feature of mean of G/B (digital number ratio of the green band to the blue band) derived from occurrence measures was the optimum discriminator of lodged and non-lodged wheat. This discriminator was still effective although the spatial spectral variations in the study area were much more complex than that in previous studies. With an unsupervised method based on the discriminator, the UAV system was able to discriminate lodged wheat from non-lodged wheat. The resultant of overall accuracy was 89.55% and Kappa coefficient was 0.76. The producer’s accuracies were 81.23% and 93.62%, whereas the user’s accuracies were 86.15% and 91.08% for lodged and non-lodged wheat, respectively. The retrieved wheat lodging distribution map showed a substantial agreement with ground reference data. 相似文献