Single‐Phase Filamentary Cellular Breakdown Via Laser‐Induced Solute Segregation

Nanosecond melting and quenching of materials offers a pathway to novel structures with unusual properties. Impurity‐rich silicon processed using nanosecond‐pulsed‐laser‐melting is known to produce nanoscale features in a process referred to as “cellular breakdown” due to destabilization of the planar liquid/solid interface. Here, atom probe tomography combined with electron microscopy is applied to show that the morphology of cellular breakdown in these materials is significantly more complex than previously documented. Breakdown into a complex, branching filamentary structure topped by a few nm of a cell‐like layer is observed. Single‐phase diamond cubic silicon highly supersaturated with at least 10% atomic Co and no detectable silicides is reported within these filaments. In addition, the unprecedented spatio‐chemical accuracy of the atom probe allows to investigate nanosecond formation dynamics of this complex material. Previously reported properties of these materials can now be reconsidered in light of their true composition, and this class of inhomogeneous metastable alloys in silicon can be explored with confidence.     

Modification of Exciton Lifetime by the Metal Cathode in Phosphorescent OLEDs,and Implications on Device Efficiency and Efficiency Roll‐off Behavior

Time resolved photoluminescence and electroluminescence measurements are used to study changes in the emission characteristics of materials typically used in phosphorescent organic light emitting devices (PhOLEDs). Studies on archetypical PhOLEDs with phosphorescent material, fac‐tris(2‐phenylpyridine) iridium (Ir(ppy)₃), show that the lifetime of triplet exciton is modified when in close proximity to a metal layer. Interactions with a metal layer ～30–100 nm away, as is typically the case in PhOLEDs, result in an increase in the spontaneous emission decay rate of triplet excitons, and causes the exciton lifetime to become shorter as the distance between the phosphorescent material and the metal becomes smaller. The phenomenon, possibly the result of the confined radiation field by the metal, affects device efficiency and efficiency roll‐off behavior. The results shed the light on phenomena affecting the efficiency behavior of PhOLEDs, and provide new insights for device design that can help enhance efficiency performance.     

Velocity field measurement of a round jet using quantitative schlieren

This paper utilizes the background oriented schlieren (BOS) technique to measure the velocity field of a variable density round jet. The density field of the jet is computed based on the light deflection created during the passage of light through the understudy jet. The deflection vector estimation was carried out using phase-based optical flow algorithms. The density field is further exploited to extract the axial and radial velocity vectors with the aid of continuity and energy equations. The experiment is conducted at six different jet-exit temperature values. Additional turbulence parameters, such as velocity variance and power spectral density of the vector field, are also computed. Finally, the measured velocity parameters are compared with the hot wire anemometer measurements and their correlation is displayed.     

Thermal activation and saturation of ion beam sculpting

We report a material-dependent critical temperature for ion beam sculpting of nanopores in amorphous materials under keV ion irradiation. At temperatures below the critical temperature, irradiated pores open at a rate that soon saturates with decreasing temperature. At temperatures above the critical temperature, the pore closing rate rises rapidly and eventually saturates with increasing temperature. The observed behavior is well described by a model based on adatom diffusion, but is difficult to reconcile with an ion-stimulated viscous flow model.     

On the effect of turbulent intensity towards the accuracy of the zero-equation turbulence model for indoor airflow application

The zero-equation turbulence model for indoor airflow applications proposed by Chen and Xu [4] has obtained immense popularity amongst the CFD practitioners in HVAC industry. A uniform turbulent intensity of 10% has been assumed in their model. In this paper, following the analogy of Chen and Xu [4] in deriving the coefficient of their zero-equation turbulence model (0.03874) which is indeed expressed as a function of turbulent intensity, the effect of turbulent intensity value assumed in the model towards the solution accuracy is investigated in this paper. Three indoor airflow cases, i.e. forced convection, natural convection and mixed convection problems are studied. It has been discovered that as the assumed uniform turbulent intensity T_i is reduced, the solution accuracy is significantly improved and the prediction comes closer to those of the two-equation standard k-? model, LES model as well as the experimental data.     

PAPR reduction in mobile WiMAX: a novel DST precoding based random interleaved OFDMA uplink system

Mobile WiMAX is a 3rd generation broadband wireless technology that enables the convergence of mobile and fixed broadband networks through a wide area radio-access. Since January 2007, the IEEE 802.16 working group has been developing a new amendment the IEEE 802.16 standard i.e. IEEE 802.16 m as an advanced air interface to meet the requirements of ITU-R/IMT-Advanced for 4G systems. The mobile WiMAX air interface adopts orthogonal frequency division multiple access (OFDMA) as multiple access technique for its uplink and downlink to improve signal performance affected by multipath distortion. All OFDMA based networks, including mobile WiMAX, experience the problem of high peak-to-average power ratio (PAPR). This paper presents a discrete-sine-transform precoding technique based random-interleaved OFDMA (RI-OFDMA) uplink system for PAPR reduction in mobile WiMAX. The PAPR of proposed system is analyzed with root-raised-cosine pulse shaping filter to keep out of band radiation low and to fulfill the spectrum mask requirements. Simulation results show that, the proposed system has low PAPR compared to the Hadamard transform precoded RI-OFDMA uplink systems and the conventional RI-OFDMA uplink systems.     

Enhancing ionic conductivity and flexibility in solid polymer electrolytes with rainforest honey as a green plasticizer

Solid polymer electrolytes (SPEs) play a pivotal role in advancing electrochemical devices, such as proton batteries and supercapacitors, owing to their potential for enhancing safety and flexibility. In this work, employs a solution casting technique to prepare SPEs, utilizing chitosan-dextran blends as the polymer matrix. Ammonium thiocyanate (NH₄SCN) is incorporated as a charge carrier, while honey is introduced as a plasticizer. The interaction between these materials is confirmed through Fourier transform infrared (FTIR) analysis. X-ray diffraction (XRD) analysis reveals that the addition of 10 wt.% honey (H10) to the polymer blend results in the lowest degree of crystallinity (15.24%), emphasizing the pivotal role of plasticizers in modulating the structural properties of SPEs. Furthermore, by incorporating 40 wt.% NH₄SCN (SN40) into the plasticizer-polymer host (H10), the ambient temperature conductivity obtains its maximum value of (1.08 ± 0.19 × 10⁻³ S cm⁻¹) with the lowest degree of crystallinity of 10.44%, verify it is the most amorphous electrolyte. The observed trend in conductivity is influenced by the diffusion coefficient (D), ion density (n), and mobility of the ions (μ). Complementing these findings, field emission scanning electron microscopy (FESEM) is employed to investigate the surface morphology and cross section of the SPEs, providing a comprehensive understanding of their structural characteristics. From linear sweep voltammetry (LSV), SN40 is electrochemically stable up to 2.2 V and the t_ion is 0.97 indicating that the ions are the dominant charge carriers.     

Characterization of vanadyl phthalocyanine based surface-type capacitive humidity sensors

This study presents the fabrication and characterization of novel surface-type capacitive humidity sensors using vanadyl phthalocyanine (VOPc) as the active material. The devices, which comprise three different thicknesses,have been fabricated using the thermal evaporation technique. A thin film of VOPc is deposited on thoroughly cleaned glass substrates with pre-pattemed Ag electrodes. The capacitive effect of the samples under humidity has been in-vestigated. Comparison of the samples with different thicknesses shows that the thinnest device seems more sensitive towards humidity. The humidity dependent capacitance properties of the sensor make it beneficial for use in commercial hygrometers.