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71.
W. F. Flanagan Lijun Zhong B. D. Lichter 《Metallurgical and Materials Transactions A》1993,24(3):553-559
A model is proposed to explain transgranular-stress corrosion cracking (T-SCC) in face-centered cubic (fcc) materials. Crack
propagation is shown to be anisotropic, in that growth near {110} < 001> is discontinuous due to crack arrest by dislocation
blunting whereas growth away from this growth orientation is continuous. For the former case, renucleation of arrested cracks
involves active dissolution of shear bands at the crack tip, which changes the stress state at Lomer-Cottrell locks, causing
them to fail by cleavage. Once the crack is nucleated, its instantaneous macroscopic crack-growth velocity is considered to
be comprised of multiple nucleation of microcracks with intervening arrests. This microcracking results from the interaction
of the stress fields from neighboring cracks which are forming simultaneously, the crack-opening constraint due to ligaments
which act as “bridges” behind the crack front, and the localized dissolution at the microcrack tip which affectsK
IC and leads to the “cobblestone” appearance. Experimental evidence and theoretical considerations are presented to support
the model. The system studied was Cu-25 at. pct Au in 0.6 M NaCl solution at potentials between 300 and 400 mV (sce), which
precludes hydrogen embrittlement.
This article is based on a presentation made in the symposium “Quasi-Brittle Fracture” presented during the TMS fall meeting,
Cincinnati, OH, October 21–24, 1991, under the auspices of the TMS Mechanical Metallurgy Committee and the ASM/MSD Flow and
Fracture Committee. 相似文献
72.
Summary The synthesis of new high optical abrasion resistance coating materials has been undertaken by functionalizing melamine and
tris(m-aminophenyl)phosphine oxide with a triethoxysilane containing reagent. These highly functionalized compounds have been
used for coating a bis-phenol-A polycarbonate substrate by the sol-gel method. Preliminary data shows the abrasion resistance
of the polymer substrate is considerably improved when it is coated by these optically clear materials. 相似文献
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Metal Science and Heat Treatment - 相似文献
76.
A. A. Konstantinov N. V. Kurenkov A. B. Malinin T. E. Sazonova S. V. Sepman 《Atomic Energy》1989,67(3):696-698
Translated from Atomnaya Énergiya, Vol. 67, No. 3, pp. 215–216, September, 1989. 相似文献
77.
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80.
An investigation into the effects of pressure (helium gas) on the isothermal fluid behavior includes: (1) the effect of pressure on the rate of melting and coking as evidenced by the rate constants k(melt) and k(coke); (2) the effect of pressure on the energies of activation of melting and coking; (3) the effects of pressure on the characteristic times; (4) the effects of pressure on the maximum isothermal fluidity. Results from the effects of pressure on k(melt) revealed that it was generally the high total sulfur, low nitrogen, low reactives/mineral matter ratio, medium rank coals which show the greatest increase in k(melt), whereas the highest rank coals show the least decrease in k(coke). The energies of activation of melting and coking were not significantly affected by pressure. The investigation also reveals increases or decreases in the respective times of softening, maximum fluidity, resolidification and total time of fluid behavior under isothermal pressurized conditions. There appears the possibility that these shifts may be rank dependent. Additionally, the lower rank coals show the largest relative increase in their fluidities when subjected to pressure. Empirical relationships were derived in order to quantitatively predict the maximum isothermal fluidity for most (fluid) coals at a given pressure. 相似文献