Modeling of solid/liquid/gas mass transfer for environmental evaluation of cement-based solidified waste

A physicochemical and transport model has been developed for the long term prediction of environmental leaching behavior of porous materials containing inorganic waste solidified with hydraulic binders and placed in a reuse scenario. The reuse scenario considered in the paper is a storage tank open to the atmosphere including material leaching with water and carbonation through the leachate contact with air. The model includes three levels: (i) the physicochemical pollution source term (chemical equilibria in the pore water and diffusion in the porous system); (ii) chemical equilibria and mass transfer in the tank; and (iii) gas/liquid transfer of carbon dioxide. The model was applied to the case of a material obtained through solidification of Air Pollution Control (APC) residues from Municipal Solid Waste Incinerator (MSWI). The simulation results are in good agreement with two scale experimental data: laboratory and field tests. Experimental data and simulations show the main trends for release of elements contained in the material: (i) the release of alkaline metals and chloride is not significantly influenced by carbonation and (ii) the release of Ca and Pb is governed by chemical equilibria in pore water and diffusion, while their speciation in the leachate is determined by pH and the presence of carbonate ions.     

Field Testing of Stabilized Soil

Remediation of a Superfund site in Stratford, Conn., involved stabilization of the subgrade with portland cement. Part of the remediation site was to be used as a parking area. The stabilized soil was to be covered with natural base∕subbase course materials and capped with an asphalt concrete cover. During the course of the remediation, a base-course layer could not be placed prior to the onset of winter. A field study was conducted to quantify any changes in the mechanical properties of the open stabilized subgrade subjected to freeze-thaw cycling during the winter of 1996–97. Field evaluation was conducted with pavement industry tools: the Clegg impact hammer and the dynamic cone penetrometer. Evaluation results show the viability of the Clegg hammer as an instrument for quality assurance and also show that there can be up to 50% loss in compressive strength of the subgrade within the uppermost layer of the material caused by freeze-thaw cycling.     

Growth of nanocomposite in eutectic Cu-Ag films

Eutectic composition Cu-Ag alloy thin films were prepared by co-deposition at room temperature onto oxidized Si substrates by thermal evaporation. Morphological development, structure and phase state of the films were investigated by transmission electron microscopy. The films possess fibre morphology 10-30 nm in diameter and strong <111> texture is present. The fibres are nanocrystalline composed of 2-3 nm size zones of Cu and Ag rich solid solution phases and a model for morphological development and phase separation is described. In the early stages of growth phase separation occurs by nucleation in melted islands and a eutectic of randomly oriented crystallites forms. In later stages of growth the phase separation takes place by spinodal decomposition. It results in a strain stabilized unique morphology corresponding to an intermediate stage of phase separation.     

Stress computations for nearly incompressible materials by the p-version of the finite element method

In the case of nearly incompressible elastic materials the strain energy, the shear stress and the difference of normal stresses can be computed accurately by direct methods when the p-version of the finite element method is used. Computation of the sum of the normal stresses requires special procedures. In this paper such procedures are described and examples are presented.     

Retroviral transfer of CPP32beta gene into malignant gliomas in vitro and in vivo

Malignant gliomas are highly aggressive neoplasms that are very resistant to current therapeutic approaches, including irradiation, chemotherapy, and immunotherapy. To improve the prognosis, it is absolutely essential to explore novel modalities of treatment. Recently, we have demonstrated that interleukin 1beta-converting enzyme (ICE), a mammalian homologue of the Caenorhabditis elegans cell death gene ced-3, induces apoptotic cell death in malignant glioma cells. To date, ICE and ICE-like proteases (the ICE family), such as Ich-1L, CPP32beta, Mch2alpha, and Mch3alpha, have been shown to mediate apoptosis in some cells. The purpose of this study is to determine whether the ICE gene family functions as a useful tool for the treatment of malignant glioma cells through induction of apoptosis. The transient transfection assays showed that CPP32beta and Mch2alpha genes induced apoptotic cell death in malignant glioma cells more effectively than did the ICE, Ich-1L, and Mch3alpha genes. To improve the efficiency of gene transfer into malignant glioma cells, we constructed the retroviral vectors containing the ICE gene family. The retroviral transfer of CPP32beta or Mch2alpha gene effectively induced apoptosis in malignant glioma cells in vitro. Furthermore, treatment of tumors grown in mice with retrovirus containing CPP32beta significantly inhibited growth of the tumors through induction of apoptosis. The retroviral transfer of CPP32beta or Mch2alpha, therefore, may be a novel and promising approach for the treatment of malignant glioma, an invariably fatal tumor.     

Material and device properties of a solid state electrochromic display

A solid state electrochromic display with the following configuration: transparent conductor/WO₃/Na_1+xZr₂Si_xP_3−xO₁₂/ Na_0.3WO₃/conductor has been fabricated and studied. The properties of the electrodes are shown to be dependant upon the preparation conditions. Two problems, specifically due to the solid state nature of this device, are also discussed. These are the incompatibility of the WO₃ layer with the processes necessary to deposit a transparent electrode onto it, and the large resistance at the solid electrode/electrolyte interfaces.     

Linear equality constraints in finite element approximation

The typical numerical problem associated with finite element approximations is a quadratic programming problem with linear equality constraints. When nodal variables are employed, the coefficient matrix of the constraint equations, [ A ], acquires a block-diagonal structure. The transformation from polynomial coefficients to nodal variables involves finding a basis for [ A ] and computing its inverse. Simultaneous satisfaction of completeness and C¹ (or higher) continuity requirements establishes linear relationships among the nodal variables and precludes inversion of the basis by exclusively element-level operations. Linear dependencies among the constraint equations and among the nodal variables can be evaluated by the simplex method. The computational procedure is outlined.     

Knowledge-based system for supporting statistical database management

In the development of the expert system described here, knowledge-based information processing has been approached from the point of view of database technology. The outlines and processes of arranging an economic national balances system are provided, and the problems encountered in applying the variables involved in such a process to an expert system are identified. The structure and architecture of the expert system are defined, and the problems of knowledge acquisition are discussed.     

Leaching behaviour of low level organic pollutants contained in cement-based materials: experimental methodology and modelling approach

The aim of this paper is the investigation of the leaching behaviour of different porous materials containing organic pollutants (PAH: naphthalene and phenanthrene). The assessment methodology of long term leaching behaviour of inorganic materials was extended to cement solidified organic pollutants. Based on a scenario-approach considering environmental factors, matrix and pollutants specificities, the applied methodology is composed of adapted equilibrium and dynamic leaching tests. The contributions of different physical and chemical mechanisms were identified and the leaching behaviour was modelled. The physical parameters of the analysed reference and polluted materials are similar. A difference in the pore size distribution appears for higher naphthalene content. The solubility of the PAH contained in the material is affected by the ionic strength and by the presence of a co-solvent; the solution pH does not influence PAH solubility. The solubility of the major mineral species is not influenced by the presence of the two PAH nor by the presence of the methanol as co-solvent in the range of the tested material compositions. In the case of the leaching of a monolith material the main transport mechanism is the diffusion in the porous system. For both mineral and organic species we observed at least two dynamic domains. At the beginning of the leaching process the released flux is due to the surface dissolution and to the diffusion of the main quantity dissolved in the initial pore solution. The second period is governed by a stationary regime between dissolution in pore water and diffusion. The model, coupling transport and chemical phenomena in the pore solution, at the monolith surface and in the leachate simulates satisfactory the release for both mineral and organic species.