Optimization of equilibrium headspace analysis of volatile flavor compounds of malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC-TOFMS)

Headspace solid-phase microextraction (HS-SPME) coupled to comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC-TOFMS) was applied for equilibrium headspace analysis of Malaysian soursop (Annona muricata) volatile flavor compounds. A two-level fractional factorial design (2^5-1) was used to determine the effect of SPME variables, namely, SPME fibers, adsorption temperature, extraction time, amount of salt, sample amount and sample concentration on the extraction efficiency of volatile flavor compounds. A total of 37 volatile compounds were identified, comprising 21 esters, 6 alcohols, 3 terpenes, 2 acids, 2 ketones, 2 aldehydes and an aromatic with different hydrophobicities (log P) ranging between −0.14 and 4.83. Extraction using 10 g of diluted (5% w/w) blended soursop pulp with CAR/PDMS fiber at 25 °C for 30 min and 30% (w/w) of NaCl under stirring mode resulted in the highest extraction efficiency of volatile flavor compounds. The principal component analysis score discriminated the influence of SPME variables on the equilibrium headspace concentration of target volatile compounds.     

WCDMA downlink capacity of cigar-shaped microcells for long tunnels

In this paper, the Wideband Code Division Multiple Access (WCDMA) downlink capacity and the interference statistics of long tunnel cigar-shaped microcells are analyzed. The hybrid model of propagation is used in the analysis where a model of 10 cigar-shaped microcells is used. The downlink capacity is given for different sector radio R, break point distance R _b and propagation parameters (s and γ). It is found that the effect of changing the value of the propagation parameter s is very small. Also, it is noticed that, increasing the propagation parameter γ will increase the sector downlink. It is found that, the effect of changing the break point distance R _b is quasi null. Finally it is noticed that the imperfect power control reduces the downlink capacity by 4 %.     

UMTS-HSDPA in High Altitude Platforms (HAPs) communications with finite transmitted power and unequal cell’s load

In this paper, the performance of HAPs (High Altitude Platforms) UMTS HSDPA (High Speed Downlink Packet Access) is studied for different scenarios and two directions (0° and 30°) within the cell where the network under study is assumed to have 61 cells. It is concluded that, for urban zone users, the effective range is lower than the effective range for users in rural zones. It is shown that in rural zones, the HSDPA mode can support the modulation 16QAM with 7/8 code rate when cells are not fully loaded. For fully loaded rural cells, the 16QAM modulation scheme with code rate of 7/8 cannot be supported. Also, it is noticed that, in urban zones, HSDPA mode can support 16QAM with code rate of 1/2 and QPSK modulation schemes when cells are not fully loaded. For fully loaded urban cells, only QPSK with code rate of 1/2 can be supported.     

Sympathoexcitation from the rostral ventrolateral medulla is mediated by spinal NMDA receptors

These studies examined the role of spinal N-methyl-D-aspartic acid (NMDA) receptors in mediating sympathoexcitation evoked by stimulation of neurons in the rostral ventrolateral medulla (RVLM). In urethane-anesthetized rats, blood pressure, heart rate, and splanchnic sympathetic nerve activity (SNA) were recorded. The NMDA receptor antagonist D-2-amino-7-phosphonoheptanoic acid (D-AP7) was administered to the spinal cord via intrathecal (IT) catheter. Blockade of spinal NMDA receptors reduced arterial blood pressure, heart rate, and SNA. Spinal administration of D-AP7 markedly attenuated the pressor and sympathoexcitatory responses evoked by L-glutamate stimulation of the RVLM. The small increases in heart rate evoked by stimulation of the RVLM were not affected by IT administration of D-AP7. These results indicate that NMDA receptors in the spinal cord mediate the pressor and sympathoexcitatory responses evoked by activation of a bulbospinal pathway originating from the RVLM. Moreover, these data suggest that excitatory amino acid neurotransmitters and NMDA receptors in the spinal cord play an important role in the maintenance and regulation of SNA and cardiovascular function.     

Recognition by prototypes

A scheme for recognizing 3D objects from single 2D images under orthographic projection is introduced. The scheme proceeds in two stages. In the first stage, the categorization stage, the image is compared to prototype objects. For each prototype, the view that most resembles the image is recovered, and, if the view is found to be similar to the image, the class identity of the object is determined. In the second stage, the identification stage, the observed object is compared to the individual models of its class, where classes are expected to contain objects with relatively similar shapes. For each model, a view that matches the image is sought. If such a view is found, the object's specific identity is determined. The advantage of categorizing the object before it is identified is twofold. First, the image is compared to a smaller number of models, since only models that belong to the object's class need to be considered. Second, the cost of comparing the image to each model in a class is very low, because correspondence is computed once for the whole class. More specifically, the correspondence and object pose computed in the categorization stage to align the prototype with the image are reused in the identification stage to align the individual models with the image. As a result, identification is reduced to a series of simple template comparisons. The paper concludes with an algorithm for constructing optimal prototypes for classes of objects.     

Experimental Determination of Cutting Forces and Surface Roughness when Turning 50CrV4 Steel (SAE 6150) and Modelling with the Artificial Neural Network Approach

In this experimental study, 50CrV4 (SAE 6150) steel parts were subjected to machining test using coated and uncoated carbide cutting tools through single point turning operation. The turning tests were performed at various cutting parameters (cutting speed, feed rate and depth of cut). In the light of these parameters, cutting forces and surface roughness values obtained were determined. A suitable cutting force measurement dynamometer was used for measuring the three cutting force components. The surface roughness values were also measured. The results of experiments were modelled with artificial neural network system. The relation between the cutting forces and surface roughness values was defined.     

Optimization of the enzyme-catalyzed synthesis of amino acid-based surfactants from palm oil fractions

The feasibility of using palm oil fractions as cheap and abundant sources of raw material for the synthesis of amino acid surfactants was investigated. Of a number of enzymes screened, the best results were obtained with the immobilized enzyme, Lipozyme. The effects of temperature, solvent, incubation period, fatty substrate/amino acid molar ratio, enzyme amount, and water removal on the reactions were analyzed and compared to those on reactions with free fatty acids and pure triglycerides as fatty substrates. All reactions were most efficient when carried out at high temperatures (70-80 degrees C) in hexane as a solvent. However, while reactions with free fatty acids proceeded better when a slight excess of the free fatty acids over the amino acids was used, reactions with triglycerides and palm oil fractions were best performed at equimolar ratios. Also, the addition of molecular sieves slightly enhanced reactions with free fatty acids but adversely affected reactions with triglycerides and palm oil fractions. Although reactions with palm oil fractions took longer (6 d) to reach equilibrium compared to reactions with free fatty acids (4 d) and pure triglycerides (4 d), better yields were obtained. Such lipase-catalyzed transacylation of palm oil fractions with amino acids is potentially useful in the production of mixed medium- to long-chain surfactants for specific applications.     

Non-linear optimization of passive direct methanol fuel cell (DMFC)

The cost associated with a direct methanol fuel cell (DMFC) is the main drawback of its commercialization. To address this issue, the main objective of this study is to minimize the cost of micro DMFCs for portable applications. The model was coupled with a non-linear constrained optimization to determine an optimum design of the DMFC with respect to the design and geometrical parameters of the anode and cathode, including methanol concentration, power density, catalyst loading, etc. Optimization was performed using Matlab to minimize the difference between the power input required and the power optimum via Non-Linear Programming (NLP). The optimum characteristics of DMFC were solved by using an NLP simulation. The outputs were verified by both experimental and modeling results. These dynamic optimization results provided an optimum design parameters for the physical properties of DMFC required to generate the portable application. Lastly, a cost analysis was also considered in this study.     

Verifying the accuracy of interlocking tables for railway signalling systems using abstract state machines

Railway transportation system is a critical sector where design methods and techniques are defined by international standards in order to reduce possible risks to an acceptable minimum level. CENELEC 50128 strongly recommends the utilization of finite state machines during system modelling stage and formal proof methods during the verification and testing stages of control algorithms. Due to the high importance of interlocking table at the design state of a signalization system, the modelling and verification of interlocking tables are examined in this work. For this purpose, abstract state machines are used as a modelling tool. The developed models have been performed in a generalized structure such that the model control can be done automatically for the interlocking systems. In this study, NuSMV is used at the verification state. Also, the consistency of the developed models has been supervised through fault injection. The developed models and software components are applied on a real railway station operated by Metro Istanbul Co.