Controllable synthesis of pure monodispersed zirconia nanopowders with tetragonal phase

Nanopowders of pure zirconia have been synthesized using citric acid (CA)-assisted lamellar liquid crystal template method. The microstructure of the zirconia powder prepared at the different mole ratios of CA to zirconium oxynitrate (ZN) was characterized by FT-IR, X-ray diffraction (XRD), laser particle size analyzer, Raman spectroscopy, and scanning electron microscope (SEM) methods. The phase structure of the sodium dodecyl sulfate (SDS)/C₁₀H₂₁OH/H₂O system before and after adding mixing solution CA and ZN was determined by POM (Polarizing Optical Microscope). The results show that lamellar structure of the SDS/C₁₀H₂₁OH/H₂O system after adding mixing solution CA and ZN is stable. The presence of CA inhibits agglomeration and growth of zirconia particle. The crystallite size of zirconia powders decreases and agglomerates lowly with addition of CA. Fourier transform infrared spectrometry (FI-IR) analyses reveal that the structure of chelating organic complex is maintained in zirconia structure at high-temperature calcination to cause oxygen vacancies which stabilizes the tetragonal phase of zirconia. The zirconia powders remained the single metastable tetragonal phase at the molar ratios of CA to ZN ranging from 1:3 to 5:1. The crystallite size of zirconia with spherical morphology varied from 32.2 to 20.1 nm with the increase of the molar ratio of CA to ZN in the range of 1:3 to 5:1.     

Facile Modification of Biochar Derived from Agricultural Straw Waste with Effective Adsorption and Removal of Phosphorus from Domestic Sewage

Journal of Inorganic and Organometallic Polymers and Materials - In recent decades, straw waste is the major byproduct around agriculture that has become one of the factors of environmental...     

Preparation,Properties and Applications of the Hybrid Organic/Inorganic Nanocomposite Based on Nanoporous Carbon Matrix

Journal of Inorganic and Organometallic Polymers and Materials - Nanoporous carbon matrix was prepared by the sol–gel process from pyrogallol-formaldehyde (PF) mixtures in water using picric...     

EFFECT OF MnS AND SLAB REHEATING TEMPERATURE ON PROPERTIES OF ORIENTED-GRAIN Fe-3%Si

本文确定了按Mns方案制造3％取向Si钢的主要成分:C=0.03—0.05％,Mn=0.06—0.08％,S=0.018—0.025％,[Mn][S]=(11—20)×10~(-4),O_2<0.007％。证明板坯加热温度提高,初次晶粒尺寸减小,二次晶粒尺寸增大,磁性明显提高(B_(10)>1.78Wb/m~2)而且稳定。合适的板坯加热温度随[Mn][S]积增加而提高。加入适量Al和N_2后,加热温度对磁性较不敏感,二次晶粒尺寸增大,B_(10)值进一步提高。二次再结晶开始温度也就是初次晶粒迅速长大和MnS质点开始聚集的温度。     

合金元素P,Cu含量对铸铁短纤维结合剂组织和性能的影响

本文研究了合金元素磷和铜对铸铁短纤维烧结体显微组织和性能的影响。结果表明，合金元素磷可显著提高铸铁短纤维烧结体的密度、致密化系数和压强度。磷与铜的共同加入可进一步提高烧结体的压溃强度和硬度，同时，铜的加入可抑制由磷引起的烧结体的急剧。烧结机理随磷、铜含量的增加逐渐由固相烧结＋瞬态液烧结转变为液相烧结。     

紫外光固化酚醛树脂的制备及在涂附磨具中的应用

本文通过丙稀酸与环氧酚醛树脂开环反应,制备出能紫外光固化的酚醛树脂结合剂,研究了制备该树脂的合适工艺条件为:催化剂N,N-二甲基苯胺的用量为体系总质量的1%,反应温度为80±5℃,反应时间为5~7h;用这种可紫外光固化的酚醛树脂制作的涂附磨具试样,不仅固化速度快,仅需4~5m in即可固化完全,而且磨削比是常规热固化试样的3倍多,使用性能大大提高。     

氢处理技术在钛合金中的应用

氢处理工艺是钛合金的一种特有的热处理方式，用于改善铸造、锻造钛合金件以及粉末冶金件的组织和性能。本文综述了氢处理在钛合金中的一些应用，主要介绍了国外的研究动向。     

轴承钢GCr15的恒温相变超塑性

研究了ＧＣｒ１５钢在Ａｃ１相变点附近的恒温超塑性特性与变形温度的关系。结果表明，与一些材料一样，该钢也存在恒温相变超塑性现象。当初始应变速率为２．５×１０＾－４ｓ＾－１时，经预调质处理的ＧＣｒ１５钢试样，在７４８℃进行超塑性拉伸试验获得最大延伸率达８００％，流动应力为２４ＭＰａ。与已有的同类研究结果相比，其延伸率提高了２００％以上。     

Multidisciplinary optimization of gas-quenching process

Distortion as a result of the quenching process is predominantly due to the thermal gradient and phase transformations within the component. Compared with traditional liquid quenching, the thermal boundary conditions during gas quenching are relatively simple to control. By adjusting the gas-quenching furnace pressure, the flow speed, or the spray nozzle configuration, the heat-transfer coefficients can be designed in terms of both the component geometry and the quenching time. The purpose of this research is to apply the optimization methodology to design the gas-quenching process. The design objective is to minimize the distortion caused by quenching. Constraints on the average surface hardness, and its distribution and residual stress are imposed. The heat-transfer coefficients are used as design variables. DEFORM-HT is used to predict material response during quenching. The response surface method is used to obtain the analytical models of the objective function and constraints in terms of the design variables. Once the response surfaces of the objective and constraints are obtained, they are used to search for the optimum heat-transfer coefficients. This process is then used instead of the finite-element analysis. A one-gear blank case study is used to demonstrate the optimization scheme.