A study of hydrogel thermal-dynamics using Fourier transform infrared spectrometer

A rapid and reliable method was presented for studying hydrogel dynamics/kinetics. Two temperature-sensitive hydrogels, poly-N-isopropylacrylamide (poly(NIPAAm)) and the copolymer of N,N-diethylacrylamide and sodium methacrylate (molar ratio=97:3, poly(NDEAAm-co-MAA)) were synthesized. The thermal-behaviors of the gels were studied through the absorbance intensities of both swollen water and gel frame components, and the peak positions of amide band along heating/cooling pathways under dynamic Fourier transform infrared (FTIR) probing. The results showed that the lower critical solution temperature (LCST) of poly(NIPAAm) is about 33-35 °C, which is consistent with reported value of ∼34 °C. Compared to poly(NIPAAm), poly(NDEAAm-co-MAA) has relatively continuous volume phase transition, starting at ∼35 °C and a better thermal-reversibility with similar swelling and deswelling profiles over a larger temperature range (10-80 °C for poly(NDEAAm-co-MAA) vs. 10-33 °C for poly(NIPAAm)). The H-bonding water along phase transition was also studied, showing a less reversibility of poly(NIPAAm) compared to poly(NDEAAm-co-MAA). In addition, FTIR spectrometer was also used to study the volume changes of poly(NDEAAm-co-MAA) under variations in environmental salinity.     

A disaggregate Box-Cox Logit mode choice model of intercity passenger travel in Germany and its implications for high-speed rail demand forecasts

We show that enriching logit mode choice model specification by mode attributes, socio economic variables and trip purpose characteristics significantly improves model quality, and that Box-Cox transformations applied to model attributes imply an asymmetry of the reaction curve, as well as more reasonable properties (diminishing marginal values of time savings, elasticities and values of time that differ among the modes) than those of the linear logit model. Moreover, the model yielded very different high speed rail market shares for Germany than results obtained with the usual linear utility functions. Received: December 1996 / Accepted: April 1997     

Characterization of Micro-Powders for the Fabrication of Compression Molded THz Lenses

We investigate different micro-powders that can be used as base materials for THz lenses fabricated by compression molding. For this application materials with a very weak THz absorbance and low dispersion are required. By measuring the THz absorption coefficient and refractive index of pellets pressed from the different micro-powders, we identify several materials that are well suited for the fabrication of compression molded THz lenses (CMLs). In addition, a considerable range of the refractive index is covered by the samples, which will allow for the fabrication of CMLs with different focal lengths for one and the same lens design.     

Using the community health assessment to screen for continued driving

This project used the interRAI based, community health assessment (CHA) to develop a model for identifying current elder drivers whose driving behavior should be reviewed. The assessments were completed by independent housing sites in COLLAGE, a non-profit, national senior housing consortium. Secondary analysis of data drawn from older adults in COLLAGE sites in the United States was conducted using a baseline assessment with 8042 subjects and an annual follow-up assessment with 3840 subjects. Logistic regression was used to develop a Driving Review Index (DRI) based on the most useful items from among the many measures available in the CHA assessment. Thirteen items were identified by the logistic regression to predict drivers whose driving behavior was questioned by others. In particular, three variables reference compromised decision-making abilities: general daily decisions, a recent decline in ability to make daily decisions, and ability to manage medications. Two additional measures assess cognitive status: short-term memory problem and a diagnosis of non-Alzheimers dementia. Functional measures reflect restrictions and general frailty, including receiving help in transportation, use of a locomotion appliance, having an unsteady gait, fatigue, and not going out on most days. The final three clinical measures reflect compromised vision, little interest or pleasure in things normally enjoyed, and diarrhea. The DRI focuses the review process on drivers with multiple cognitive and functional problems, including a significant segment of potentially troubled drivers who had not yet been publicly identified by others. There is a need for simple and quickly identified screening tools to identify those older adults whose driving should be reviewed. The DRI, based on the interRAI CHA, fills this void. Assessment at the individual level needs to be part of the backdrop of science as society seeks to target policy to identify high risk drivers instead of simply age-based testing.     

Development of new polymer�CBaTiO3-composites with improved permittivity for embedded capacitors

A series of commercially available nanosized barium titanates has been investigated with respect to their use as high-k-ceramic filler in polymer based composites with improved dielectric properties. The thermal treatment of the barium titanate powders at 1,000°C causes a significant increase of the composite’s permittivity. X-ray diffraction experiments prior and after heat treatment revealed that the barium titanate with smallest particle size and the largest specific surface area possesses the thermodynamically unstable cubic phase. In case of the other investigated barium titanates the crystal lattice is distorted. Thermal treatment induces the phase change into the tetragonal one and crystal lattice relaxation enabling higher permittivity values. Composites with a solid load around 78 wt% with a bimodal particle size distribution show high permittivities around 50 and a low loss factor around 5‰ suitable for the realization of embedded capacitors via screen printing or tape casting.     

Computational Intelligence in Biomedical Engineering (Begg, R. et al.; 2008) [Book reviews]

The book is a comprehensive account of the recent research in CI. It covers applications of CI in four important areas: cardiology, EMG, electroencephalography, and gait and movement pattern. This is an excellent reference for researchers, practicing engineers, academics, and graduate students who are looking for applications of CI in health care.     

Structural stability of intermetallic phases in the Sn–Ti system

The total energies of intermetallic compounds in the Sn–Ti system are calculated employing electronic density-functional theory (DFT) using pseudopotentials constructed by the projector augmented waves (PAW) method in the generalized gradient (GGA) approximation for the exchange and correlation energy. The calculations are performed for the experimentally observed compounds at their ideal stoichiometry as well as for structures which are stable in systems of early transition metals or rare earth elements with p-elements of columns IIIB, IVB, and VB. The calculated formation enthalpy of the hexagonal Sn₅Ti₆ compound is slightly less exothermic than the value obtained by direct reaction calorimetry. For the stable intermetallic compounds, the calculated zero-temperature lattice parameters agree well with those obtained experimentally at ambient temperature. More, for stable phases with unit cell-internal degree(s) of freedom, the results of ab initio calculations show good agreement when compared with data obtained by structural analysis of X-ray diffraction. The composition dependence of the enthalpies of formation is slightly asymmetric. The electronic densities of state of the D8₈- Sn₃Ti₅ compound have been computed; the curve shows the hybridization of Sn 5p states with Ti 3d states. The stability of the intermetallic compounds in the Ti–Sn system is due to this hybridization.     

A Newly Developed Computer Graphics System for the Display of Underground Mine Environments

A newly developed computer graphics software package designed for the display of remote sensor information, such as underground air quality data, on a color graphics video screen is discussed. The software also has trending, predictive ventilation, contaminant, and mine fire capabilities. It was developed at Michigan Technological University under US Bureau of Mines contract H0212024. The package utilizes a unique system of display indexing that provides a simple, efficient method of recalling a series of mine schematics, detailing an underground operation and an alarm display and acknowledgment scheme that provides an effective method for identifying problem areas that may exist in the mine network. The package also permits the display of trend plots, which an operator uses to review a particular sensor value as a function of time over a period of several days. The software package has been written in Fortran and has been designed for use with a specific hardware system, although it can be modified for other hardware installations.