Induced low temperature catalytic ignition by transient changes in the gas composition

The effect of gas composition changes on the low temperature activity for supported platinum model catalysts has been studied. By introducing well-controlled periodic O₂ pulses to a simple diluted gas mixture of CO and O₂, a substantial improvement of the low temperature oxidation activity was observed. The reason for low activity on noble metals at low temperatures is often attributed to self-poisoning by CO. The improved catalytic performance observed is proposed to origin from the transients causing a surface reactant composition that is favourable for the reaction rate, i.e. lower degree of self-poisoning. This was also confirmed by in situ Fourier transform infrared (FT-IR) spectroscopy in combination with mass spectrometry (MS) measurements, which gave evidence for the existence of a strong interplay between the gas phase concentration and the adsorbate composition for these catalysts.     

Reliability analysis of hydraulic systems of LHD machines using the power law process model

Earlier, a preliminary study of the reliability characteristics of a fleet of load-haul-dump (LHD) machines deployed at Kiruna mine showed that the engine and the hydraulics are the two most critical subsystems. Hydraulic systems are selected for further study because such systems are still under a development phase. Maintenance data for two years for these machines are analyzed. The tests for trends and serial correlation showed that times between successive failures for the hydraulic systems are in most cases not independent and identically distributed. Goodness-of-fit tests showed that the power law process model provides a good fit to the failure data of the hydraulic systems. Methods for parameter estimation in the power law process model and estimation of optimal maintenance intervals for such systems are presented. Emphasis is on the use of graphical methods for data analysis.     

Measuring psychosocial work quality and health: Development of health care measures of measurement.

Demands on workload and work efficiency have increased because of ongoing global changes in health care organizations. Assessing and evaluating effects of changes on organizational and individual well-being require valid and reliable methods. Questionnaires from 3 large health care studies were used to develop instruments for work quality and health. Study 1 included 2,935 participants from all occupational groups. Study 2 sampled 3,545 nurses and midwives. Participants in Study 3 consisted of 3,506 employees at a large hospital. Variable fields of work quality, health and well-being, and modifying factors were factor analyzed with replicated structures in new samples, including 6 factors of work quality, 5 health factors, and 2 modifying factors. All except 2 factors had high internal consistency (Cronbach's α?=?.69–84) and low factor intercorrelations within areas. Social climate (but not individual resources) had, according to our model, a modifying effect on the work-health interaction (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

An approximate theory for calculation of roll torque during edge rolling of steel slabs

A roll torque model is derived for edge rolling. An upper bound solution assuming plain strain in the draught-spread plane is designed and the torque is derived. The torque and power calculated by the model is compared to power measurements in the edging stand of the hot strip mill at Fagersta Stainless AB. Slab shape after rolling is compared to estimated. The agreement between estimated and measured slab shape is very good. The calculated power is in good agreement with measurements for conventional stainless steel grade Fagersta R 350 (SS 2333), while the power is sligthly overestimated for the high alloy stainless steels Fagersta R 429 and R 560. The reason for this is probably the used flow-stress model. As the torque and power model is in good agreement with measurements it can be included in process control systems for width control.     

Wind energy potential in southern Sweden-Example of planning methodology

This study presents a planning model for Swedish activities in the field of wind power. Models and results of calculations of the land-based wind energy potential with the Wind Atlas Analysis and Application Programme, WA^sP, are described and analysed in a geographical information systems (GIS) called the ArcView^® GIS system. One county in southern Sweden was chosen as a case study to present the methods used. The results from that case study indicate a great wind energy potential but there are nevertheless many factors limiting that potential. The study calls for a further development of planning tools in the field. Important areas for the future are the development of knowledge in market issues, wind power technology, environmental issues, and public opinion on constructing wind turbines.     

Deformation and fracture of a long-rod projectile induced by an oblique moving plate: Experimental tests

The influence of projectile length to diameter ratio (15, 30 and 45), plate thickness (0.5, 1 and 2 projectile diameters), projectile velocity (1500, 2000 and 2500 m/s) and plate velocity (−300 to 300 m/s) on the interaction between long-rod tungsten projectiles and oblique steel plates (obliquity 60°) was studied experimentally in small-scale reverse impact tests. The residual projectiles and their motions were characterised in terms of changes in length, velocity, angular momentum, linear momentum and kinetic energy. The parameters found to have the largest influence on the disturbance of the projectile were the plate velocity, in particular its direction, and the thickness of the plate. In the ranges studied, the influence of length to diameter ratio and of projectile velocity were found to be less important.     

An improved dynamic solar collector test method for determination of non-linear optical and thermal characteristics with multiple regression

The objective is to characterise the solar collector during a relatively short testing period with no requirement for steady state climatic conditions. This information is then used for predicting annual performance of the collector. A standard collector model that is compatible with the ISO 9806-1 test standard is used with correction terms for beam and diffuse incidence angle modifiers, thermal capacitance, wind speed and sky temperature. This results in a more complete characterisation of the collector. The collector parameters are identified by multiple linear regression, MLR. The method has been tested for characterisation of unglazed collectors, glazed flat plate collectors, evacuated tubular collectors, CPC collectors and concentrating collectors with satisfying results. Typically the correlation coefficient R² is better than 0.99 and the standard deviation of the difference between model and measurement is in the range 3–10 W/m².

In the original method the angular dependence of the optical efficiency and the temperature dependence of the heat losses are supposed to be adjusted to a predetermined function. The most recent development is a routine that makes it possible to accurately identify non-linear optical and thermal performance. This extended MLR method can identify the zero loss efficiency for every angle of incidence interval and the temperature dependent heat losses for every temperature interval. This opens the application of the method to collectors with special incidence angle and heat loss effects that cannot be described easily with a combination of elementary functions. Instead a table of parameter values is determined, which is used directly in standard simulation programmes. This method will further increase the accuracy when comparing different collector designs. It has been used for comparing different glazings and for comparison with spectrophotometric measurements. It has also been used for analysing the heat loss factors for Teflon and honeycomb glazings. Since the total power output of the collector is less dependent on the heat loss coefficient than on the optical efficiency the scattering in this data is larger than for the incidence angle curves.

The reflectance of booster mirrors cannot be derived with the MLR-method with acceptable accuracy. The correlation between direct irradiance and irradiance from the reflector exhibit a very strong correlation. Instead the effective reflectance of the mirror can be estimated by comparison of the measured output with calculation by the complete collector and reflector model. This effective reflectance is not compatible with the specular reflectance obtained from spectrophotometric measurements caused by large differences in acceptance angles.

Standard multiple linear regression available in most spread sheet and statistical programs can be used for the parameter identification in the extended MLR-procedure. The identification takes only a few seconds. At the Älvkarleby Laboratory the test method is now used as a routine tool for the evaluation of new collector materials and designs. The Swedish National testing institute has evaluated the methods with the conclusion that they have a potential for being used in standardised collector testing.