The use of the Novosol process for the treatment of polluted marine sediment

The work presented in this article concerns polluted marine sediments. The article is divided into three parts. The first part discusses existing industrial procedures of treatment. The second part introduces the Novosol((R)) process, which was used for the treatment of polluted marine sediments. This process is based on the stabilization of heavy metals in the solid matrix by phosphatation and the destruction of organic matter by calcination. Finally, after a comparison had been made between environmental results obtained on both polluted marine sediments and inert ones, treated sediments were introduced in the production of clay bricks. The results obtained show that the Novosol process leads to the immobilization of most heavy metals and can be considered as an efficient tool for the stabilisation of polluted marine sediment. Thus, the results of physical and mechanical tests as compressive strength and water absorption indicate that performances obtained were comparable to standard brick values. These results confirm that, once treated, polluted sediments can be recycled.     

A poly(cyclopentadithiophene) matrix suitable for electrochemically controlled DNA delivery

A conducting polymer is tested for DNA delivery trials. The conducting matrix used is successful for electrochemical delivery of DNA accumulated by covalent immobilization. The electrochemical process consists of the reduction of arylsulfonamide moieties, which occur as linker groups. The specific design of the polymer allows the electronic properties to be promoted, making available the cleavage potential in physiological media. The amount of DNA released from a modified platinum electrode is investigated by quartz crystal microbalance. The released species used to prove the system performance are long sequences of DNA strands, which are amplified by PCR after liberation and identified by electrophoresis migration.     

A Low-Complexity Hybrid Framework for Combining-Type Non-regenerative MIMO Relaying

Combining-type relay systems can benefit from distributed array gain if the signals retransmitted from different relays are superimposed coherently at the destination. For this purpose, we propose a low-complexity hybrid framework in which the non-regenerative multiple-input-multiple-output relaying matrix at each relay is generated by cascading two substructures, akin to an equalizer for the backward channel and a precoder for the forward channel. For each of these two substructures, we introduced two one-dimensional parametric families of candidate matrix transformations. The first family, non-cooperative by nature, depends only on the backward or forward channel of the same relay. The second (cooperative) family also makes use of information derived from the channels of other relays. This hybrid framework allows for the classification and comparison of all possible combinations of these substructures, including several previously investigated methods and their generalizations. The design parameters can be optimized based on individual channel realizations or on channel statistics; in the latter case, the optimum parameters can be well approximated by linear functions of the signal-to-noise ratios. The proposed methods achieve a good balance between performance and complexity: they outperform existing low-complexity strategies by a large margin in terms of both capacity and bit-error rate, and at the same time, are significantly simpler than previous near-optimal iterative algorithms.     

Removal of dark coloured and polyphenolic compounds of sugar beet vinasse by adsorption onto activated carbons: Application to a crosscurrent adsorption process

Sugar beet distillery vinasse is rich in betaine but the recovery of betaine by ionic exchange first requires removing ethanol‐insoluble compounds as well as dark coloured and polyphenolic compounds. The adsorption kinetics and isotherms of the latter compounds were studied on two commercial activated carbons. The results show that the pseudo‐second order kinetic model provided the best correlation, and the Langmuir model was selected for describing the isotherms. The data can be used to conduct experiments with a view to applying the crosscurrent process methodology to determine the number of stages necessary for the discolouration of the solution. © 2011 Canadian Society for Chemical Engineering     

Analysis of reliability and optimization of ESD protection devices supported by modeling and simulation

An analysis of electrostatic discharge (ESD) protection structures supported by advanced 2-D mixed mode electro-thermal device and circuit simulation with calibrated electro-physical models to increase the reliability of protected IC’s is presented. The critical temperature as a criterion of device destruction is defined and experimentally verified. Numerical simulation and visualization of the internal electro-physical properties of the analyzed structures during a very short ESD pulse considerably improved the understanding of their physical behavior and contributes to a proper design and optimization of doping and geometry of the analyzed ESD protection devices. The analyzed devices are designed as protection against Human Body Model (HBM) and International Electromechanical Commission model (IEC) 61000-4-2 with very high robustness. The obtained results are shown on two examples. Modification of the device layout by splitting the cathode contact of the ESD diode into two parts allowing area reduction with improved electrical characteristics is the subject of the first example. The influence of doping fluctuations on the device robustness is presented in the second example. Different triggering and failure mechanisms of the diode and transistor structure during HBM and IEC pulse are presented.     

Lattice Relaxation and Dislocation Reduction in MBE CdTe(211)B/Ge(211)

We have used x-ray diffraction to assess the thickness dependence of strain in molecular-beam epitaxial (MBE) CdTe(211)/Ge(211). For 25-nm-thick layers, we find tensile stress of 100 MPa and in-plane strain of ~1.5 × 10⁻³. This stress relaxes during growth and becomes zero beyond 1 μm. We use the Dunn and Koch formula to estimate the threading dislocation density from the full-width at half-maximum of the (224) rocking curve. We then estimate the annihilation radius of MBE-grown CdTe(211)B/Ge(211) to be ~10 nm. Our layers have etch pit densities between 5 × 10⁷ cm⁻² and 5 × 10⁶ cm⁻² for a thickness of 10 μm. The lowest densities were obtained by periodic annealing epitaxy. We discuss mechanisms for the saturation of the dislocation density.     

Absence of 2'-deoxyguanosine-carbon 8-bound ochratoxin A adduct in rat kidney DNA monitored by isotope dilution LC-MS/MS

The contribution of DNA adduct formation in the carcinogenic action of the mycotoxin ochratoxin A (OTA) has been subject to much debate. Recently, a carbon-bonded ochratoxin A-2'-deoxyguanosine adduct (dGuoOTA) formed by photochemical reaction in vitro has been shown by 32P-postlabeling/TLC to comigrate with a spot detected in DNA isolated from rat and pig kidney following exposure to OTA. Considering the large body of evidence arguing against covalent DNA binding of OTA and the poor resolution and specificity of postlabeling analysis, we developed a stable isotope dilution LC-MS/MS method to analyze dGuoOTA in kidney DNA isolated from rats treated with OTA. dGuoOTA and nitrogen-15-labeled dGuoOTA (15N(5)-dGuoOTA) were prepared by photoirradiation of OTA in the presence of dGuo or nitrogen-15-labeled dGuo. Conditions for DNA hydrolysis were optimized using a synthetic oligonucleotide containing dGuoOTA to ensure complete release of dGuoOTA. The LOD of the method (S/N > 3) was 10 fmol dGuoOTA on-column. However, dGuoOTA was not detected in DNA samples isolated from male F344 rats treated with OTA for up to 90 days at doses known to cause renal tumor formation. Detection limits, calculated for each individual sample based on the absolute LOD and the amount of DNA injected, were as low as 3.5 dGuoOTA/10(9) nucleotides. These data are consistent with previous results showing lack of DNA adduct formation by OTA and demonstrate that dGuoOTA is not formed in biologically relevant amounts under physiological conditions in vivo.     

The interplay of mastery and performance goals in social comparison: A multiple-goal perspective.

Régner, Escribe, and Dupeyrat (2007) recently demonstrated that not only performance-approach and performance-avoidance goals (respectively, the desire to outperform others and not to be outperformed by others) but also mastery goals (the desire to acquire knowledge) were related to social comparison orientation (SCO, the tendency to search for social comparison information). In the present article, the possibility of a link between mastery goals and social comparison that depends on the level of performance-approach goals—a possibility supported by a multiple-goal perspective—was tested by examining the interaction effect between mastery and performance-approach goals. This is an important endeavor, as educational settings are rarely free from performance-approach goals, even when mastery goals are promoted. In Study 1, we tested self-set achievement goals (mastery, performance-approach, and performance-avoidance goals) as predictors of SCO; the interaction between mastery goals and performance-approach goals indicated that the higher the performance-approach goal endorsement, the stronger the link between mastery goals and SCO. In Study 2, we manipulated goal conditions; mastery goals predicted interest in social comparison in the performance-approach goal condition only. Results are discussed in terms of the importance of multiple-goal pursuit in academic settings. (PsycINFO Database Record (c) 2010 APA, all rights reserved)