Waste green sands as reactive media for groundwater contaminated with trichloroethylene (TCE)

Waste green sands are byproducts of the gray iron foundry industry that consist of sand, binding agents, organic carbon, and residual iron particles. Because of their potential sorptive and reactive properties, tests were conducted to determine the feasibility of using waste green sands as a low cost reactive medium for groundwater treatment. Batch and column tests were conducted to determine the reactivity, sorptive characteristics, and transport parameters for trichloroethylene (TCE) solutions in contact with green sands. Normalized rate constants for TCE degradation in the presence of iron particles extracted from green sands were found to be comparable to those for Peerless iron, a common medium used to treat groundwater. Rate constants and partition coefficients obtained from the batch tests were found to be comparable to those from the column tests. Analytical modeling shows that reactive barriers containing green sand potentially can be used to treat contaminated groundwater containing TCE at typical concentrations observed in the field.     

A data model for managing drug therapy within a patient data management system for intensive care units

The major intent of this article was to describe the design principles of the drug-therapy documentation module of the Patient Data Management System (PDMS) ICUData, in routine use at the intensive care unit (ICU) of the Department of Anesthesiology and Intensive Care Medicine at the University Hospital of Giessen, Germany, since February 1999. The new drug management system has been in routine use since March 2000. Until 8 January 2001, 1140 patients have been documented using this approach. It could be demonstrated that it was possible to transform the formerly unstructured text-based documentation into a detailed and structured model. The mediated benefit resulted in the automatic calculation of fluid balance. Further, detailed statistical analyses of therapeutic behavior in drug administration are now possible.     

Midlatitude cirrus cloud climatology from the Facility for Atmospheric Remote Sensing. IV. Optical displays

In this fourth of a series of papers that describe long-term cloud research at the Facility for Atmospheric Remote Sensing at Salt Lake City, Utah, an approximately 10-year record of polarization lidar and photographic observations is analyzed to characterize the occurrence of optical displays in our local varieties of midlatitude cirrus clouds. The frequencies of occurrence of various types of halo, arc, and corona displays are evaluated according to their appearance and longevity over nominal 1-h observation periods and to the meteorological source of the cirrus. We find that complex halo-arc displays are rare at our locale and that even the so-called common 22 degree halo occurs infrequently as a complete long-lived ring. For example, only approximately 6% of the 1561-h daytime cirrus periods have bright and prolonged 22 degree halos, although a total of 37.3% have some indications of this halo, even if they are brief and fragmentary. Other fairly frequent features are the 22 degree upper tangent arc (8.6%), 22 degree parhelia (8.5%), and solar corona (7.2%). Of the optical displays observed, 83.6% are refraction based, only 1.9% are due to reflection phenomena, and a surprising 15.4% are caused by diffraction. Complex halo-arc displays are disproportionally associated with cirrus formed in tropical or subtropical airflow and also contain more horizontally oriented planar ice crystals. Lidar linear depolarization ratios from a subset of vivid displays show significant differences between halo- and the corona-producing cirrus, reflecting the effects of particle shape. Halos are associated with relatively warm cirrus that contain randomly and horizontally oriented planar ice crystals, whereas the colder corona cirrus produce much stronger depolarization from crystals too small to be uniformly oriented. Comparisons are made with available information from other locales, and we attempt to explain the geographical differences in terms of basic cirrus cloud processes.     

Catalytic effects of carbon sorbents for mercury capture

Activated carbon sorbents have the potential to be an effective means of mercury control in combustion systems. Reactions of activated carbons in flow systems with mercury and gas stream components were investigated to determine the types of chemical interactions that occur on the sorbent surface. The effects of carbon type, particle size, temperature, and reactive gases were studied. Sorption kinetics and capacities for lignite- and bituminous-based carbons were compared with those for catalytic carbons at temperatures of 107 degrees C, 150 degrees C, and 163 degrees C. In the air and baseline gas studies, the catalytic carbons exhibited far better sorption than the lignite- and bituminous-derived carbons. With the catalytic carbons, the greater sorption kinetics and capacity in an air stream or baseline gas composition compared with nitrogen provides a clear demonstration that O(2) is required in the gas stream for higher reactivities and capacities. Thus, a catalytic chemisorption mechanism predominates for the sorption of mercury at these conditions. The reaction kinetics are inversely proportional to the temperature, indicating that a preliminary physisorption step with mercury associating with a surface site is rate-determining. In synthetic flue gas streams containing HCl (50 ppm), the sorption kinetics of the catalytic carbon are slightly inferior to those of lignite-based carbon. Thus, the reaction is dominated by a different interaction, where HCl reacts with mercury on the carbon surface and the oxidation sites on the catalytic carbon apparently have no advantage. Granular and fine-particle carbons gave similar results in flue gas streams.     

Measuring up [UK national measurement programme]

A recent government-sponsored survey found that barely one UK company in ten was aware of the national measurement services available, The author outlines a new programme set up to change that statistic     

Durability issues and service lifetime prediction of electrochromic windows for buildings applications

In general, the purposes of this paper are to elucidate the crucial importance of durability and service lifetime prediction (SLP) for electrochromic windows (ECWs) and to present an outline for developing a SLP methodology for ECWs. The specific objectives are (a) to illustrate the generic nature of SLP for several types of solar energy conversion or energy conservation devices, (b) to summarize the major durability issues associated with ECWs, (c) to justify using SLP in the triad of cost, performance, and durability rather than just durability, (d) to define and explain the seven major elements that constitute a generic SLP methodology, (e) to provide background for implementing the SLP methodology for ECWs, including the complexity of the potential degradation mechanisms, and (f) to provide an outline of studies using ECWs for improving the durability of ECW materials and predicting a service lifetime for ECWs using the SLP methodology outlined in objective (d). Our major conclusions are that substantial R&Dis necessary to understand the factors that limit ECW durability, and that it is possible to predict the service lifetime of ECWs.     

Efficacy of two behavioral treatment programs for comorbid geriatric insomnia.

Older adults with comorbid insomnia and medical illness have been excluded from behavioral treatment research, but recent evidence suggested that such treatments would be effective with this population. In this study, 38 older adults with comorbid insomnia were randomized to 1 of 3 conditions: classroom cognitive-behavioral treatment (CBT), home-based audio relaxation treatment (HART), or delayed-treatment control. Compared to the control group, the CBT group had significant changes in 5 of 7 self-report measures of sleep at the 4-month follow-up. The HART group obtained significant outcomes on 3 of 7 measures. Wrist actigraphy measures and secondary-outcome measures did not yield significant findings for either treatment. Clinically significant changes at follow-up were obtained for 54% of patients in CBT, 35% in HART, and 6% in the control group when treatment dropouts were included. Although not as effective as in-person CBT, home interventions may have utility as a first-line, low-cost treatment. (PsycINFO Database Record (c) 2010 APA, all rights reserved)