N取代吩噻嗪衍生物的合成及其铜离子传感性能

以1-氯-4(4-氯苯基)酞嗪为原料,用吩噻嗪上氮原子取代1号位的氯原子生成新化合物1-吩噻嗪-4(4-氯苯基)酞嗪(PzCBP),采用核磁、质谱、单晶X射线衍射对其分子结构进行表征。选择14种主要的过渡金属及碱土金属阳离子对其进行荧光滴定实验,研究PzCBP对金属离子的荧光响应性质。结果表明:PzCBP在乙腈溶液中的紫外吸收波长为288 nm,最大发射波长为413 nm;该化合物具有对Cu2+的选择性荧光淬灭性能,其与Cu2+的物质的量比值为1.0,在0~10μmol/L范围内对Cu2+的响应曲线进行拟合,检测限达到0.09μmol/L,能作为Cu2+的荧光探针。     

特种阻燃材料涂膜石棉织物的开发

采用高分子功能膜涂覆石棉织物。涂膜为有机硅、有机氟通过共聚改性特种丙烯酸酯类,具有阻燃、防霉、防油气外溢等功能,在保留石棉防火被阻燃功能的同时,使应用性能进一步提升,显示了良好开发前景。     

EXPERIMENTAL INVESTIGATIONS OF CAVITATION EFFECTS ON FLOW CHARACTERISTICS OF SMALL ORIFICES AND VALVES IN WATER HYDRAULICS

The flow characteristics and cavitation effects of water passing through small sharp-edged cylindrical orificesand valves of different shapes in water hydraulics are investigated. The test results using orifices with different aspect ratios and different diameters show that the flow coefficients in the case of non-cavitating flow are larger than that of flow inthe case of cavitation occurrence. The flow coefficients of flow with cavitation initially decrease as Reynolds number increases and ultimately tend to be of constant values close to contraction coefficient. Large aspect ratio has an effect ofsuppressing cavitation. The experimental results about disc valves illustrate that the valves with sharp edge at large opening are less affected by cavitation than that at small opening. Throttle with triangle notch has better anti-cavitation abilitythan that with square notch. The flowrate of the throttle with square notch is significantly affected by the flow direction orthe flow passage shape.     

Comparing of system reliabilities of repairable coherent systems in a changing environment

In this paper multicomponent reliability systems are considered where component failure rate and repair completion rate depend on the environment state and, ages and current repair durations of the other components. this is a generalization of the model of Shaked M. and Shanthikumar J.G.[3]. Sufficient conditions on the set of the rates which imply stochastic ordering between first failure times of two such systems are found. Sufficient conditions on rates which imply that the first failure time of such a system is new better than used(NBU) are given. Some results of [3] may be regarded as the special cases of our assertions.     

星载激光测高仪大气传输延迟对测距精度的影响

地球表层的大气折射可对激光测高仪的激光脉冲传输造成延迟,该延迟对激光飞行时间的测量精度以及地球表面三维轮廓的监测造成显著影响.因此,激光测高仪测距精度需要通过大气传播误差函数进行修正.着重讨论了激光脉冲基于天顶延迟的计算方法和相关映射函数模型的选择,并采用NMF连分式映射函数分别对干项和湿项进行计算.结果表明,在1.0...     

超级13Cr油套管在含H2S气井环境下的腐蚀试验

近20年来,在国内外H₂S/CO₂共存环境、高含Cl^-的深井或复杂水平井中,为保障井筒寿命并控制耐蚀合金管柱成本,超级13Cr不锈钢油套管的应用逐步增多,而ISO等标准中对于超级13Cr油套管的适用条件规定严格,特别是在超级13Cr的抗硫化物应力开裂影响因素方面,不同学者研究认识不统一。为此,模拟陕北某区块含H₂S气井腐蚀环境,利用电化学系统和高压腐蚀测试系统,评价了超级13Cr油套管的电化学和抗硫化物应力开裂能力。结果表明,在模拟环境下的超级13Cr电化学腐蚀速率为0.01 mm/a,而传统13Cr的腐蚀速率为0.26 mm/a。同时在抗硫化物应力开裂试验中,加载80% AYS和90% AYS下的超级13Cr没有出现NACE标准溶液试验下的开裂问题。该结果为类似气井环境下的超级13Cr应用提供了一定的参考。     

水压阀关键技术的研究

基于水压阀的研究现状和本文所进行过的相关研究得出结论：从摩擦学的角度选择合理“阀芯-阀套”相互适宜的材料配对和设计有利于抑制空化产生的合适的阀口几何结构形式是研制水压阀的关键技术难点。基于这两方面的技术问题，还介绍了目前可能的技术解决方案。     

用DPC内涂层套管控制油水井内腐蚀研究

中国石油长庆油田分公司部分油井管柱遭受严重的内腐蚀。研究了DPC内涂层的主要性能,结果表明DPC内涂层质量可满足控制油井套管内腐蚀的要求。提出了DPC内涂层套管的实施工艺,并累计成功实施了75口井。     

传感器现场校准测试系统电气系统设计与实现

传感器现场校准测试系统用于对运载火箭装配的脉冲频率输出式压力传感器的静态性能、压力开关及磁敏行程开关传感器的静态和动态性能进行测试,此测试系统解决装箭状态下压力开关响应时间测试问题。电气系统基于RS-232串口通信上、下位机模式。下位机软件功能模块间接口清晰,提高了软件的可扩展性、可移植性和可维护性,且源代码易于理解。