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91.
Tensile tests were performed on high-purity W and Mo polycrystals at room temperature for a range of axial strain-rates 2.1 × 10−4–2.1 × 10−2 s−1. The critical resolved shear stress (CRSS) data was analyzed by using the analytical formulation for the strain-rate dependence
of the CRSS derived in the kink-pair nucleation (KPN) model of flow stress in crystals with high intrinsic lattice friction.
On evaluation of various microscopic slip-parameters of the model, the active slip-system in both W and Mo polycrystals was
identified as {110}〈111〉. This is in good agreement with that deduced from the published data on the temperature dependence
of the CRSS of these crystals as well as from the observed slip-lines on the deformed crystals reported in the literature.
Moreover, the available data on the temperature dependence of the CRSS of Mo, Nb, Fe, V, and K crystals were also analyzed
within the framework of the KPN model of flow stress. Peierls mechanism was found to be responsible for the CRSS of these
metals; the active slip-systems in refractory metals Mo, Nb, Fe, and V were {110}〈111〉 and {211}〈111〉 whereas that in alkali
metal K was {321}〈111〉. 相似文献
92.
The U─Zr─C tertnary phase diagram is optimized by graphical and numerical curve fitting of self-consistent thermodynamic and phase diagram data reported in the literature. The system is described from 2473 to 3693 K using isothermal ternary phase diagrams. The solidus and liquidus curves of the Ux Zr1−x Cy solid solution were estimated from combined thermodynamic and phase diagram data. The solidus and liquidus curves in the ternary system were calculated using a modified form of a free-energy minimization method developed by Rudy and Chang. The calculated curves agree with experimental data. 相似文献
93.
R. U. Vaidya A. H. Bartlett H. Kung D. P. Butt 《Journal of Materials Science Letters》1998,17(9):777-780
94.
The patch-clamp technique was used to characterise the ion channels in cells located in the mid region of mouse jejunal crypts. Six different channels were seen. A large outwardly rectified K+ channel (BK) (conductance, g at 0 mV = 92 +/- 6 pS), which was highly selective for K+ [PK+ (1) > PRb+ (0.6) > PCs+ (0.09) approximately PNa+ (0.07) > PLi+ (0.04)], had a low, voltage-independent open probability (Po) in the on-cell (O/C) configuration and appeared in 66% of the patches. In inside-out (I/O) patches, this channel had a linear current/voltage (I/V) relationship (g = 132 +/- 3 pS), Po was voltage dependent and it was blocked by cytoplasmic Ba2+ (5 mmol/l). An intermediate K+ channel (IK) which was present in 49% of O/C patches, had a linear I/V (g = 38 +/- 3 pS), ran-down in O/C patches, and was not seen in I/O patches. A number of smaller channels (SC) with conductances ranging from 5 to 20 pS were seen in 16% of O/C patches. Also present in the basolateral membrane were a Cl- channel (ICOR) and a nonselective cation channel (NSCC). These channels were only seen in I/O patches. ICOR had an outwardly rectified conductance (g at 0 mV = 36 +/- 2 pS), its Po was independent of voltage and unaffected by variations in cytoplasmic Ca2+ (100 nmol/l to 1 mmol/l) or ATP (0-1 mmol/l). The NSCC had a linear conductance (20 +/- 1 pS), its Po increased with depolarisation and elevation of cytoplasmic [Ca2+] (> or = 10 micromol/l), but was reduced by cytoplasmic ATP. None of the basolateral channels described here were activated by cAMP-dependent secretagogues, although a Cl- conductance was activated. This cAMP-dependent Cl- conductance was distinct from the basolateral Cl- channel and thus is most likely located in the apical membrane. 相似文献
95.
96.
A state-space oriented approach to analyze dynamic errors in a hybrid computer simulation loop is presented. The approach helps to predict the value of the sampling interval that achieves stable simulation with a prescribed accuracy. A pre-perturbation technique to compensate for the serious digital execution time delay error is then developed. It has the advantages that it does not require additional computer hardware and/or software and its utilization does not result in generation of any extraneous modes.The approach points out the contribution of each individual error source in the hybrid computer loop to the overall simulation accuracy. 相似文献
97.
Modern techniques for analysis of X-ray diffraction profiles have been applied to several of the platinum-silica gel catalysts described in Part I to determine average platinum crystallite size, percentage exposed, crystallite shape, size distribution, lattice parameter, residual stresses and strains, presence or absence of faulting, and mean-square amplitude of vibration. In addition the surface area of the gel was determined with small-angle scattering (SAS). There is good agreement between the percentage exposed of platinum measured by gas adsorption in Part I and the results reported here, calculated from crystallite sizes, indicating the crystallite size is the true platinum particle size. Crystallites to sizes as small as ≈25 Å have been examined. Furthermore, the crystallites are equiaxed in shape (and definitely not cuboidal) and are strain and defect free, except in the case where the average size is near the pore size of the gel. Size distributions are sharper when the catalyst preparation is by impregnation rather than by ion exchange. The size distributions indicate that there is coalescence of some surface species during preparation rather than coarsening (Ostwald ripening). The meansquare amplitude of vibration of platinum increases by ≈30% as the particles decrease in size from ≈100 to ≈25 Å. There is no change in the lattice parameter greater than ≈0.1%. The gel surface areas determined by SAS are in agreement with those determined in Part I by physisorbtion of nitrogen. 相似文献
98.
Bilal S. Hamad Ahmad A. Rteil Bruno R. Salwan Khaled A. Soudki 《Canadian Metallurgical Quarterly》2004,8(3):248-257
This paper reports on the third phase of a multiphase study undertaken at the American University of Beirut (AUB) to examine the effect of fiber-reinforced polymer (FRP) sheets in confining tension lap splice regions in reinforced concrete beams. Results of the first two phases showed that glass and carbon fiber-reinforced polymer (GFRP and CFRP) sheets were effective in increasing the bond strength and improving the ductility of the mode of failure of tension lap splices in high-strength concrete (HSC) beams with nominal concrete strength of 70 MPa. The experimental results of the two phases were used to propose a new FRP confinement parameter, Ktr,f, that accounts for the bond strength contribution of FRP sheets wrapping tension lap splice regions in HSC beams. In this third phase of the AUB study, the trend of the results of phases 1 and 2 and the validity of the analytical model proposed were verified if normal-strength concrete (NSC) is used instead of HSC. Seven beams with nominal concrete strength of 27.58 MPa (4 ksi) were tested in positive bending. Each beam was designed with a tension lap splice in a constant moment region in the midspan of the beam. The main test variables were the configuration (1 strip, 2 strips, or a continuous strip) and the number of layers (1 layer or 2 layers) of the CFRP sheets wrapping the splice region. The test results demonstrated that CFRP sheets were effective in enhancing the bond strength and ductility of failure mode of tension lap splices in NSC in a very similar way to HSC. In addition, the FRP confinement index proposed earlier for HSC was proven to be valid in the case of NSC. 相似文献
99.
100.
The simultaneous absorption of two gases accompanied by chemical reaction into a slurry of fine suspended particles was numerically analysed using the model obtained with some extension of the corresponding single gas absorption.Experiments were performed for the simultaneous absorption of sulfur dioxide and carbon dioxide with a plane gas—liquid type stirred tank absorber. The experimental results were satisfactorily elucidated by the proposed model and it is suggested that when accompanied by sulfur dioxide absorption, carbon dioxide may almost be regarded as an inert gas. 相似文献