Weldability and microstructural variations in weldments of Ti-5Ta-1.8Nb alloy

The successful replacement of the present generation of corrosion-resistant materials (nitric acid-grade stainless steel and Ti) by Ti-5Ta-1.8Nb, which has better corrosion resistance, depends on its weldability characteristics. This article presents the results of a study on the fabrication, qualification, and microstructural characterization of the welds. Welding was carried out using the direct current electrode negative (DCEN) polarity tungsten inert gas (TIG) (manual) welding method with high-purity Ar shielding. Testing was carried out as per the ASME standard (section IX, welding and brazing). Qualification tests found that the weldment met the required properties. The weldment showed heterogeneous microstructures, which are rationalized based on differences in phase transformation mechanisms that are dictated by the thermal cycles experienced by various microscopic regions. The results, described in this article, confirm that the weldability of the developmental Ti-Ta-Nb alloy is excellent. A preliminary evaluation of the corrosion behavior of the welds showed rates comparable to that of the base metal, establishing that this alloy could be considered as an alternative material for use in highly corrosive environments.     

Kharitonov''s theorem revisited

A simple interpretation of Kharitonov's theorem is given.     

Kinetics of Melt Crystallization of a Sunflower Oil‐Based Polyunsaturated Fatty Acid Mixture

Important parameters like supercooling and cooling rates affecting the melt crystallization of a polyunsaturated fatty acid (PUFA) mixture obtained from sunflower oil were investigated and compared via high‐resolution polarized‐light microscopy. PUFA was thermally characterized in a differential scanning calorimeter and the significant liquid‐solid‐phase transition temperatures determined were then implemented in the development of specific temperature profiles. Analyzed between two glass slides, induction times were found to decrease with low crystallization temperatures and the number of nuclei per unit area increased with higher supercooling and cooling rates. A comparison between the linear crystal growth rates of pure standards of each of the main fatty acids present in the PUFA mixture and the PUFA mixture itself indicated that the latter is much slower than that of each of its pure components.     

Cover Feature: Superior Proton-Transfer Catalytic Promiscuity of Cytochrome c in Self-Organized Media (7/2021)

Evolutionarily elderly proteins commonly feature greater catalytic promiscuity. Cytochrome c is among the first set of proteins in evolution to have known prospects in electron transport and peroxidative properties. Here, we report that cyt c is also a proficient proton-transfer catalyst and enhances the Kemp elimination (KE; model reaction to show proton transfer catalytic property) by ∼750-fold on self-organized systems like micelles and vesicles. The self-organized systems mimic the mitochondrial environment in vitro for cyt c. Using an array of biophysical and biochemical mutational assays, both acid–base and redox mechanistic pathways have been explored. The histidine moiety close to hemin group (His18) is mainly responsible for proton abstraction to promote the concerted E2 pathway for KE catalysis when cyt c is in its oxidized form; this has also been confirmed by a H18A mutant of cyt c. However, the redox pathway is predominant under reducing conditions in the presence of dithiothreitol over the pH range 6–7.4. Interestingly, we found almost 750-fold enhanced KE catalysis by cyt c compared to aqueous buffer. Overall, in addition to providing mechanistic insights, the data reveal an unprecedented catalytic property of cyt c that could be of high importance in an evolutionary perspective considering its role in delineating the phylogenic tree and also towards generating programmable designer biocatalysts.     

Human Age Recognition by Electrocardiogram Signal Based on Artificial Neural Network

Sensing and Imaging - Multimodal image fusion is a process of combining multiple images, generated by identical or diverse imaging modalities, to get precise inside information about the same body...     

Mineral element composition of spinach

An extensive study has been made on the mineral element compositions of spinach leaves and stems. Twenty two locally grown different spinach samples have been analysed for 16 elements using ICP and atomic absorption spectrophotometric techniques. Both spinach leaves and stems were analysed separately. A detailed elucidation of the inorganic matrix in spinach leaves and stems has been provided. © 1998 SCI.     

A new normalized relatively stable lattice structure

This paper proposes a new lattice filter structure that has the following properties. When the filter is linear time invariant (LTI), it is equivalent to the celebrated Gray-Markel lattice. When the lattice parameters vary with time, it sustains arbitrary rates of time variations without sacrificing a prescribed degree of stability, provided that the lattice coefficients are magnitude bounded in a region where all LTI lattices have the same degree of stability. We also show that the resulting LTV lattice obeys an energy contraction condition. This structure thus generalizes the normalized Gray-Markel lattice, which has similar properties but only with respect to stability as opposed to relative stability     

A variational approach to path planning for hyper-redundant manipulators

Motion planning for hyper-redundant manipulators in a complicated and cluttered workspace is a challenging problem. Many of the path planning algorithms, based on cell decomposition or potential field, fail due to the high dimensionality and complex nature of the C-space. Probabilistic roadmap methods (PRM) which have been proven to be successful in high dimensional C-spaces suffer from the drawback of generating paths which involve a lot of redundant motion. In this paper, we propose a path optimizing method to improve a given path in terms of path length and the safety against the collisions, using a variational approach. The capability of variational calculus to optimize a path is demonstrated on a variety of examples. The approach succeeds in providing a good quality path even in high dimensional C-spaces.     

Moving from Weakly Endochronous Systems to Delay-Insensitive Circuits

We consider the problem of synthesizing the asynchronous wrappers and glue logic needed for the correct GALS implementation of a modular synchronous system. Our approach is based on the weakly endochronous synchronous model, which defines high-level, implementation-independent conditions guaranteeing correct desynchronization at the level of the abstract synchronous model. We can therefore factor the synthesis problem into (1) a high-level, implementation-independent phase insuring the weak endochrony of each synchronous module and (2) the actual wrapper synthesis phase, highly simplified by the high-level assumptions, yet flexible enough to produce various, efficient implementations.We focus here on the synthesis of delay-insensitive asynchronous wrappers from weakly endochronous synchronous modules, and show how this can be done for a simple DLX processor model.