Cave animals live under highly constant ecological conditions and in permanent darkness, and many evolutionary adaptations of cave-dwellers have been triggered by their specific environment. A similar “cave effect” leading to pronounced chemical interactions under such conditions may be assumed, but the chemoecology of troglobionts is mostly unknown. We investigated the defensive chemistry of a largely cave-dwelling julid group, the controversial tribe “Typhloiulini”, and we included some cave-dwelling and some endogean representatives. While chemical defense in juliform diplopods is known to be highly uniform, and mainly based on methyl- and methoxy-substituted benzoquinones, the defensive secretions of typhloiulines contained ethyl-benzoquinones and related compounds. Interestingly, ethyl-benzoquinones were found in some, but not all cave-dwelling typhloiulines, and some non-cave dwellers also contained these compounds. On the other hand, ethyl-benzoquinones were not detected in troglobiont nor in endogean typhloiuline outgroups. In order to explain the taxonomic pattern of ethyl-benzoquinone occurrence, and to unravel whether a cave-effect triggered ethyl-benzoquinone evolution, we classed the “Typhloiulini” investigated here within a phylogenetic framework of julid taxa, and traced the evolutionary history of ethyl-benzoquinones in typhloiulines in relation to cave-dwelling. The results indicated a cave-independent evolution of ethyl-substituted benzoquinones, indicating the absence of a “cave effect” on the secretions of troglobiont Typhloiulini. Ethyl-benzoquinones probably evolved early in an epi- or endogean ancestor of a clade including several, but not all Typhloiulus (basically comprising a taxonomic entity known as “Typhloiulus sensu stricto”) and Serboiulus. Ethyl-benzoquinones are proposed as novel and valuable chemical characters for julid systematics. 相似文献
In this article, the fixed‐time attitude tracking problem for rigid spacecraft is investigated based on the adding‐a‐power‐integrator control technique. First, a fixed‐time attitude tracking controller is designed to guarantee fixed‐time convergence of tracking errors. Then, by considering the presence of random disturbance and actuator faults, an adaptive fault‐tolerant attitude tracking controller is designed to guarantee tracking errors converge to a residual set of zero in a fixed time. The complete bounds on settling time are derived independently of initial conditions. The simulation results illustrate the highly precise and robust attitude control performance obtained by using the proposed controllers. 相似文献
Designing high-efficient and low cost of electrodes with seamless integration of substrate and electrocatalyst particles is of significant concern for electrocatalytic water splitting. In this study, we actualized in situ growth of Co3O4 nanoneedles on titanium (Ti) mesh (denoted as Co3O4@Ti) by a simple combination of hydrothermal approach and subsequently calcination treatment under relatively low temperatures. The as-prepared Co3O4@Ti samples were evaluated as anodes for electrocatalytic oxygen evolution reaction (OER) in alkaline electrolyte. It demonstrates that the optimized Co3O4@Ti electrode displayed good OER activity with a small overpotential of 416 mV at a current density of 20 mA cm?2, which is on a par with commercial RuO2 catalyst (overpotential of 403 mV at 20 mA cm?2). The satisfactory OER performance of Co3O4@Ti electrode is largely attributed to the seamless integration of conductive Ti mesh substrate and the direct growth of Co3O4 nanoneedles on Ti mesh with sufficient active sites. This study suggests the potential application of Co3O4@Ti electrode as preeminent OER catalyst.