The air composition and reactivity from outdoor and indoor mixing field campaign was conducted to investigate the impacts of natural ventilation (ie, window opening and closing) on indoor air quality. In this study, a thermal desorption aerosol gas chromatograph (TAG) obtained measurements of indoor particle‐ and gas‐phase semi‐ and intermediately volatile organic compounds both inside and outside a single‐family test home. Together with measurements from a suite of instruments, we use TAG data to evaluate changes in indoor particles and gases at three natural ventilation periods. Positive matrix factorization was performed on TAG and adsorbent tube data to explore five distinct chemical and physical processes occurring in the indoor environment. Outdoor‐to‐indoor transport is observed for sulfate, isoprene epoxydiols, polycyclic aromatic hydrocarbons, and heavy alkanes. Dilution of indoor species is observed for volatile, non‐reactive species including methylcyclohexane and decamethylcyclopentasiloxane. Window opening drives enhanced emissions of semi‐ and intermediately volatile species including TXIB, DEET, diethyl phthalate, and carvone from indoor surfaces. Formation via enhanced oxidation was observed for nonanal and 2‐decanone when outdoor oxidants entered the home. Finally, oxidative depletion of gas‐phase terpenes (eg, limonene and α‐pinene) was anticipated but not observed due to limited measurement resolution and dynamically changing conditions. 相似文献
This study employs a novel stress-based Hybrid–Bishop–Hill yield model approach to evaluate the yield surface of oxygen-free electronic copper samples. The local yield surface is determined from three parameters of crystal orientation and one parameter of geometrically necessary dislocation (GND). All four local state variables can be rapidly determined by analysis of measured electron backscatter diffraction patterns. Estimates for the polycrystalline yield surface are obtained by standard averaging procedures. The shape of the yield surface is most influenced by the texture of the material, while the volume of the envelope scales with the average GND density. However, correlations between crystal orientation and GND content modify the yield surface shape and size. While correlations between GND density and crystal orientation are not strong for most copper samples, there are sufficient dependencies to demonstrate the benefits of the detailed four-parameter model. The four-parameter approach has potential for improving estimates of elastic-yield limit in all polycrystalline materials. 相似文献
Problem: Planners may read plans often, but the profession continues to view the interpretation of plan content as something that is either too obvious or too unimportant to require explicit discussion. Plans are seldom adequately interpreted. This is regrettable because plans contain a rich variety of content and meaning. Purpose: This article calls for planners to “read through” plans, not just to grasp their essential ideas or the means of implementing those ideas, but also to perceive additional levels of meaning relating to a) a plan's place within a larger intellectual sphere, b) a plan's statement on the social and political values of the time, and c) a plan as a part of the history of the planning profession and the life of cities. Methods: I propose a visual approach to plan reading descended from Panofsky's (1939Panofsky, E.1939. Studies in iconology: Humanistic themes in the art of the Renaissance, New York, NY: Harper and Row. [Google Scholar]) theory of iconology and use this to examine three very different plans that describe different size cities (small, large, very large) during different periods over the past 80 years (the 1930s, 1960s, 2000s). I analyze three levels of meaning in each plan: its factual meaning, or “plain sense” (Mandelbaum, 1990Mandelbaum, S. J.1990. Reading plans. Journal of the American Planning Association, 56(3): 350–358. [Taylor &; Francis Online], [Web of Science ®], [Google Scholar]); its contextual meaning, or relation to political, social, economic, and physical conditions; and its temporal meaning, or setting within the scope of observations made by other plan readers in the perspective of elapsed time. Results and conclusions: Factual readings show that information may be found in diverse aspects of a plan document, from seemingly superficial aspects like its cover to unarguably central elements such as recommendations. Factual readings depend on understanding the relationships among different elements, and reveal information about the plan and its framers that may not otherwise be readily apparent. Contextual readings show us that plan recommendations are as much a product of contemporary conditions and norms as they are of plan-specific “survey and diagnosis” (Nolen, 1936Nolen, J.1936. Comprehensive city plan for Dubuque, Iowa, Dubuque, IA: City Planning and Zoning Commission. [Google Scholar]). This raises the question of whether plan quality is to be judged only in terms of skillful execution of concerns of the day or whether innovation is also important. Temporal readings reveal that plans and planning have changed dramatically over time, simultaneously confirming and questioning the conventional wisdom of planning history. Takeaway for practice: Many planners read plans on a regular basis, and plans continue to constitute the major printed currency of the planning profession. Both plans and planning will benefit if planners become more discerning readers of the profession's principal idea vessels. Formal plan interpretation is rare, but each planner can become a better plan interpreter. Research support: None. 相似文献
A dissimilar metal weldment consisting of SA508-309L-308L-304L is widely used in light-water nuclear reactors. These weldments demonstrate dissimilar susceptibility to stress corrosion cracking that are related to the microstructure, properties, and residual stress. In this work, microstructures, hardness, and the residual stress distribution of the dissimilar metal weldments were investigated, with the correlation of increased hardness in the heat-affected zone (HAZ) to the microstructure. 304L HAZ demonstrated similar grain morphology as the base material, and the increase in hardness was primarily attributed to the increased dislocation density. SA508 HAZ demonstrated a change of grain morphology resulting from the different peak temperatures and cooling rates. The increased hardness in the SA508 HAZ was attributed to the refined grain morphology, higher dislocation density, and higher number density of precipitates. A ~ 20–30-μm-wide martensitic zone formed at the fusion boundary of SA508-309L, where Cr-rich carbide precipitates were observed, with the average size and the number density of 44.1 ± 16.9 nm and 1.5 × 1021 m−3, respectively. Residual stress results demonstrated the largest tensile stress at 309L butter, indicating its high cracking susceptibility.
Aeration properties of acidified casein-stabilized emulsions containing liquid oil droplets have been compared to the whipping of dairy cream. The foam systems were characterized in terms of overrun, microstructure, drainage stability, and rheology. With acidification using glucono-δ-lactone, the casein-stabilized emulsions could be aerated to give foams of far higher overrun (>600%) than whipped cream (∼120%). The development of foam volume, stability and rheology in the aerated casein-stabilized emulsion systems was found to be strongly dependent on the pH and the concentration of added calcium ions. Whereas whipped cream is stabilized by partially coalesced fat globules, the casein emulsion foams are stabilized by aggregation (gelation) of the protein coat surrounding the oil droplets. Casein emulsion foams formed at low pH were found to be more stable than whipped cream, whilst those formed at high pH were predominantly liquid-like and unstable. Instability arose in the acidified casein emulsion foams mainly through gel syneresis. We conclude that there are substantial textural differences between whipped cream and acidified casein emulsion foams, especially in terms of the small-deformation rheology and the extent of the linear viscoelastic regime. 相似文献
This article documents that the hydrogen economy continues to attract significant attention among politicians, the media, and some academics. We believe that an explanation lies in the way that the hydrogen economy fulfills psychological and cultural needs related to a future world where energy is abundant, cheap, and pollution-free, a “fantasy” that manifests itself with the idea that society can continue to operate without limits imposed by population growth and the destruction of the environment. The article begins by explaining its research methodology consisting of two literature reviews, research interviews of energy experts, and the application of symbolic convergence theory, a general communications theory about the construction of rhetorical fantasies. We then identify a host of socio-technical challenges to explain why the creation of a hydrogen economy would present immense (and possibly intractable) obstacles, an argument supplemented by our research interviews. Next, we employ symbolic convergence theory to identify five prevalent fantasy themes and rhetorical visions—independence, patriotism, progress, democratization, and inevitability—in academic and public discussions in favor of the hydrogen economy. We conclude by offering implications for scholarship relating to energy policy more broadly. 相似文献