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101.
Stress Analysis of Elastic-Plastic Contact Damage in Ceramic Coatings on Metal Substrates 总被引:1,自引:0,他引:1
Anthony C. Fischer-Cripps † Brian R. Lawn Antonia Pajares ‡ Lanhua Wei § 《Journal of the American Ceramic Society》1996,79(10):2619-2625
An elastic-plastic analysis of damage in ceramic coatings on metal substrates from contacts with spherical indenters is made using finite element modeling. Computations are carried out specifically for plasma-sprayed alumina:titania on a soft steel. The algorithm assumes an elastic sphere with frictionless contact on a flat elastic-plastic layered specimen, and incrementally evaluates the expanding contact field as a function of applied load. Two key aspects of the contact field are examined: (i) the indentation stress-strain curve; (ii) the damage zone geometry. Composite coating/substrate indentation stress-strain curves are computed for two coating thicknesses, using input material parameters from iterative fits to data from control tests on free-standing coating and substrate materials. Contours of principal shear stresses, most notably those contours corresponding to yield zone boundaries in both the softer substrate and the harder coating, are mapped out in the fully plastic region. Corresponding distributions of tensile stresses are also mapped out, and are shown to correlate with the locations of transverse fractures in the coating. General implications concerning material and geometrical design of ceramic-based layer structures are discussed. 相似文献
102.
In Situ Processing of Silicon Carbide Layer Structures 总被引:1,自引:0,他引:1
Nitin P. Padture David C. Pender Sataporn Wuttiphan† Brian R. Lawn 《Journal of the American Ceramic Society》1995,78(11):3160-3162
A novel route to low-cost processing of silicon carbide (SiC) layer structures is desribed. The processing involves pressureless liquid-phase cosintering of compacted power layers of SiC, containing alumina (Al2 O3 ) and yttria (Y2 O3 sintering additives to yield and yttrium aluminum garnet (YAG) second phase. By adjusting the β:α SiC phase ratios in the individual starting powders, alternate layers with distinctively different microstructures are produced: (i) "homogeneous" microstructures, with fine equiaxed SiC grains, designed for high strength; and (ii) "heterogeneous: microstructures with coarse and elongate SiC grains, designed for high toughness. By virtue of the common SiC and YAG phases, the interlayer interfaces are chemically compatible and strongly bonded. Exploratory Hertzian indetation tests across a bilayer interface confirm the capacity of the tough heterogeneous layer to inhibit potentially dangerous cracks propagating through the homogeneous layer. The potential for application of this novel processing approach to other layer architectures and other ceramic systems is considered. 相似文献
103.
How garments contribute to performance of the clothing system during wear is of interest, as is understanding the value of using fabric properties to inform end-use characteristics. To investigate the influences of layering upper-body garments, four fabrics were used to construct two first-layer garments (wool and polyester) and two outer-layer garments (wool and membrane laminate). Over six sessions, 10 moderately trained males wore each first-layer garment as a single layer and in combination with each outer-layer garment while resting, running and walking in cold environmental conditions (8 ± 1°C, 81 ± 4% RH). Here, the type of garment arrangement worn (fabric type or number of layers) had little influence on heart rate, core body temperature and change in body mass. Weighted mean covered skin temperature was warmer and weighted mean next-to-skin vapour pressure was typically higher (following the onset of exercise) with two layers versus one. Differences among fabrics for individual properties were typically overstated compared to differences among corresponding garments for physiological and psychophysical variables under the conditions of this study. These findings inform the interpretation of particular fabric properties and highlight issues to be acknowledged during development/refinement of fabric test methods.
Practitioner Summary: We examined the way in which selected fibre, fabric and garment (layering) characteristics contribute to performance of the clothing system during wear under cold conditions. Selected properties of the constituent fabrics were found to provide limited insight into how garments perform during wear under the conditions of this study. 相似文献
104.
R. M. Butler 《加拿大化工杂志》1991,69(4):819-824
Petroleum can be produced more efficiently using horizontal wells instead of conventional wells. For a typical 16 hectare well spacing, the pressure drawdown is as small as one-fiftieth of that for conventional wells. In some cases, where coning is a problem in conventional production, horizontal wells allow operation with much less coproduction of the displacing fluid. In the thermal recovery of bitumen and heavy oils, the Steam-Assisted Gravity Drainage process with horizontal production wells allows the systematic sweeping of the reservoir with economic production rates and without steam bypass. This paper described and reviews the application of horizontal wells to the production of heavy crude oils and bitumen by both non-thermal and thermal methods. 相似文献
105.
Brian Amsden 《Polymer》2002,43(5):1623-1630
There are numerous models describing solute diffusion in polymer solutions. An analysis of these models demonstrates that none can provide a consistent explanation of the phenomenon observed for solutes that can be modeled as essentially solid spheres. For this reason, a new model based on a physical obstruction approach is presented. In this model, solute movement in the presence of polymer chains is assumed to be governed by the probability of the solute molecule encountering a series of openings between the chains larger than its hydrodynamic radius. The model is tested against data taken from the literature for a series of polymer solutions and solute probes and found to provide good agreement to the effects of solute size, polymer concentration, and polymer flexibility. 相似文献
106.
Xuqi Song John R. Grace Hsiaotao Bi C. Jim Lim Edward Chan Brian Knapper Craig McKnight 《加拿大化工杂志》2006,84(2):161-169
The hydrodynamics of fluid cokers were studied in a pressurized fully cylindrical cold model of diameter 483 mm, geometrically and dynamically scaled down by a factor of ~20 from commercial units. Differential pressure fluctuations, voidage distributions, solids momentum flux distributions and steady state gas mixing behaviour in the reactor section are compared for the same operating conditions with two kinds of particles, FCC and fluid coke. The voidage distributions and core‐annular flow structures in the reactor section were similar enough that either FCC or fluid coke particles can be used for cold modelling of fluid cokers. 相似文献
107.
K.M. McNamara K.K. Gleason D.J. Vestyck J.E. Butler 《Diamond and Related Materials》1992,1(12):1145-1155
The quality of chemically vapor deposited diamond films was assessed in terms of sp2/sp3 content as determined by solid-state nuclear magnetic resonance (NMR) and Raman spectroscopy. While the results of the two techniques are in qualitative agreement, only the NMR spectra yield quantitative values for the sp2/sp3 ratio. Only sp3 carbon was observed in the NMR spectra of very high quality hot-filament, microwave plasma, and d.c. arc-jet chemically vapor deposited films. As expected, Raman spectroscopy is extremely sensitive to sp2 bonded carbon, identifying small amounts below the detection limit of the NMR spectrometer. Comparison of the two techniques, however, indicates that Raman spectroscopy may be so sensitive to sp2 bonded carbon that sp3 bonded carbon in films containing as much as 90% sp3 bonded material may remain undetected. NMR linewidths indicate that the sp3 carbon in such material shows more disorder than that found in high-quality polycrystalline films. 相似文献
108.
The determination of the diffusion coefficient for water in various porosity cellulose acetate membranes by a gravimetric method, using a humidified carrier gas, is described. It was found to be impossible to obtain meaningful results for very porous membranes, although dense membranes gave limiting values of diffusion coefficient at high carrier gas velocities. This phenomenon is explained in terms of the dissipation of the heat of sorption by the forced convection provided by the carrier gas. The variation of diffusion coefficient with concentration of water in dense cellulose acetate is explained in terms of clustering of water molecules in the polymer at high concentration. 相似文献
109.
Joseph Eng Jr. Bernd Frühberger Jingguang G. Chen Brian E. Bent 《Catalysis Letters》1998,54(3):133-140
The thermal decomposition pathways of isobutene and 1-butene on both Mo(110) and 4 × 4-C/Mo(110) surfaces have been studied using high-resolution electron energy loss spectroscopy (HREELS) in order to highlight the substantially different activities of these two surfaces towards the cleavage of C–H and C–C bonds. On clean Mo(110), the CH2 group of isobutene decomposes upon heating to 150 K, producing either a /-bonded isobutenylidene [(CH3)2CCH] species or a 1,1-di-/-bonded isobutenyl [(CH3)2CC] species. Upon further heating, extensive C–H bond scission occurs to form hydrocarbon fragments which do not contain CH3 or CH2 groups, but appear to have largely intact carbon skeletons. By contrast, isobutene is molecularly adsorbed on the carbide-modified surface at 150 K. Further heating produces isobutylidyne [(CH3)2HCC] by 300 K, which subsequently decomposes via C–C bond scission to generate surface methyl groups. The different activation sequence of the C–H and C–C bonds of isobutene on clean and carbide-modified Mo(110) surfaces is also qualitatively confirmed by comparative studies of 1-butene on the two surfaces. 相似文献
110.
The effect of adding an oxygenated poison (O2, CO or H2O) to a hydrogen/nitrogen stream producing ammonia over a triply promoted (K2O, CaO, Al2O3) commercial catalyst is not unsurprisingly rapidly to poison the catalyst. However, immediately the oxygenated poison reacts with the catalyst and before total poisoning has occurred, which in these experiments took 10 min, there was an explosive release of ammonia producing concentrations in the gas phase in excess of the equilibrium value. This is thought to be due to a convulsive reorganisation of the surface of the catalyst in forming regions of an oxide overlayer, resulting in the expulsion of the standing surface nitrogen atom coverage as ammonia. However, in contradistinction to the observation of complete poisoning of the triply promoted catalyst shortly after switching the water (2.9%) into the hydrogen/nitrogen stream, when polycrystalline iron was used as the catalyst, after the initial pulse of ammonia was observed, the small quantity of water (2.9%) in the hydrogen/nitrogen stream resulted in an increased rate ( ×3) of ammonia synthesis which declined only slightly over the twenty minute duration of the experiment. The difference in behaviour between the triply promoted catalyst and the polycrystalline iron is thought to be due to the relative ease of reduction of the latter, so that submonolayer quantities of oxide can be stabilised on the surface of the polycrystalline iron. The promoting effect of this oxide overlayer is either structural or electronic; no distinction can be made from these experiments. The technique of injecting either O2 or CO into a hydrogen/nitrogen stream which is producing ammonia over promoted catalysts in quantities insufficient to cause complete poisoning and measuring the oxygen coverage of the catalyst to a measured decrease in the ammonia synthesis rate, appears to be a ready, in situ method for the determination of the active catalyst area. 相似文献