Graft polymerization of acrylonitrile onto wheat straw

Acrylonitrile was graft polymerized onto ground, water-washed wheat straw using Fe²⁺-H₂O₂ as initiator. Reaction conditions were selected to minimize homopolymer formation and maximize the amount of polyacrylonitrile (PAN) grafted to straw. Polymerizations typically yielded straw-g-PAN containing 30–35% PAN. A two-step fractionation scheme was developed for determining the relative amounts of PAN grafted to cellulose, hemicellulose, and lignin. This scheme involved (1) delignification of straw-g-PAN with sodium chlorite followed by removal of lignin-grafted PAN by extraction with dimethylformamide (DMF), and (2) hydrolysis of the hemicellulose component with 1 N trifluoroacetic acid followed by DMF extraction of hemicellulose-grafted PAN. Product remaining after these two treatments was assumed to be cellulose-g-PAN. When relative amounts of PAN grafted to cellulose, hemicellulose, and lignin were compared with relative percentages of these components present in wheat straw, the percentage of total PAN grafted to lignin was less than its relative percentage in straw, whereas that grafted to hemicellulose was considerably more. Although the use of Ce⁴⁺ as initiator gave little or no polymer with whole, water-washed straw, grafted polymerization occurred when delignified straw was used as substrate. Relative amounts of PAN grafted to cellulose and hemicellulose were not greatly different from those observed with Fe²⁺-H₂O₂ initiation onto whole straw.     

The anomalous dispersion of X-rays by single crystal ZnSe

An X-ray photographic method is described which allows the (111) and (¯1¯1¯1) faces of a suitably prepared slice of a single crystal of ZnSe to be distinguished. Etching in hot concentrated HCl produces triangular pits on the (111), zinc face, but merely roughens the (¯1¯1¯1) selenium face.     

Augmenting real data with synthetic data: an application in assessing Radio‐Isotope identification algorithms

The performance of Radio‐Isotope IDentification (RIID) algorithms using gamma spectroscopy is increasingly becoming important. For example, sensors at locations that screen for illicit nuclear material rely on isotope identification to resolve innocent nuisance alarms arising from naturally occurring radioactive material. Recent data collections for RIID testing consist of repeat measurements for each of several scenarios to test RIID algorithms. Efficient allocation of measurement resources requires an appropriate number of repeats for each scenario. To help allocate measurement resources in such data collections for RIID algorithm testing, we consider using only a few real repeats per scenario. In order to reduce uncertainty in the estimated RIID algorithm performance for each scenario, the potential merit of augmenting these real repeats with realistic synthetic repeats is also considered. Our results suggest that for the scenarios and algorithms considered, approximately 10 real repeats augmented with simulated repeats will result in an estimate having comparable uncertainty to the estimate based on using 60 real repeats. Published in 2009 by John Wiley & Sons, Ltd.     

Performance Analysis of COFDM for Broadband Transmission on a Fading Multipath Channel

This paper gives a unified analysis of the effects of multipath dispersion and Doppler spreading due to fast fading in OFDM systems, deriving simple closed-form expressions for intersymbol and interchannel interference in the most important cases. It shows also why sine wave carriers are in general the optimum bearers for the sub-channels. The expressions for interference are used to estimate the BER performance of coded OFDM, showing that the use of forward error correction (FEC) coding and a guard period are both essential for optimum performance. As an example it is shown that a 64 sub- channel OFDM system can achieve a data rate of 6.4 Mbit/s on a typical urban mobile radio channel.     

Estimation procedures and error analysis for inferring the total plutonium (Pu) produced by a graphite-moderated reactor

Graphite isotope ratio method (GIRM) is a technique that uses measurements and computer models to estimate total plutonium (Pu) production in a graphite-moderated reactor. First, isotopic ratios of trace elements in extracted graphite samples from the target reactor are measured. Then, computer models of the reactor relate those ratios to Pu production. Because Pu is controlled under non-proliferation agreements, an estimate of total Pu production is often required, and a declaration of total Pu might need to be verified through GIRM. In some cases, reactor information (such as core dimensions, coolant details, and operating history) are so well documented that computer models can predict total Pu production without the need for measurements. However, in most cases, reactor information is imperfectly known, so a measurement and model-based method such as GIRM is essential. Here, we focus on GIRM's estimation procedure and its associated uncertainty. We illustrate a simulation strategy for a specific reactor that estimates GIRM's uncertainty and determines which inputs contribute most to GIRM's uncertainty, including inputs to the computer models. These models include a “local” code that relates isotopic ratios to the local Pu production, and a “global” code that predicts the Pu production shape over the entire reactor. This predicted shape is included with other 3D basis functions to provide a “hybrid basis set” that is used to fit the local Pu production estimates. The fitted shape can then be integrated over the entire reactor to estimate total Pu production. This GIRM evaluation provides a good example of several techniques of uncertainty analysis and introduces new reasons to fit a function using basis functions in the evaluation of the impact of uncertainty in the true 3D shape.     

General differential modulation scheme for quasi-orthogonal space?time block codes with partial or full transmit diversity

A general and simple differential modulation scheme that can be applied to both partial-diversity quasi-orthogonal space-time block codes and full-diversity quasi-orthogonal space-time block codes is reported. A new class of quasi-orthogonal coding structures is presented for various number of transmit antennas. Differential encoding and decoding can be simplified to differential Alamouti codes by grouping the signals in the transmitted matrix and decoupling the detection of data symbols, respectively. For the codes with partial transmit diversity, the new scheme can achieve constant amplitude of transmitted signals, and avoid signal constellation expansion; in addition, it has a linear signal detector with very low complexity. Simulation results show that these partial-diversity codes can provide very useful results at low signal-to-nose ratio for current communication systems. For codes with full transmit diversity achieved by constellation rotation, the proposed scheme has performance equal to the best full-rate quasi-orthogonal schemes previously described in the literature with the benefit of a simpler detector. Moreover, a simple linear detector is also presented for the case when two orthogonal ASK constellations are used. Extension to more than four transmit antennas is also considered.     

Flexible convergence of wireless standards and services — the IST FLOWS-project

At the start of 2002 the eight partners of the IST project FLOWS began an ambitious three-year programme of work to study the convergence of wireless systems and especially as a multi-standards approach for the provision of mobile services. The FLOWS-project is working on the appropriate techniques to enable such convergence at the user’s terminal. This paper will provide an overview of the project, its vision, the activities and expected results.      

Infant mortality: a multi-level analysis of individual and community risk factors

This paper reports the results of an analysis of infant mortality based on a conceptual model that combines micro-level and macro-level variables taken from demographic, sociological and epidemiological research traditions. Using generalized hierarchical linear modeling techniques, we analyze 1988 and 1989 linked birth and death records for Upstate New York matched with county-level data from government and private sources. Net of health and sociodemographic risk factors. our results show that the number of per capita primary care physicians and local government expenditures on health care services and hospitals are positively linked to an increase in the probability of infant death and that our indicator of hospital facilities is negatively related to risk of death. We also find that some negative health behaviors and health resources of mothers are mediated by the local health care environment. Our results demonstrate the utility of combining perspectives from several disciplines when evaluating infant death, especially the impact of policy-related issues concerning health care service in