Strain-induced crystallization,Part IV: Induction time analysis

The empirical equation, 1/t_i = Ae^Ei/RT, which expresses the exponential dependence of the reciprocal of crystallization induction time, t_i, has been analyzed and shown to be equivalent to the nucleation rate equations derived earlier in Part III (1). Consequently we have used the t_i measurements obtained earlier by Krueger and Yeh to calculate not only the nucleation rate enhancements but also the melting point elevations, the relative crystal thickness changes and molecular coil extension ratios of shear-crystallization polyethylene. It is shown that polyethylene when crystallized between 129 and 131°C at shear rates between 1.56 and 9.70 sec^?1 can have melting point increases of 4.2 to 7.2°C and crystal thickness decreases of 20 to 25 percent, when compared to those crystallized at 130°C in the quiescent state. The predicted “coil” extension in the melt just prior to shear-induced crystallization ranges between 21 and 36 percent. The results of these analyses as well as those on nucleation rates of polyethylene oxide are discussed in detail.     

四种杀菌剂对枸杞黑果病的防治效果

枸杞黑果病是枸杞产区的主要病害．发病后造成黑花、黑蕾和黑果，使枸杞产量降低，品质变劣。为探明四种杀菌剂对枸杞黑果病的防治效果及最佳剂量，2003年对下述四种杀菌剂进行了田间药效对比试验，调查防效结果如下：20％三苯基醋酸锡WP450～281g／hm^2(以有效成分计，下同)，20％氟硅唑EC21．08g／hm^21．5％噻霉酮EW16、88～21．08g／hm^2、40％氟硅唑EC450g／hm^2和70％甲基托布津WP787．5g/hm^2对枸杞黑果病防效均在88．25％以上。经LSD检验各处理间防效无显著差异。     

硫醇自组装膜的电化学研究进展

综述了在金电极上硫醇自组装膜的电化学表征方法，性质和应用，介绍了自组装膜上的电子传递机理，并进行了简要的展望。     

发酵工厂中空气净化工艺的合理选择

从节能、降低成本、优化工艺的角度，对无菌空气制备过程中，空气预处理流程的选择、空气净化设备、过滤介质以及设备的遴选进行探讨，以实现工艺和工程设计的优化结合。     

南阳直馏柴油碱洗乳化的原因及对策

分析了南阳石蜡精细化工厂直馏柴油碱洗乳化的原因，介绍了该厂直馏柴油碱洗抗乳化措施，这些措施包括：优化操作参数，加强生产管理，深度碱洗柴油轻组分然后轻、重组分混合出厂。这些措施的综合应用彻底解决了南阳石蜡精细化工厂直馏柴油碱洗乳化的问题，又保证了柴油收率。     

环氧-聚氨酯互穿网络防腐蚀涂料

研制的环氧-聚氨酯互穿网络(IPN)防腐蚀涂料具有优异的防腐蚀性能和附着力。介绍了该涂料的制法。列举了IPN涂层的性能指标。讨论了影响涂层性能的各种因素。     

基于SOAP的企业异构信息系统集成

阐述了SOAP通信协议的构成和实现机制以及与相似协议的比较。基于它的跨平台的能力,将其运用于企业的分布式环境中,实现了异构信息系统间的互操作和跨部门的数据处理,提高企业数据处理的效能,同时为企业异构信息系统集成提供了新的方法。     

Word的高级应用——制作表单

通过实例,详细讲解用Word的窗体工具建立表单,以解决行政部门制作电子文档的空白表格时,让填写的人员方便、快捷地填写内容,又不随意修改(破坏)原有格式和原文。     

Preparation of phenolic resin derived 3-D ordered macroporous carbon

Three-dimensionally ordered long-range macroporous carbon structures were prepared using commercially available phenolic resin by utilizing sacrificial colloidal silica crystalline arrays as templates that were subsequently removed by HF etching after pyrolysis in an argon atmosphere. SEM, TEM, and BET were employed to characterize the morphology and the surface area of the porous carbon structures. The pore size (150–1000 nm) and BET surface area, which reflect pore volume (298.6 m²/g (1.32 cm³/g) ∼ 93.7 m²/g (0.12 cm³/g)), of the macroporous carbon structures produced were approximately proportional to the size (150–1000 nm) of the sacrificial silica sphere templates used (annealing temp. 550°C). The achieved 550 nm porous carbon structures were examined to function as potential catalyst carriers and were successfully impregnated with Ag or Pt-Ru on their inner walls after borohydride reduction at room temperature. In addition, porous carbon patterns were fabricated using the ‘micromolding in capillary’ technique, which has potential applications in the microreaction technology.     

基于PXI总线的LVDS数据采集存储模块的设计

鉴于SAR原始数据量大以及数据传输速率限制的问题,设计了基于PXI的雷达回波和图像数据实时记录模块。大容量数据采集记录系统基于通用的商业PC平台设计,选用FPGA作为主控芯片对电路整体逻辑进行控制;利用LVDS作为数据传输接口对数据进行接收,实现了数据采集、缓存以及通过PXI总线上传至上位机硬盘,以便后续处理。文中介绍了系统方案的总体设计,以及采集存储硬件电路的设计,并对电路的关键技术给以详细的分析。