Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent

A three-dimensional zinc phosphate compound with DFT topology, designated as ZnPO₄-EU1, has been synthesized by an ionothermal approach from the system HF-ZnO–P₂O₅-choline chloride-imidazolidone. Ethylenediamine, derived from decomposition of the imidazolidone component of the deep-eutectic solvent (DES) itself, is delivered to the synthesis and serves as an appropriate template for ZnPO₄-EU1. Experiments in which the synthesis conditions were varied showed that ZnPO₄-EU1 may be prepared over a wide molar ratio of P/Zn = 0.55–13.0. Powder X-ray diffraction patterns have been obtained at intervals to track the crystallization process of this material. The experimental data show that Zn₃(PO₄)₂ · 4H₂O (a dense phase) was first isolated from the DES after reaction for 1 h. Subsequently, the pure phase of ZnPO₄-EU1 was obtained with increasing crystallization time from 12 h to 72 h. The experimental results show that the nucleation and crystallization take place with relatively low levels of solvent degradation, demonstrating that zinc phosphate with a three-dimensional framework can be synthesized by in situ generation of an appropriate template using an unstable DES at high temperatures (150–200 °C).     

全球粮食危机中化肥产业面临的问题与对策

从国内外整体形势来看,通货膨胀带来的粮食危机正在全球蔓延,化肥供应不稳、价格不断增长已经对粮食生产以及农业甚至国家经济平稳发展形成了严重影响.能源和粮食紧张将是我国长期面临的问题,这就决定了化肥产业的发展方向.在产业内部,必须走向大型化基础产业与小型服务型产业结合的道路,各种产品应该根据商品特性和农业需求进行市场细分.建议国家加强对化肥产业的宏观调控、转变调控方式,加强市场需求的预警预测和实时调节,提高国家对肥料施用技术的支持力度.同时建议企业做好信息分析工作,及时做出有利于国家和企业长远发展的决策,不应盲目跟随涨价而丧失市场,当前应利用化肥涨价的时机开展技术服务工作,抢占化肥市场制高点.     

Effects of Spatial Characteristics on Smart Antenna System with Uniform Linear Antenna Array

1IntroductionCurrently,smart antenna technology can greatly en-hance system performance and i mprove the system ca-pacity so that it has been considered as a keytechnologyinthe third generation wireless communicationsystems .The researches on channel model , beamforming algo-rithms and receive algorithms have been widely carriedout and a great many of proposition have beensubmittedtothe 3th Generation Project Partner (3GPP) . Fromthe viewpoint of link-level and system-level research,many asp…     

关于木糖(醇)生产过程中环保、清洁、节能生产方法的研究

本文从环境保护角度,面对木糖(醇)生产过程中大污染、高能耗,寻找解决办法,实现可持续发展的目标.     

Analysis of S-SEED''s characteristics in optical switch

This article introduces the basic structure of a symmetric self-electrooptic effect device （S-SEED）, and applies the Kirchoff＇ s current law and a purely equivalent capacitive model, to analyze S-SEED＇s switch characteristics. Linear approximation and N-segment approximation are utilized to obtain S-SEED＇s voltage-time （V-T） and characteristics. Theoretical analysis is verified by simulations, and the results demonstrate that the precision of S-SEED＇s switch time can satisfy the requirement in applications with linear approximation. Moreover, the simulations compare S-SEED＇s switch characteristics with different input powers and input contrast ratios, which reveal that increasing input contrast ratio is an effective way to improve S-SEED＇s switch characteristics.     

建筑物下采煤方法设计

论文针对了北掌矿井井田范围建(构)筑物多、压煤严重等特点,在分析比较充填开采和条带式开采等"建下"开采方法的技术上,确定了比较适合该矿的冒落条采法开采技术,指出新建矿井以建筑物下开采为主也可获得较好的经济社会效益。在此基础上,对条采工作面长度,保留煤柱宽度及主要指标进行了设计。     

Automating application software generation

Many approaches have been proposed to enhance software productivity and reliability. These approaches typically fall into three categories: the engineering approach, the formal approach and the knowledge-based approach. But the optimal gain in software productivity cannot be obtained if one relies on only one of these approaches. This paper describes the work in knowledge-based software engineering conducted by the authors for the past 10 years. The final goal of the research is to develop a paradigm for software engineering which integrates the three approaches mentioned above. A knowledge-based tool which can support the whole process of software development is provided in this paper.     

An experiment for showing some kind of artificial understanding

In this paper we design an experiment which can be depicted as a simple scenario, a very limited 'world'. In this world, there are an actor that can pursue a project and an observer that is keeping its eyes on the actor. We try to show in the experiment that the observer can to some degree understand the actor based on its knowledge and some metaphors, i.e. understand what the actor is doing and why. As the conclusion of this experiment, we try to show some features of 'understanding'. These are (1) that 'understanding' has to be based on some preliminary knowledge; (2) that 'understanding' is a process of incremental learning; (3) that, as for symbolic systems, some metaphors are necessary for mapping real entities into concepts in mind.     

催化裂化汽油脱硫助剂TS-01的工业试验

中国石油化工股份有限公司九江分公司在I套催化裂化装置进行了TS—0l催化裂化汽油脱硫双功能助剂的工业应用。结果表明：TS—0l剂对催化裂化汽油有较好的脱硫效果。当TS—0l剂注入原料中的量为70μg／g时，对催化裂化汽油的硫脱除率约为20％；注入量为120μg／g时，硫脱除率可达到25％-30％。汽油中脱除的硫主要以硫化氢形态转移至于气、液化气中。TS—01剂对产品分布及产品其它质量无明显影响，该剂亦有良好的金属钝化效果。     

Commercial Test of Multi-functional Desulfurizing Agent TS-01 for Gasoline in FCC Process

Experimental use of multi-functional desulfurizing agent TS-01 for FCC gasoline in the FCC unit of SINOPEC Jiujiang Company shows that the multi-functional desulfurizing agent can effectively remove various kinds of sulfur in FCC gasoline and diesel fuel and fulfill passivation on heavy metals.