Large-Scale Synthesis of Graphene Films by Joule-Heating-Induced Chemical Vapor Deposition

We report large-area synthesis of few-layer graphene films by chemical vapor deposition (CVD) in a cold-wall reactor. The key feature of this method is that the catalytic metal layers on the SiO₂/Si substrates are self-heated to high growth temperature (900°C to 1000°C) by high-current Joule heating. Synthesis of high-quality graphene films, whose structural and electrical characteristics are comparable to those grown by hot-wall CVD systems, was confirmed by transmission electron microscopy images, Raman spectra, and current–voltage analysis. Optical transmittance spectra of the graphene films allowed us to estimate the number of graphene layers, which revealed that high-temperature exposure of Ni thin layers to a carbon precursor (CH₄) was critical in determining the number of graphene layers. In particular, exposure to CH₄ for 20 s produces very thin graphene films with an optical transmittance of 93%, corresponding to an average layer number of three and a sheet resistance of ~600 Ω/square.     

All‐Carbon Nanotube‐Based Flexible Field‐Emission Devices: From Cathode to Anode

The fabrication of a flexible field‐emission device (FED) using single‐walled carbon nanotube (SWNT) network films as the conducting electrodes (anode and cathode) and thin multi‐walled CNT/TEOS hybrid films as the emitters is reported. P‐type doping with gold ions and passivation with tetraethylorthosilicate (TEOS) made the SWNT network film highly conductive and environmentally stable, and hence a good alternative to conventional indium tin oxide electrodes. CNT/TEOS hybrid emitters showed high current density, low turn‐on field, and long‐term emission stability, compared with CNT emitters; these characteristics can be attributed to the TEOS sol, acting both as a protective layer surrounding the nanotube tip, and as an adhesive layer enhancing the nanotube adhesion to the substrate. All‐CNT‐based flexible FEDs fabricated by this approach showed high flexibility in field emission characteristics and extremely bright electron emission patterns.     

Extended Pilot‐Based Coding for Lossless Bit Rate Reduction of MPEG Surround

Pilot‐based coding (PBC), which is used for lossless bit rate reduction of audio coding, has been recently proposed for MPEG Surround. We propose extended PBC for further lossless bit rate reduction of MPEG Surround. Extended PBC selects the number of pilots depending on the parameter band number and the type of spatial parameter. It then encodes the pilots and the relevant difference data. Experiments show that extended PBC is more effective than the original PBC, especially for high bit rate modes, with a negligible complexity increase on the decoder side.     

Equalization digital on-channel repeater in the single frequency networks

Digital On-Channel Repeater (DOCR) can be used for Single Frequency Networks (SFN's). It is much simple and low cost compared to Distributed Transmitter which needs Studio to Transmitter Link (STL). However, traditional DOCR has one of those defects such as a power limit, a long time system processing delay or a poor output signal quality. In order to overcome all of those defects, we introduce Equalization DOCR (EDOCR) which regenerates the original 8-VSB output signal with relatively short time system processing delay. Lab. and Field test results show that the EDOCR can eliminate the loop-back signal up to 5.5 dB with 5.5 /spl mu/s system processing delay. By using EDOCR, we can save spectrum resources and extend coverage areas.     

Synthesis and device application of hybrid host materials of carbazole and benzofuran for high efficiency solution processed blue phosphorescent organic light-emitting diodes

Highly efficient solution processed blue phosphorescent organic light-emitting diodes were developed using a carbazole–dibenzofuran hybrid host material. Asymmetric carbazole–dibenzofuran hybrid host material was synthesized by coupling reaction of phenylcarbazole and dibenzofuran, and it showed good film morphology and bipolar charge transport properties after solution coating. Blue phosphorescent organic light-emitting diodes fabricated by spin coating exhibited extremely high quantum efficiency of 23.9%, which was better than any other data reported for solution processed blue phosphorescent organic light-emitting diodes.     

可编程逻辑PLD和CPU组构W—CDMA modem

绪论从用户数量和将要支持的服务种类来看,社会对先进的信息服务的要求正在与日俱增。在这个社会里,高速Internet接入被认为是理所当然的,语声和低速率数据业务不足以满足用户的要求。支持大量开支带宽的多媒体业务的需求,是用户向蜂窝系统和网络提出的新的挑战。因此,在被称IMT-2000的动议的推动下,国际电信联盟（ITU)提出了几个能够满足这些要求的标准。很多第三代(3G)无线标准是基于宽待码分多址(W-CDMA)技术的。W-CDMA笼罩了四处散布的用户信号。这些各自具有独特序列的用户信号生成了发射波形,汇集接收到的波形又可以重…     

Disclosing the Role of Defect-Engineered Metal–Organic Frameworks in Mixed Matrix Membranes for Efficient CO2 Separation: A Joint Experimental-Computational Exploration

Incorporation of defects in metal–organic frameworks (MOFs) offers new opportunities for manipulating their microporosity and functionalities. The so-called “defect engineering” has great potential to tailor the mass transport properties in MOF/polymer mixed matrix membranes (MMMs) for challenging separation applications, for example, CO₂ capture. This study first investigates the impact of MOF defects on the membrane properties of the resultant MOF/polymer MMMs for CO₂ separation. Highly porous defect-engineered UiO-66 nanoparticles are successfully synthesized and incorporated into a CO₂-philic crosslinked poly(ethylene glycol) diacrylate (PEGDA) matrix. A thorough joint experimental/simulation characterization reveals that defect-engineered UiO-66/PEGDA MMMs exhibit nearly identical filler–matrix interfacial properties regardless of the defect concentrations of their parental UiO-66 filler. In addition, non-equilibrium molecular dynamics simulations in tandem with gas transport studies disclose that the defects in MOFs provide the MMMs with ultrafast transport pathways mainly governed by diffusivity selectivity. Ultimately, MMMs containing the most defective UiO-66 show the most enhanced CO₂/N₂ separation performance—CO₂ permeability = 470 Barrer (four times higher than pure PEGDA) and maintains CO₂/N₂ selectivity = 41—which overcomes the trade-off limitation in pure polymers. The results emphasize that defect engineering in MOFs would mark a new milestone for the future development of optimized MMMs.     

Extreme Two‐Phase Cooling from Laser‐Etched Diamond and Conformal,Template‐Fabricated Microporous Copper

This paper reports the first integration of laser‐etched polycrystalline diamond microchannels with template‐fabricated microporous copper for extreme convective boiling in a composite heat sink for power electronics and energy conversion. Diamond offers the highest thermal conductivity near room temperature, and enables aggressive heat spreading along triangular channel walls with 1:1 aspect ratio. Conformally coated porous copper with thickness 25 µm and 5 µm pore size optimizes fluid and heat transport for convective boiling within the diamond channels. Data reported here include 1280 W cm^?2 of heat removal from 0.7 cm² surface area with temperature rise beyond fluid saturation less than 21 K, corresponding to 6.3 × 10⁵ W m^?2 K^?1. This heat sink has the potential to dissipate much larger localized heat loads with small temperature nonuniformity (5 kW cm^?2 over 200 µm × 200 µm with <3 K temperature difference). A microfluidic manifold assures uniform distribution of liquid over the heat sink surface with negligible pumping power requirements (e.g., <1.4 × 10^?4 of the thermal power dissipated). This breakthrough integration of functional materials and the resulting experimental data set a very high bar for microfluidic heat removal.     

New queueing strategies employing service interval-based priority for real-time communications in atm networks

In this paper, we propose queueing strategies employing the service interval-based priority (sip) which can provide delay-bounded, and loss-free services, while maximizing bandwidth utilization in the atm network. We also describe a variation of the sip, the residual service interval-based priority (rsip) which can achieve almost full utilization by assigning priorities dynamically on the basis of the residual service interval. We store the realtime cells belonging to different connections in logically separated queues, and for each queue, we set a parameter called service interval, during which only one cell is allowed to be transmitted. The sip server takes and transmits the head-of-line (hol) cell of the queue which has the smallest service interval, while the rsip server selects the queue with the smallest residual service interval. When there is no eligible real-time cell, it transmits non-real-time cell, thus enabling a maximized bandwidth utilization. Employing the above queueing strategies, we analyze the delay characteristics deterministically with the leaky bucket bounded input traffic and then dimension the optimal service interval. In dimensioning the service interval and buffer space of each real-time service queue, we consider burstiness of traffic in conjunction with delay constraints, so that bandwidth utilization can get maximized. In addition, we consider the issues of protection from malicious users, average bandwidth utilization, and coupling between the delay bound and the bandwidth allocation granularity.     

Fast Classification Networks For Signal Processing

We present a generalization of the corner classification approach to training feedforward neural networks that allows rapid learning of nonbinary data. These generalized networks, called fast classification (FC) networks, are compared against backpropagation and radial basis function networks and are shown to have excellent performance for prediction of time series and pattern recognition. FC networks do not require iterative training and they can be used in many signal processing applications where fast, nonlinear filtering provides an advantage.